68 results about "Zero liquid discharge" patented technology

An evaporation based method for generation of high pressure steam from produced water in the heavy oil production industry. De-oiled produced water is processed through a high pH/high pressure evaporator driven by a commercial watertube boiler. The vapor produced by the evaporator is suitable for the steam assisted gravity drainage (SAGD) method being utilized by heavy oil recovery installations, without the use of once through steam generators that require extensive chemical treatment, and without requiring atmospheric distillation, which requires high power consuming compressors. Evaporator blowdown may be further treated in a crystallizing evaporator to provide a zero liquid discharge (ZLD) system and, with most produced waters, at least 98% of the incoming produced water stream can be recovered in the form of high pressure steam.

A zero liquid discharge (ZLD) power plant (20) includes an advanced oxidation system (72) for reducing contaminants in source water (70) to form feed water (40) for a boiler (24). The system (72) includes an ozonation module (86) for applying high concentration ozone to the source water (70) to form a mixed stream (104), an ozone reactor (92) in which the mixed stream is retained (104) under pressure, an ultraviolet reactor (98) downstream from the ozone reactor (92) for enhanced contaminant reduction, and a retention tank (103) downstream from the reactor (98). In one configuration, the source water (70) is evaporator distillate from an evaporator (52) that recycles cooling tower blowdown 30. The system (72) achieves organic contaminant reduction at total organic carbon (TOC) levels of less than three hundred parts per billion.

A process for enhanced removal of impurities from water by an enhanced multi-step electrocoagulation process including electrocoagulation, solids separation, hardness removal, crystallization, and, optionally, reverse osmosis and evaporative purification. Embodiments of the invention may remove multiple impurities at substantial savings in time, energy, and chemical use. Zero liquid discharge options are also reported.

In certain embodiments, a system includes a gasification system configured to output grey water. The system also includes a grey water zero liquid discharge (ZLD) system configured to receive the grey water and to generate a first stream of distillate. The grey water ZLD system comprises an ammonia stripping system. An amount of water into and out of the grey water ZLD system is approximately equal.

The invention relates to a solar zero-liquid-discharge sea water desalting plant and method. Moisture in sea water is evaporated quickly at low energy consumption by using a liquid spray method and multistage hot air contact; 100-400 DEG C hot air is supplied by a condensation solar heat collector, micro-dimension sea water drops perform moisture diffusion and heat transfer with dry hot air many times, nano drop characteristic evaporation is implemented an atomization evaporator, the obtained high-temperature saturated moist air is cooled by a saturated moist air condenser to obtain fresh water, the rest low-temperature saturated air is exhausted, and solid crystals are taken out from the bottom of the atomization evaporator. The invention is suitable for desalting of sea water, or concentration separation or liquid-solid separation of bitters and other electrolyte water solutions. The invention has the advantages of perfect structure, strong automatic control performance and high efficiency, and fully utilizes the solar energy.

Embodiments presented herein provide an evaporation based zero liquid discharge method for generation of up to 100% quality high pressure steam from produced water in the heavy oil production industry. De-oiled water is processed in an evaporation system producing a distillate that allows steam to be generated with either drum-type boilers operating at higher pressures or once-through steam generators (OTSGs) operating at higher vaporization rates. Evaporator blowdown is treated in a forced-circulation evaporator to provide a zero liquid discharge system that could recycle>98% of the deoiled water for industrial use. Exemplary embodiments of the invention provide at least one “straight sump” evaporator and at least one hybrid external mist eliminator. Embodiments of the evaporation method operate at a higher overall efficiency than those of the prior art by producing distillate at a higher enthalpy which minimizes the high pressure boiler preheating requirement.

A method is presented for the production of cellulosic ethanol, acetic acid and derivatives from the extract containing fibers and hemicelluloses after steam cooking of biomass in a host plant. The process is integrated with the host plant process to minimize the effect of loss of heat value from the extracted hemicelluloses and eliminate the need for the waste water treatment plant.

