Preparation method and application of Co-Pi/PDA/BiVO4 (cobalt phosphate/polydopamine/bismuth vanadium oxide) ternary composite photoelectrode
A polydopamine, ternary composite technology, applied in electrodes, chemical instruments and methods, electrolytic components, etc., can solve the problems of slow water oxidation kinetics, easy recombination of photogenerated electron holes, restricting the performance of bismuth vanadate, etc. Good chemical stability, good repeatability, good photoelectrochemical performance
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Embodiment 1
[0031] A kind of cobalt phosphate-polydopamine-bismuth vanadate (Co-Pi / PDA / BiVO 4 ) A preparation method for a ternary composite photoelectrode, comprising the steps of:
[0032] (1) Dissolve 3.32 g KI in 50 ml deionized water, add 0.9701 g Bi(NO 3 ) 3 ·5H 2 0, drop nitric acid to adjust the pH to 1.2 to obtain a mixed solution;
[0033] (2) Dissolve 0.7514 g of p-benzoquine in 20 ml of absolute ethanol and stir to dissolve. The two solutions were mixed and stirred vigorously for 10 minutes to obtain a BiOI solution;
[0034] (3) Electrodeposition is carried out through the three-electrode system of the electrochemical workstation, specifically, FTO is used as the working electrode, Pt wire is used as the counter electrode, and Ag / AgCl is used as the reference electrode. BiOI was electrodeposited on the FTO for 5 min with an applied bias of -0.1V. Then, the BiOI surface was rinsed with deionized water and dried at room temperature;
[0035] (4) Drop 2 drops of 0.1 mol / L d...
Embodiment 2
[0040] A kind of cobalt phosphate-polydopamine-bismuth vanadate (Co-Pi / PDA / BiVO 4 ) A preparation method for a ternary composite photoelectrode, comprising the steps of:
[0041] (1) Dissolve 3.32 g KI in 50 ml deionized water, add 0.9701 g Bi(NO 3 ) 3 ·5H 2 0, drop nitric acid to adjust the pH to 1.7 to obtain a mixed solution;
[0042] (2) Dissolve 1.001 g of p-benzoquinone in 20 ml of absolute ethanol and stir to dissolve. The two solutions were mixed and stirred vigorously for 10 minutes to obtain a BiOI solution;
[0043] (3) Electrodeposition is carried out through the three-electrode system of the electrochemical workstation, specifically, FTO is used as the working electrode, Pt wire is used as the counter electrode, and Ag / AgCl is used as the reference electrode. BiOI was electrodeposited on the FTO for 5 min with an applied bias of -0.1V. Then, the BiOI surface was rinsed with deionized water and dried at room temperature;
[0044] (4) Drop 2 drops of 0.2 mol / ...
Embodiment 3
[0049] A kind of cobalt phosphate-polydopamine-bismuth vanadate (Co-Pi / PDA / BiVO 4 ) A preparation method for a ternary composite photoelectrode, comprising the steps of:
[0050] (1) Dissolve 3.32 g KI in 50 ml deionized water, add 0.9701 g Bi(NO 3 ) 3 ·5H 2 0, drop nitric acid to adjust the pH to 2.0 to obtain a mixed solution;
[0051] (2) Dissolve 1.10 g of p-benzoquinone in 20 ml of absolute ethanol and stir to dissolve. The two solutions were mixed and stirred vigorously for 10 minutes to obtain a BiOI solution;
[0052] (3) Electrodeposition is carried out through the three-electrode system of the electrochemical workstation, specifically, FTO is used as the working electrode, Pt wire is used as the counter electrode, and Ag / AgCl is used as the reference electrode. BiOI was electrodeposited on FTO for 5 min with an applied bias of -0.1 V. Then, the BiOI surface was rinsed with deionized water and dried at room temperature;
[0053] (4) Add 0.3 mol / L dimethyl sulfo...
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