Multi-branched high-molecular demulsifying main agent and efficient crude oil demulsifier
A polymer and multi-branch type technology, applied in the direction of dehydration/demulsification by chemical methods, can solve the problems of poor demulsification effect, low desalination rate and dehydration rate, and can not better meet the mining needs, so as to improve desalination Good effect of dehydration and demulsification
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[0037] The present invention also provides a method for preparing the multi-branched polymer demulsifier main agent described in the above technical solution, which is characterized in that it comprises the following steps:
[0038] a) reacting phloroglucinol, triethylenetetramine and formaldehyde to obtain the phenolic amine initiator shown in formula (II);
[0039] b) reacting the phenolic amine initiator with propylene oxide and ethylene oxide to obtain the multi-branch polymer demulsifying main agent represented by formula (I).
[0040] According to the present invention, first phloroglucinol, triethylenetetramine and formaldehyde are reacted to obtain the phenolic amine initiator shown in formula (II):
[0041]
[0042] In the present invention, it is preferred to firstly mix phloroglucinol and triethylenetetramine and heat to dissolve. Wherein, the mass ratio of phloroglucinol to triethylenetetramine is preferably 1: (3-3.15). The heating temperature is preferably 4...
Embodiment 1
[0088] 1.1 Sample preparation
[0089] Weigh 1 part of phloroglucinol and 3.1 parts of triethylenetetramine, put them in a 500mL three-necked flask, put the three-necked flask into a constant temperature heating magnetic stirrer at 40°C, and stir until the phloroglucinol is completely dissolved; Slowly add 3.3 parts of formaldehyde with a constant pressure dropping funnel under the same conditions, and the dropping rate is 1 drop / s; after the dropping is completed, raise the temperature to 75°C and react at a constant temperature for 1.5 hours; after that, pour the reaction mixture into a beaker, Dry in a vacuum oven at 120°C and 1.33kpa for 3 hours, then lower the temperature to 45-50°C, take out the product, and obtain the phenamine initiator represented by formula (II).
[0090] Take 1 part of phenolic amine initiator and 225 parts of propylene oxide (PO) into the autoclave, and at the same time, add 0.03 parts of potassium hydroxide as a catalyst, and use N 2 Purge and re...
Embodiment 2
[0106] Add 1 part of pentaerythramine and 100 parts of propylene oxide into the autoclave, and add 0.03 parts of potassium hydroxide as a catalyst at the same time, and use N 2 Purge and replace for 2 minutes, raise the temperature to 135°C within 1-1.5 hours, and react at the pressure of 0.35MPa for 2 hours; after the reaction, pour cooling water into the room temperature, open the lid of the autoclave, and add 60 parts of ethylene oxide alkane, heated to 120°C, and reacted for 1.5h; after the reaction was completed, cooling water was introduced to cool down to room temperature, and the product was neutralized with a small amount of glacial acetic acid to neutralize the catalyst. Wax viscosity reducer.
[0107] The synthetic wax-repelling viscosity-reducing agent was characterized by infrared spectroscopy, and the characteristic peaks were identified and assigned according to the frequency and intensity of the absorption peaks. The structure list is shown in Table 4.
[0108...
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