Many processes generate wastewater streams rich in sulfate and chloride. These salt components are traditionally not recovered and are discharged to the environment. The invention recovers pure water for recycle/reuse and simultaneously generates valuable pure salts of NaCl and Na2SO₄ for beneficial reuse, eliminating the waste stream. Process consists of the sequential crystallization of salt products with an intermediate purification step in which a chemical reactant is added to elevate levels of purity. The process is configured to simultaneously achieve zero liquid discharge.

We provide an evaporation based zero-liquid discharge method for generation of steam for enhanced oil recovery (EOR) processes utilizing once-through steam generators (OTSGs). The method includes feeding the OTSG(s) with produced water, vaporizing a fraction of this water for steam injection and blowing down the balance of the water. This water, referred to as OTSG blowdown, can be flashed to produce a vapor stream and a liquid that is fed to a mechanical vapor compression (MVC) evaporative process. The latent energy contained in the vapor stream generated by the upstream flash is beneficially recycled to substantially reduce or eliminate the energy consumption of the MVC process. The evaporative process can be used to reduce the liquid waste for disposal or eliminate the need for liquid disposal by achieving zero liquid discharge.

A stacked type falling film evaporator includes a first evaporator, a second evaporator, a first vapor recovering device, a second vapor recovering device and a vapor recompressor. The first evaporator and the second evaporator respectively have evaporation tubes of a length of 5 m to 10 m, and are stacked in such a manner that wastewater passes through the first evaporator and the second evaporator in order. The first vapor recovering device collects vapor generated from the wastewater in the first evaporator and supplies the collected vapor to the second evaporator. The second vapor recovering device collects vapor generated from the wastewater in the second evaporator and supplies the collected vapor to the first evaporator. The vapor recompressor compresses the vapor collected in the second vapor recovering device before the vapor is supplied to the first evaporator.

This invention obtains fresh water and only solid waste from input saline water. This result is commonly known as desalination having zero liquid discharge (ZLD). The current common means of ZLD desalination is to use any common desalination process such as distillation, reverse osmosis, electrodialysis, etc. followed by brine recovery and crystallization which are both based on evaporation of water processes. This invention provides an alternative to the commonly used brine recovery and crystallization processes to produce only solid waste. This invention has major components of (a) new ion concentration process, (b) combinations of prior art desalination processes and new ion concentration processes to produce fresh water and nearly saturated saline water from a saline water input, (c) another combination of prior art desalination and new ion concentration processes to produce fresh water and supersaturated saline water having a salinity in the metastable state zone from a nearly saturated saline water input, and (d) a separate process that precipitates out solids from the supersaturated saline water after seed crystals are introduced. The process also provides a means that prevents long-term buildup of precipitated solids in the ion concentration process that supersaturates the nearly saturated saline water input. The ion concentration process is composed of variations of prior art ion transfer processes where electrodialysis and capacitive deionization are examples.

The invention discloses a distillation separation method for oily wastewater, which comprises the steps of vacuum evaporation, distillation treatment and condensation treatment, and pollutant concentration and pollutant discharge, wherein the vacuum evaporation is used for evaporating industrial wastewater in vacuum, and moisture in the wastewater is gasified into gas; the distillation treatment and the condensation treatment are used for distillating and separating the evaporated gas after being liquefied, and the separated water is distillated to obtain 90-95% of water through concentration and then is industrially recycled; the pollutants left after wastewater evaporation are concentrated so as to concentrate out 5-10% of waste; and the concentrated pollutants are discharged. Breakthrough zero liquid discharge and zero pollution are realized; and the treatment cost is reduced, and a clean water treatment process is used for producing clean water. According to the method disclosed by the invention, sewage discharge and recording in government departments are not needed, evaporation and concentration are carried out at a low temperature in a vacuum state, and the environmental design is safe, so that 24-hour fully automatic operation and an automatic cleaning function are realized.

We provide an evaporation based method for water recovery from gasification wastewater to achieve zero liquid discharge. Grey water from a gasification system is processed by an evaporation system which recovers >99% of the influent water and generates a solid phase in a crystallizing reactor. The crystallizing reactor converts dissolved solids present as highly soluble species into alternative chemical forms that are amenable to precipitation and removal from the liquid phase to achieve zero liquid discharge.

