Visible light-responsive N, B co-doped In2O3/TiO2 precursor, and preparation method and application thereof

Abstract

The invention discloses a visible light-responsive N, B co-doped In2O3 / TiO2 precursor, and a preparation method and application thereof. In the In2O3 / TiO2 precursor, the N element accounts for 1-3% ofthe mass of the precursor, the B element accounts for 0.01-0.6% of the mass of the precursor, and a molar ratio of In to Ti is 0.001-0.03. The N, B co-doped In2O3 / TiO2 precursor can be dissolved in acommon solvent, so that the precursor can be loaded on substrates such as fibers, molecular sieves, silicon wafers, and glass wafers by simple impregnation, the substrate after loading is subjected to high-temperature roasting in air, and the precursor is converted into a N, B co-doped In2O3 / TiO2 photo-catalyst, and loaded on the substrate, so that the problem of catalyst recycling is solved, andthe problem that an ordinary TiO2 catalyst has no response to visible light is solved.

Description

technical field [0001] The invention belongs to the field of material science, in particular to a visible light responsive N, B co-doped In 2 o 3 / TiO 2 Precursors, their preparation methods and applications. Background technique [0002] Since the 20th century, with the continuous development and progress of science and technology, the global industry has achieved unprecedented development. However, while the development of industry is promoting economic development and bringing convenience to human life, it is also ruthlessly destroying the environment on which human beings live. The air pollution and water pollution brought about by industrial development have an impact on people's lives. has become increasingly apparent. As an advanced oxidation technology, the photocatalytic oxidation technology based on semiconductor catalysts has attracted increasing attention from scholars at home and abroad. Almost all organic compounds can be completely oxidized to CO by photo...

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Problems solved by technology

[0003] TiO 2 The photocatalytic properties of semiconductors have been confirmed by many researches, but there are two key problems to be solved in order to be practical: ① Traditional photocatalytic research is generally carried out in a suspended photocatalytic reaction system, where TiO 2 The powder is easy to agglomerate, and it is difficult to realize the continuous separation, recovery and regeneration of the catalyst; ②TiO 2 Photocatalytic oxidation can only be carried out in the limited wavelength range of ultraviolet light, and the proportion of utilizing sunlight is low, which limits the popularization and application of photocatalytic technology

However, the obtained catalyst exists in the form of powder, which is not conducive to the recycling of the catalyst. Even if it is recovered, it is easy to agglomerate when it is used for the second time after recovery, thereby reducing the photocatalytic performance and making the utilization rate of titanium dioxide per unit mass low.

[0006] In summary, the TiO prepared by the prior art 2 Photocatalysts generally exist in the form of powder, and the photocatalytic reaction is generally carried out in a suspended photocatalytic reaction system, which is difficult to settle and recover, and TiO 2 The powder is easy to agglomerate, and it is difficult to realize the continuous separation, recovery and recycling of the catalyst; there are also related studies on loading the powder, but there are generally problems of uneven loading and easy powder drop; moreover, ordinary TiO 2 The catalyst only responds to ultraviolet light, and the ultraviolet part of sunlight accounts for less than 5%, these problems severely limit the TiO 2 Practical application of photocatalyst

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