Environmentally-friendly formaldehyde purification spray capable of releasing negative oxygen ions, and preparation method thereof
A formaldehyde purification and negative oxygen ion technology, applied in the field of air purification, can solve the problems of low efficiency and inconvenience of formaldehyde purification
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Embodiment 1
[0061] S1: Take FeCl respectively 3 ·6H 2 O and FeCl 2 4H 2 O, dissolve in deionized water, stir and mix evenly, then add 0.5mol / L sodium hydroxide, adjust the pH to 13, continue to stir and react for 40min, and carry out solid-liquid separation with a magnet to obtain nano-ferric oxide;
[0062] S2: Take nano iron ferric oxide, adjust the pH to 4 with 37% hydrochloric acid, then add sodium oleate, stir and react at 60°C for 30 minutes, carry out solid-liquid separation with a magnet, and then wash 3 times with absolute ethanol at a washing temperature of 30°C, vacuum drying to obtain modified nano ferric oxide;
[0063] S3: Take the modified nano ferric ferric oxide, dissolve it in ethanol, stir for 20 minutes, then raise the temperature to 60°C, add 3-aminopropyltriethoxysilane, react for 8 hours, separate the solid and liquid with a magnet, and then use absolute ethanol, Washing with toluene, after washing, dissolve the first material in toluene, add triethylamine and 2...
Embodiment 2
[0073] S1: Take FeCl respectively 3 ·6H 2 O and FeCl 2 4H 2 O, dissolve in deionized water, stir and mix evenly, then add 0.5mol / L sodium hydroxide, adjust the pH to 13, continue to stir and react for 50min, and carry out solid-liquid separation with a magnet to obtain nano-ferric oxide;
[0074]S2: Take nano iron ferric oxide, adjust the pH to 4 with 37% hydrochloric acid, then add sodium oleate, stir and react at 65°C for 35 minutes, carry out solid-liquid separation with a magnet, and then wash 5 times with absolute ethanol at a washing temperature of 35°C, vacuum drying to obtain modified nano-ferric oxide;
[0075] S3: Take the modified nano ferric ferric oxide, dissolve it in ethanol, stir for 30 minutes, then raise the temperature to 65°C, add 3-aminopropyltriethoxysilane, react for 10 hours, separate the solid and liquid with a magnet, and then use absolute ethanol, Washing with toluene, after washing, dissolve the first material in toluene, add triethylamine and 2...
Embodiment 3
[0085] S1: Take FeCl respectively 3 ·6H 2 O and FeCl 2 4H 2 O, dissolve in deionized water, stir and mix evenly, then add 0.5mol / L sodium hydroxide, adjust the pH to 14, continue to stir and react for 60min, and magnetizes for solid-liquid separation to obtain nano-ferric oxide;
[0086] S2: Take nano iron ferric oxide, adjust the pH to 4 with 37% hydrochloric acid, then add sodium oleate, stir and react at 70°C for 40 minutes, carry out solid-liquid separation with a magnet, and then wash 6 times with absolute ethanol at a washing temperature of 40°C, vacuum drying to obtain modified nano-ferric oxide;
[0087] S3: Take the modified nano ferric ferric oxide, dissolve it in ethanol, stir for 40 minutes, then raise the temperature to 70°C, add 3-aminopropyltriethoxysilane, react for 12 hours, separate the solid and liquid with a magnet, and then use absolute ethanol, Washing with toluene, after washing, dissolve the first material in toluene, add triethylamine and 2-bromois...
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