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Ionothermal synthesis method of hierarchical pore AlPO-34 molecular sieve

An ionothermal synthesis, alpo-34 technology, applied in the direction of molecular sieve characteristic aluminum phosphate, molecular sieve and base exchange phosphate, phosphorus compound, etc., can solve the problems of expensive organic templates, shorten the synthesis time, reduce energy consumption, reduce The effect of production costs

Inactive Publication Date: 2020-03-17
DALIAN UNIV OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The above reports have carried out a more detailed study on the adsorption performance and adsorption behavior of multi-level porous aluminum phosphate molecular sieves under different system pollutants, which proves that aluminum phosphate molecular sieves have great application potential in sewage treatment, but it is worth noting that the above-mentioned many The synthesis of hierarchical pore aluminum phosphate molecular sieve materials requires the use of relatively expensive organic templates or pore-forming agents
Moreover, most hierarchical porous aluminum phosphate molecular sieve adsorbents are usually prepared by hydrothermal synthesis in a relatively high self-boosting pressure autoclave, so it will bring non-negligible operational safety issues and equipment safety issues

Method used

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  • Ionothermal synthesis method of hierarchical pore AlPO-34 molecular sieve
  • Ionothermal synthesis method of hierarchical pore AlPO-34 molecular sieve
  • Ionothermal synthesis method of hierarchical pore AlPO-34 molecular sieve

Examples

Experimental program
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Effect test

Embodiment 1

[0034] Prepare the hierarchical porous AlPO-34 molecular sieve as follows:

[0035] (1) Dissolve aluminum isopropoxide, phosphoric acid, hydrofluoric acid, and cyclohexylamine in 1-butyl-3-methylimidazolium bromide ionic liquid in an oil bath, and the molar ratio is 2:2:3: 3:80, stir evenly until the solid is completely dissolved, then carry out the aging operation, the aging temperature is 50°C, the aging time is 120min, the stirring speed is 200rpm, and the AlPO-34 molecular sieve synthetic liquid is obtained;

[0036] (2) Pour the synthesis solution obtained in step (1) into a microwave reactor, and heat it with microwaves. The synthesis temperature is 150° C., and the synthesis time is 2 hours. After the synthesis is completed, the solid product is obtained by static centrifugation, and the solid product is repeatedly washed with ethanol until there is no ionic liquid;

[0037] (3) Dry the washed solid product obtained in step (2), place the dried solid in a muffle furnac...

Embodiment 2

[0041] By the same operation as in Example 1, only using phosphorous acid as the P source, the resulting hierarchically porous AlPO-34 zeolite molecular sieve is effective for Cr in sewage 3+ The adsorption rate is 98.9%, and the distribution coefficient is 1.67×10 4 mg / L.

Embodiment 3

[0043] The same operation as in Example 1 was carried out, except that the microwave reaction temperature was 180° C., and the synthesis time was 1 h. The prepared zeolite molecular sieve membrane was applied to the adsorption of heavy metal ions, and was applied to Cu in sewage 2+ The adsorption temperature is 25°C, the initial metal ion concentration is 800ppm, and the adsorption time is 30min. The absorption and extraction rate is 97.1%, and the distribution coefficient is 8.93×10 3 mg / L.

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Abstract

Belonging to the technical field of inorganic material adsorption, the invention discloses an ionothermal synthesis method of a hierarchical pore AlPO-34 molecular sieve. The AlPO-34 zeolite molecularsieve is directly prepared by ionothermal synthesis method. The molecular sieve prepared by the method is uniform in morphology and homogeneous in size, compared with the traditional hierarchical pore molecular sieve synthesis, an additional mesoporous template agent or complex post-treatment operation is not needed, the synthesis method is simple and efficient, and the synthesis steps are simple. The synthesized hierarchical pore AlPO-34 zeolite molecular sieve can be applied to separation of heavy metal ions, shows potential application possibility in the fields of environment and catalysis, and has important and wide application prospects.

Description

technical field [0001] The invention belongs to the technical field of inorganic material adsorption, relates to the synthesis and application of multi-level porous AlPO-34 molecular sieves, and provides a new ionothermal synthesis method for synthesizing multi-level porous AlPO-34 zeolite molecular sieve microspheres through ionic liquids. Background technique [0002] With the rapid development of contemporary industry, industrial wastewater discharged from industrial activities such as mining, textile, printing and dyeing affects the water safety of nearly 80% of the world's population. Therefore, how to deal with many heavy metal ions and organic dyes contained in sewage has become the key point in water treatment research. At present, the main methods of sewage treatment are chemical neutralization method, redox method, biological treatment method, physical adsorption method and so on. Among them, the physical adsorption method has attracted much attention due to its l...

Claims

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Application Information

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IPC IPC(8): C01B37/04C01B39/54
CPCC01B37/04C01B39/54C01P2002/72C01P2004/03
Inventor 王金渠李洪健周亮陶宇轩
Owner DALIAN UNIV OF TECH
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