The invention relates to the field of water treatment and discloses a concurrent flow reverse osmosis film assembly, a reverse osmosis system and a method for treatment of salt containing water. The concurrent flow reverse osmosis film assembly comprises a reverse osmosis film, a concentrated water separating net and a fresh water separating net. A concentrated water flow channel is formed by the concentrated water separating net, and a fresh water flow channel is formed by the fresh water separating net. A raw water inlet and a concentrated water outlet are formed in the concentrated water flow channel, and a permeation side water inlet and a water producing outlet are formed in the fresh water flow channel. By using the concurrent flow reverse osmosis film assembly and the reverse osmosis system for the treatment of the salt containing water, the operating pressure and the running cost do not need to be improved, but the concentration limitation of an existing reverse osmosis system can be broken through; and the discharge quantity of final concentrated saltwater of the system is greatly reduced, the recycling efficiency of water resource can be improved, and the comprehensive treatment cost for achieving zero liquid discharge can be greatly lowered.

The present invention provides an industrial wastewater recovery apparatus (100) aiming at Zero Liquid Discharge (ZLD). The apparatus (100) provides two stages in pre-heating the spiral coil pipe (103) containing wastewater and also conserves the heat by using the two heat exchangers (104, 105). The apparatus (100) agitates the surface wastewater to increase the rate of evaporation for faster heating. The apparatus (100) provides two stages in condensation of distilled water and also provides real-time monitoring of the water quality. The apparatus (100) provides automatic cleaning in the various parts during the operations. Further, a plurality of IoT sensor (201) monitor the real time parameters of the industrial wastewater recovery apparatus (100) and data is available to the user on the electronic display device (204).

The invention discloses a method for deeply treating inorganic high-salt industrial wastewater and realizing zero liquid discharge. The method comprises the following steps: treating alkaline waste residues, chemically removing hardness, precipitating and separating, carrying out double-membrane concentration and recycling according to different quality. The method disclosed by the invention has the beneficial effects that all the high-salt wastewater can be recycled and the zero liquid discharge is realized; calcium-containing alkaline waste residues (such as carbide slag and lime powder), carbonate-containing alkaline waste residues, waste gas containing carbon dioxide and the like are industrial wastes and comprehensive utilization of treating wastes by wastes is realized; the hardness is technically removed and the total hardness is reduced to be lower than or equal to 4mmol/L; scaling properties of the wastewater are reduced and the industrial wastewater is convenient to concentrate through low-pressure reverse osmosis; and particularly, according to different water quality of the high-salt industrial wastewater, different hardness removing materials and methods are adopted and the hardness removing cost is low.

Disclosed are zero liquid discharge (ZLD) processes that utilize naturally occurring or supplemental silicate in the water supply for removing magnesium and calcium hardness from aqueous alkaline streams in the form of a silica gel, thereby allowing separation of a low hardness supernant for recycling.

The desalination system with mineral recovery is a system for desalinating water using spray drying, which allows for both the production of purified water and the recovery of mineral salts. The desalination system with mineral recovery is a two-stage system for zero-liquid discharge (ZLD) desalination of feed water. The feed water may be, for example, seawater, reverse osmosis (RO) brine (i.e., the waste brine from a RO process), nano-filtration (NF) reject, multistage flash (MSF) brine, or the like. The first stage receives the feed water and uses a spray drying process to produce concentrated brine and a first volume of purified water. The concentrated brine is fed to the second stage, which also uses a spray drying process to produce a second volume of purified water and a volume of recovered mineral salts.

A method for desalinating a brine includes the use of a cooled intermediate-cold-liquid (ICL), which combines with the brine in a crystallization or freezing tank to produce a slurry of ice, brine, and ICL. The method includes steps for separating the ICL, ice and brine, and returning the separated ICL to the source of cooled ICL tank. The method concludes with the steps of passing the separated brine to the crystallization tank, and melting the separated ice to form desalinated water. The method is significant in that it produces desalinated liquid water and solid salts. The combination of superior heat transfer with high quality purified water and competitive desalination economy makes the disclosed freeze desalination technology an attractive solution for desalination of highly concentrated brines produced in a variety of industries, including but not limited to the oil and gas industry and reject brine management.