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Corrosion inhibitor for ethylene chemical engineering

A corrosion inhibitor and chemical technology, applied in the field of corrosion inhibitors for ethylene chemical industry, can solve the problems of unfriendly environment, poor anti-corrosion effect of corrosion inhibitors, and generation of harmful substances, etc., to achieve corrosion inhibition speed and good corrosion inhibition performance , good environmental protection effect

Inactive Publication Date: 2019-07-16
上海贵通新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to provide a kind of corrosion inhibitor for ethylene chemical industry, to solve the need to use corrosion inhibitor in the current ethylene processing process in the above background technology, but the existing corrosion inhibitor will produce harmful substances after use, which is not good for the environment Friendly, and the anti-corrosion effect of the corrosion inhibitor is not good

Method used

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  • Corrosion inhibitor for ethylene chemical engineering
  • Corrosion inhibitor for ethylene chemical engineering

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Experimental program
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Effect test

Embodiment 1

[0020] Sodium silicate 15%, acrylic acid 3%%, hydroxyethylidene diphosphate 1%, mercaptobenzothiazole 5%, benzotriazole 16%, oleic acid 10%, ethylenediamine 10%, diethylenetriamine 11%, imidazoline 12%, alkanol 1%, quaternary ammonium salt 1%, acetylenic alcohol 2%

[0021] Preparation method: Weigh sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzotriazole, imidazoline and oleic acid, then mix sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzene And triazole, imidazoline and oleic acid undergo dehydration condensation reaction to generate compound imidazoline, wherein the temperature of vacuum dehydration in the dehydration condensation reaction is 150°C, and the reaction time is 5h; compound imidazoline, ethylenediamine, alkylamine Base alcohol and alkylamino alcohol are mixed according to the ratio of 1:2:1:2, and the temperature is raised to 70-80°C while stirring, and the heating reaction is carried out for 2 hours; 70% ...

Embodiment 2

[0023] Sodium silicate 17%, acrylic acid 5%, hydroxyethylidene diphosphate 3%, mercaptobenzothiazole 7%, benzotriazole 20%, oleic acid 15%, ethylenediamine 13%, diethylenetriamine 16% , imidazoline 17%, alkanol 3%, quaternary ammonium salt 2%, acetylenic alcohol 4%.

[0024] Preparation method: Weigh sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzotriazole, imidazoline and oleic acid, then mix sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzene And triazole, imidazoline and oleic acid undergo dehydration condensation reaction to generate compound imidazoline, wherein the temperature of vacuum dehydration in the dehydration condensation reaction is 150°C, and the reaction time is 5h; compound imidazoline, ethylenediamine, alkylamine Base alcohol and alkylamino alcohol are mixed according to the ratio of 1:2:1:2, and the temperature is raised to 70-80°C while stirring, and the heating reaction is carried out for 2 hours; 70%...

Embodiment 3

[0026] Sodium silicate 18%, acrylic acid 6%, hydroxyethylidene diphosphate 4%, mercaptobenzothiazole 8%, benzotriazole 23%, oleic acid 18%, ethylenediamine 14%, diethylenetriamine 18% , imidazoline 118%, alkanol 4%, quaternary ammonium salt 2.5%, acetylenic alcohol 5%.

[0027] Preparation method: Weigh sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzotriazole, imidazoline and oleic acid, then mix sodium silicate, hydroxyethylidene diphosphate, mercaptobenzothiazole, benzene And triazole, imidazoline and oleic acid undergo dehydration condensation reaction to generate compound imidazoline, wherein the temperature of vacuum dehydration in the dehydration condensation reaction is 150°C, and the reaction time is 5h; compound imidazoline, ethylenediamine, alkylamine Base alcohol and alkylamino alcohol are mixed according to the ratio of 1:2:1:2, and the temperature is raised to 70-80°C while stirring, and the heating reaction is carried out for 2 hours; ...

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Abstract

The invention discloses a corrosion inhibitor for ethylene chemical engineering. The corrosion inhibitor for ethylene chemical engineering is prepared by the following steps of: 1, burdening, specifically, 15%-20% of sodium silicate, 3%-7% of acrylic acid, 1%-6% of HEDP, 5%-10% of mercaptobenzothiazole, 16%-26% of benzotriazole, 10%-20% of oleic acid, 10%-16% of ethylenediamine, 11%-21% of diethylenetriamine, 12%-20% of imidazoline, 1%-6% of alkylamino alcohol, 1%-3% of quaternary ammonium salt and 2%-6% of acetylenic alcohol are prepared; and 2, mixing, specifically, dehydration condensationreaction of sodium silicate, HEDP, mercaptobenzothiazole, benzotriazole, imidazoline and oleic acid is carried out to form complex imidazoline, wherein under the vacuum dehydration condition of the dehydration condensation reaction, the temperature is 150 DEG C, and the reaction time is 5 h. The corrosion inhibitor prepared by the method has the imidazoline ring structure with a high corrosion inhibition property, and therefore, the corrosion inhibitor has a good corrosion inhibition performance; and by adding a synergist, acetylenic bonds in acetylenic alcohol molecules can suffer hydrogenation reaction with nascent hydrogen in the corrosion process, and the corrosion inhibitor can form a multilayer protective film in the reaction process, and effectively inhibits the corrosion rate. Thecorrosion inhibitor does not contain phosphorus, and has a good environmental protection property.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a corrosion inhibitor for ethylene chemical industry. Background technique [0002] Ethylene is a colorless, slightly odorous gas with a density of 1.256g / L, which is slightly less dense than air. It is hardly soluble in water but easily soluble in organic solvents such as carbon tetrachloride. Ethylene is the basic chemical raw material for synthetic fibers, synthetic rubber, synthetic plastics (polyethylene and polyvinyl chloride), synthetic ethanol (alcohol), and is also used to manufacture vinyl chloride, styrene, ethylene oxide, acetic acid, acetaldehyde, and ethanol Ethylene is one of the most produced chemical products in the world, and the ethylene industry is the core of the petrochemical industry. Ethylene products account for more than 75% of petrochemical products and occupy an important position in the national economy. The world has taken ethylene product...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F11/10
CPCC23F11/10
Inventor 徐文忠
Owner 上海贵通新材料科技有限公司
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