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Multi-branched high-molecular demulsifying main agent and efficient crude oil demulsifier

A polymer and multi-branch type technology, applied in the direction of dehydration/demulsification by chemical methods, can solve the problems of poor demulsification effect, low desalination rate and dehydration rate, and can not better meet the mining needs, so as to improve desalination Good effect of dehydration and demulsification

Active Publication Date: 2019-11-26
山东京博众诚清洁能源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the demulsifiers used are mainly epoxidized copolymers with high carbon alcohol as the initiator, and block polyether demulsifiers with resin as the initiator. These main agents have poor demulsification effect on high-salt and high-water crude oil. , the desalination rate and dehydration rate are low, and there is still a high salt content and water content after dehydration, which cannot better meet the mining needs

Method used

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  • Multi-branched high-molecular demulsifying main agent and efficient crude oil demulsifier
  • Multi-branched high-molecular demulsifying main agent and efficient crude oil demulsifier
  • Multi-branched high-molecular demulsifying main agent and efficient crude oil demulsifier

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preparation example Construction

[0037] The present invention also provides a method for preparing the multi-branched polymer demulsifier main agent described in the above technical solution, which is characterized in that it comprises the following steps:

[0038] a) reacting phloroglucinol, triethylenetetramine and formaldehyde to obtain the phenolic amine initiator shown in formula (II);

[0039] b) reacting the phenolic amine initiator with propylene oxide and ethylene oxide to obtain the multi-branch polymer demulsifying main agent represented by formula (I).

[0040] According to the present invention, first phloroglucinol, triethylenetetramine and formaldehyde are reacted to obtain the phenolic amine initiator shown in formula (II):

[0041]

[0042] In the present invention, it is preferred to firstly mix phloroglucinol and triethylenetetramine and heat to dissolve. Wherein, the mass ratio of phloroglucinol to triethylenetetramine is preferably 1: (3-3.15). The heating temperature is preferably 4...

Embodiment 1

[0088] 1.1 Sample preparation

[0089] Weigh 1 part of phloroglucinol and 3.1 parts of triethylenetetramine, put them in a 500mL three-necked flask, put the three-necked flask into a constant temperature heating magnetic stirrer at 40°C, and stir until the phloroglucinol is completely dissolved; Slowly add 3.3 parts of formaldehyde with a constant pressure dropping funnel under the same conditions, and the dropping rate is 1 drop / s; after the dropping is completed, raise the temperature to 75°C and react at a constant temperature for 1.5 hours; after that, pour the reaction mixture into a beaker, Dry in a vacuum oven at 120°C and 1.33kpa for 3 hours, then lower the temperature to 45-50°C, take out the product, and obtain the phenamine initiator represented by formula (II).

[0090] Take 1 part of phenolic amine initiator and 225 parts of propylene oxide (PO) into the autoclave, and at the same time, add 0.03 parts of potassium hydroxide as a catalyst, and use N 2 Purge and re...

Embodiment 2

[0106] Add 1 part of pentaerythramine and 100 parts of propylene oxide into the autoclave, and add 0.03 parts of potassium hydroxide as a catalyst at the same time, and use N 2 Purge and replace for 2 minutes, raise the temperature to 135°C within 1-1.5 hours, and react at the pressure of 0.35MPa for 2 hours; after the reaction, pour cooling water into the room temperature, open the lid of the autoclave, and add 60 parts of ethylene oxide alkane, heated to 120°C, and reacted for 1.5h; after the reaction was completed, cooling water was introduced to cool down to room temperature, and the product was neutralized with a small amount of glacial acetic acid to neutralize the catalyst. Wax viscosity reducer.

[0107] The synthetic wax-repelling viscosity-reducing agent was characterized by infrared spectroscopy, and the characteristic peaks were identified and assigned according to the frequency and intensity of the absorption peaks. The structure list is shown in Table 4.

[0108...

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Abstract

The invention provides a multi-branched high-molecular demulsifying main agent and an efficient crude oil demulsifier. The multi-branched high-molecular demulsifying main agent has a structure represented by formula (I). The efficient crude oil demulsifier comprises, by mass, 25-50% of the multi-branched high-molecular demulsifying main agent, 15-30% of a paraffin-control viscosity reducer, 10-20%of a penetrant, 5-15% of an antifreeze agent and 15-40% of a solvent; and the multi-branched high-molecular demulsifying main agent is the multi-branched high-molecular demulsifying main agent of theformula (I). The efficient crude oil demulsifier is obtained by using the multi-branched high-molecular demulsifying main agent is used as a main agent and mixing with the paraffin-control viscosityreducer, the penetrant, the antifreeze agent and the solvent, the paraffin-control viscosity reducer and the penetrant further assist the multi-branched high-molecular demulsifying main agent, and theparaffin-control viscosity reducer, the penetrant and the multi-branched high-molecular demulsifying main agent are compounded to achieve synergistic effects, so good demulsifying conditions and a good demulsifying environment are provided for efficient and rapid demulsification, and a good demulsifying effect is achieved.

Description

technical field [0001] The invention relates to the technical field of petroleum exploitation, in particular to a multi-branch polymer demulsifier main agent and a high-efficiency crude oil demulsifier. Background technique [0002] With the continuous deepening of oil exploration, enhanced oil recovery methods are more and more widely used, the composition of crude oil production fluid is becoming more and more complex, the water and inorganic salts in the crude oil emulsion increase, making the emulsion more stable, and the difficulty of crude oil demulsification increases. If the crude oil in this state is collected, transported and refined without treatment, it will easily cause equipment corrosion, fouling, and tower flushing during the crude oil refining process, resulting in danger and economic losses. [0003] Crude oil demulsification methods include: electric demulsification method, gravity sedimentation method, ultrasonic demulsification method, centrifugal demuls...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G33/04C08G65/28
CPCC08G65/2627C10G33/04
Inventor 马雪菲梁万根崔卫华杨聪宋吻吻崔振杰靖培培
Owner 山东京博众诚清洁能源有限公司
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