A method for improving the detoxification of excess calcium hydrate during cellulose ethanol production relates to the method for improving the detoxification of the excess calcium hydrate. The invention solves the problems of big dosage of calcium hydroxide and low converting rate of cellulose ethanol of existing detoxification methods of the excess calcium hydrate, the method comprises the following steps: firstly, preparing a steam explosion straw, secondly, preparing filtrate A and a filter residue, thirdly, preparing filtrate B, fourthly, placing the filtrate B into the residue and adjusting the PH, then carrying out the damp-heat disinfection, adding cellulose and saccharomyces cerevisiae, then carrying out the saccharifying and fermentation, namely completing the improvement of the detoxification of the excess calcium hydrate during cellulose ethanol production. The invention not only reduces the dosage of the calcium hydrate, and the dosage is only 50%-60% of that of the prior art, but also improves the conversion rate of the cellulose ethanol to 84%-95% from the original 75%-79%, and can be widely applied in the production technologies. The method of the invention has the advantages that the required equipment is simple, and the cost of raw materials is low.