Self-polishing antiseptic antiscale coating and preparing method thereof

An anti-scaling coating and self-polishing technology, applied in the coating, metal material coating process, fusion spraying, etc., can solve the problems that are difficult to achieve self-polishing anti-corrosion, anti-scaling, electrochemical corrosion, roughness increase, etc.

Inactive Publication Date: 2020-01-10
XI'AN PETROLEUM UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] At present, the anti-corrosion coatings of oil well pipes or surface pipelines in use are mainly organic coatings. However, during the application process, it was found that friction and collision of oil pipes will inevitably occur during the downhole process, resulting in damage to the coating and exposed metal. The electrochemical corrosion phenomenon of "big cathode and small anode" is easy to appear during downhole service, which will accelerate the perforation failure of the pipe string
At present, the commonly used coatings, no matter how many layers of structure, the outermost layer is basically a passivation layer or a dense layer, which mainly relies on blocking the entry of corrosive media to achieve the purpose of anti-corrosion. There is no self-polishing effect, and the scale layer is easy to adhere to the surface, and As the adhesion increases, the roughness increases and scaling becomes easier, therefore, it is difficult to achieve the dual purpose of self-polishing, anti-corrosion and anti-scaling

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  • Self-polishing antiseptic antiscale coating and preparing method thereof
  • Self-polishing antiseptic antiscale coating and preparing method thereof

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preparation example Construction

[0044] A method for preparing a self-polishing anti-corrosion and anti-fouling coating, comprising the following steps:

[0045] Step 1, the surface of the oil pipe, casing or ground pipeline is degreased, sand blasted and derusted, cleaned and dried;

[0046] Step 2, using a thermal spraying method to spray the inert metal on the inner or outer wall of the pipeline as an inert metal layer;

[0047] Step 3, using a thermal spraying method to spray the active metal on the outside of the inert metal layer as an intermediate layer;

[0048] Step 4, use the brushing method to brush the material of polymer or passivated liquid alloy on the outside of the middle layer as the surface layer of the composite coating, that is, the sealing layer. The sealing layer should be evenly brushed and the dosage should be strictly controlled. Ensure that some holes are closed, and some hole channels are left, and the number of channels is controllable.

[0049] For the sealing layer, the number M...

Embodiment 1

[0060] The self-polishing anti-corrosion and anti-scaling coating is nickel-based alloy stainless steel at the bottom, zinc alloy at the middle layer, and organic sealing agent at the surface. The plasma thermal spraying method is sequentially prepared on the outer wall of the pipe string. The nickel-based alloy stainless steel layer has a dense structure, which can prevent the infiltration of corrosive media and play the role of isolation and corrosion resistance; the zinc alloy layer has a low potential and has the function of sacrificial anode. Electronics avoid the phenomenon of "big cathode and small anode"; the organic sealing agent layer can effectively seal most of the inherent pores on the surface of the coating, control the infiltration channel of corrosive media, and ensure the anti-corrosion effect.

[0061] The self-polishing anti-corrosion and anti-scaling coating design is a comprehensive application of the electrochemical sacrificial anode anti-corrosion mechan...

Embodiment 2

[0063] The self-polishing anti-corrosion and anti-fouling coating files are the bottom layer 13Cr stainless steel, the middle layer Al alloy, and the surface layer sealing agent. The supersonic thermal spraying method is sequentially prepared on the outer wall of the pipe string. The thermal spraying process is arc current 240A, arc voltage 32V, and spraying distance 150mm. The prepared composite coating has a dense structure, high density, and optimal corrosion resistance, with a corrosion rate of only 0.072mm / a.

[0064] Most of the pores on the surface of the self-polishing anti-corrosion and anti-fouling coating are sealed by the sealing agent, leaving only a small part of the inherent pores, which are evenly distributed on the coating surface. Under the corrosion conditions of oil and gas fields, the self-polishing anti-corrosion and anti-scaling coating is affected by the synergistic effect of corrosion / scaling, and the surface will undergo a "self-polishing" behavior of...

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Abstract

A self-polishing antiseptic antiscale coating sequentially comprises an inert metal layer, an active metal layer and a hole sealing layer from interior to exterior, and the inert metal layer, the active metal layer and the hole sealing layer are sequentially prepared on the inner wall and the outer wall of an oil pipe or a casing pipe or a ground pipeline. A preparing method of the self-polishingantiseptic antiscale coating comprises the steps that firstly, a hot spraying method is adopted, and inert metal is sprayed to the outer wall of the pipeline to serve as the inert metal layer; secondly, the hot spraying method is adopted, and active metal is sprayed to the exterior of the inert metal layer to serve as a middle layer; and thirdly, a brush coating method is adopted, an alloy with the material being macromolecules or passivation liquid is brushed to the exterior of the middle layer to serve as a surface layer of a composite coating; and in hypersalinity water, the coating can becorroded layer by layer, attachment of scales and corrosion products is difficult, and the characteristics of self-polishing, corrosion preventing and scale preventing are achieved.

Description

technical field [0001] The invention belongs to the technical field of oil and gas field corrosion and protection, and in particular relates to a self-polishing anti-corrosion and anti-scaling coating and a preparation method thereof, which are mainly used for anti-corrosion and anti-scaling of oil pipes, casing pipes or the inner or outer walls of surface pipelines. Background technique [0002] With the deepening of exploration and development of oil and gas fields, the environment faced by oil and gas extraction is getting worse and worse, especially the emergence of high salinity water, high carbon dioxide and hydrogen sulfide content, which makes the oil and gas field wellbore and ground corrosion and scaling problems Increasingly prominent, including occurring on the inner and outer walls of tubing, casing, and surface pipelines. Some pipelines or wellbores need to be inspected or pigged once in only one month of production, which has a great impact on production and h...

Claims

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Application Information

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IPC IPC(8): C23C4/131C23C4/134C23C4/06C23C4/18
CPCC23C4/06C23C4/131C23C4/134C23C4/18
Inventor 胥聪敏奚运涛陈文浩王文渊宋鹏迪高豪然陈月清
Owner XI'AN PETROLEUM UNIVERSITY
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