The invention relates to a method of complex utilization of the waste residue that from gold extraction with cyanidation. This invention belongs to the field of metallurgy and chemical technology. Firstly, the waste residue that from gold extraction with cyanidation is pretreated with acid. The floatation process is adopted here. The first step is to concentrate cuprum, plumbum, zincum and argentum; Secondly, collect 47%-52% of the high-grade sulfur and concentrate gold and argentums; Then roast the high-grade sulfur concentrate, the gas is utilized to produce acid, and the waste heat is utilized to produce electricity, and the waste residue is utilized to extract gold with cvanidation. After washing by water, the leavings which contains 62%-68% iron can be used as iron concentrate. Finally, produce slag brick with the refuse. The technology which could reclaim the elements, such as Fe, S, Cu, Pb, Zn, Au, Ag, complex utilizes the waste residue that from gold extraction with cyanidation. The invention takes full advantage of resource. The effect of integrated utilization of resource and the economic benefit are enhanced and the environmental pollution is lessened by this way.