Metallic @ GST medium heterogeneous nano core-shell structure and preparation method thereof
A technology of metal nanoparticles and shell structure, which is applied in the direction of nanotechnology, nanotechnology, metal material coating technology, etc., can solve the problems of material performance difference, difficulty in processing, limitation of tuning characteristics accuracy, etc., to achieve efficient preparation and reliable properties. The effect of tuning and high-efficiency electromagnetic conversion efficiency
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Embodiment 1
[0040] Such as figure 1 As shown in the picture at the far right, a heterogeneous nano-core-shell structure of a metal@GST medium, in which the core structure is a metal nanoparticle structure with surface plasmon resonance characteristics, and the shell structure is an amorphous phase transition Material GST.
[0041] Preferably, the surface free energy of the nanostructure is controlled by controlling the size of the metal nanoparticle.
[0042] Preferably, the metal is a commonly used plasmonic metasurface material, that is, any one of gold, silver, copper, platinum or nickel.
[0043] Preferably, the GST is Ge m Sb n 、 Ge m Te n 、 Ge m Sb n Te k or Sb m Te n , where m and n are natural numbers.
[0044] Preferably, the thickness of the core structure is in the range of 2nm-15nm.
[0045] Preferably, the thickness of the shell structure is in the range of 2nm-50nm.
[0046] Compared with the direct use of GST as the dielectric substrate, the metal@GST dielectric ...
Embodiment 2
[0048] A method for preparing a metal@GST medium heterogeneous nano-core-shell structure, comprising the following contents: processing metal nanoparticles with different surface free energies by thermal annealing, and performing phase transition on the surface of the metal nanoparticles by magnetron sputtering Material GST nano film layer deposition.
Embodiment 3
[0050] Such as figure 1 As shown, a method for preparing a metal@GST medium heterogeneous nano-core-shell structure based on surface free energy regulation, including the following steps:
[0051] Step 1, preparation of the metal nano film substrate: plating a metal film with a thickness of k1 on the surface of the substrate;
[0052] Preferably, the substrate is an electrolyte or semiconductor material with a high melting point.
[0053] Preferably, the base material is silicon, quartz glass or ITO glass.
[0054] Better, by the k 1 The control of the metal nanoparticle size is realized by the control of the nanoparticle size. The control of the nanoparticle size is the control of the surface free energy of the nanostructure. The control of the surface free energy of the nanostructure also realizes the control of the deposition of atoms bombarded by magnetron sputtering, thereby realizing phase change materials. Encapsulation of metal nanostructures.
[0055] Preferably, ...
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