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High-stability wallpaper adhesive

A technology of wallpaper glue and glue base, applied in the direction of polymer adhesive additives, non-polymer adhesive additives, adhesive types, etc., can solve the problems of low bonding stability, wallpaper glue is easy to be affected by moisture, etc., to achieve Stably maintain the bonding performance, guarantee the moisture-proof effect, and the effect that is not easy to be affected by moisture

Active Publication Date: 2019-11-05
陈云兰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention is to provide a high-stable wallpaper glue in view of the problems that the commonly used wallpaper glue is easy to be affected by moisture and has low bonding stability.

Method used

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  • High-stability wallpaper adhesive

Examples

Experimental program
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Effect test

preparation example Construction

[0028] The preparation method of composite wallpaper glue base material, comprises the steps:

[0029](1) According to the mass ratio of 7:1~3:0.1:30~50, diatomite, hexacyclite passed through a 120 mesh sieve, silane coupling agent KH-550, and ethanol solution with a volume fraction of 70% were mixed and stirred, Immerse at room temperature for 8~12h, move to a centrifuge, centrifuge at 2000~4000r / min for 7~13min, collect the centrifuge and mix it with additives at a mass ratio of 5~8:2, heat mix at 75~83°C for 20~40min, cool down to 25~45℃, add Pingpingjia-O25 with 7~12% centrifuge mass, mix evenly, and homogenize at 3.1~5.2MPa for 7~13min to obtain a homogeneous material;

[0030] (2) In terms of parts by weight, take 25~40 parts of homogeneous material, 12~20 parts of fiber aggregate, 2~5 parts of rosin, 3~7 parts of hydrogenated rosin, and 70~90 parts of water in the reactor and mix them in 45 Stir at ~65°C for 40~60min, add catalyst with 1~4% of homogeneous material mass...

Embodiment 1

[0034] Catalyst: Mix stannous octoate and ferrocene at a mass ratio of 3:1 to obtain a catalyst.

[0035] Monomer liquid: in parts by weight, take 10 parts of acrylamide, 4 parts of methyl methacrylate, 1 part of disodium ethylenediamine tetraacetate, and 40 parts of sodium bicarbonate solution with a mass fraction of 20% and mix them to obtain mono body fluid.

[0036] Initiator: Mix potassium persulfide and sodium bisulfite at a mass ratio of 5:1 to obtain an initiator.

[0037] Fiber aggregate: at 75°C, mix microcrystalline cellulose and 1-allyl-3 methylimidazole chloride in a reaction kettle at a mass ratio of 1:20, protect with nitrogen, keep stirring for 4 hours to obtain a mixture, Raise the temperature to 120°C, take the mixed material and add stannous octoate, lactide, and p-dioxanone at a mass ratio of 10:1:1:6 to mix, keep the temperature for 5 hours, and cool naturally to room temperature to obtain the reaction material. The material is mixed with isopropanol at ...

Embodiment 2

[0047] Catalyst: Mix stannous octoate and ferrocene at a mass ratio of 5:1 to obtain a catalyst.

[0048] Monomer liquid: in parts by weight, take 12 parts of acrylamide, 6 parts of methyl methacrylate, 2 parts of disodium ethylenediamine tetraacetate, and 50 parts of sodium bicarbonate solution with a mass fraction of 20% and mix them to obtain mono body fluid.

[0049] Initiator: Mix potassium persulfide and sodium bisulfite at a mass ratio of 5:1.5 to obtain the initiator.

[0050] Fiber aggregate: at 80°C, mix microcrystalline cellulose and 1-allyl-3 methylimidazole chloride in a reaction kettle at a mass ratio of 1:25, protect with nitrogen, and keep stirring for 5 hours to obtain a mixture. Raise the temperature to 130°C, take the mixed material and add stannous octoate, lactide, and p-dioxanone at a mass ratio of 13:1:2:6 to mix, keep the temperature for 6 hours, and cool naturally to room temperature to obtain the reaction material. The material was mixed with isopro...

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Abstract

The invention discloses a high-stability wallpaper adhesive, and belongs to the field of chemical building materials. Diatomite, hexacyclic stone and the like are used for preparing a homogenizing material, a large amount of diatomite components exert a cation exchange property and are in exchange interaction with cations in an organic compound, the internal stability is improved, microcrystallinecellulose is used as a main component, 1-allyl-3-methylimidazolium chloride is used as an ionic solvent and p-dioxanone is used as a grafting monomer to prepare an amphiphilic fiber polymer material,and a hydrophilic shell is used for stabilizing and dispersing micelles and protecting contact between hydrophobic molecules and an environment medium, and has a good moisture resistance; a moisture-proof material is prepared by taking acrylamide, methyl methacrylate and the like as raw materials, so that a macromolecular polymer in an aqueous solution exceeds a certain mass concentration, hydrophobic portions are associated to form a dynamic three-dimensional network structure, a moisture-proof effect is stabilized, and the bonding strength of the wall adhesive is improved. The problem thatthe commonly used wallpaper adhesive at present is easy to damp and low in adhesion stability is solved.

Description

technical field [0001] The product of the invention belongs to the field of chemical building materials and relates to a high-stable wallpaper glue. Background technique [0002] In recent years, wallpaper has become the first choice as a decoration material to beautify the indoor environment, and wallpaper glue is widely used in the market as an adhesive for bonding wallpaper. Wallpaper glue can be divided into two types: wet glue and glue powder, both of which have their own advantages and disadvantages. Wet glue has high initial adhesion and good bonding performance. Even if it is bonded to some relatively thick wallpapers, it is not easy to warp; but wet glue is more troublesome to use, and it needs to be dissolved in water several times; Water brings inconvenience to storage and transportation. After being stored and frozen in winter, the glue-opening performance becomes poor, and the transportation cost is high. Wallpaper glue powder is an adhesive specially prepared...

Claims

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Application Information

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IPC IPC(8): C09J101/08C09J133/26C09J11/08C09J11/04C09J11/06C08F220/56C08F220/14C08F220/54C08B15/00
CPCC08B15/00C08F220/56C08K2003/387C08L2205/025C08L2205/035C09J11/04C09J11/06C09J11/08C09J101/08C08L33/26C08L91/06C08L93/04C08K9/06C08K7/26C08K5/098C08K3/38C08K13/06C08F220/14C08F220/54
Inventor 庞定根
Owner 陈云兰
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