A cationic metal complex iridium-benzophenanthroline crystal material and its preparation method and application
A technology of metal complexes and benzohydrophenanthroline, applied in luminescent materials, indium organic compounds, organic chemical methods, etc., to achieve good thermal stability and solubility, low transmittance, and reduce the degree of conjugation
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0037] (1) Iridium dichloro bridge compound [Ir(ppz) 2 ( μ -Cl) 2 ] 2 Synthesis:
[0038] Add 350 mg (1 mmol) of hydrated iridium trichloride, 0.288 mL (2.3 mmol) of 1-phenylpyrazole ligand, 24 mL of ethylene glycol ether and 8 mL of water to the reaction flask, under nitrogen protection at 135°C Condensation was refluxed for 24 hours, and the degree of reaction progress was monitored by TLC during the reaction. After the reaction was completed, the solution was cooled to room temperature and filtered with a small Buchner funnel. The resulting precipitate was washed with ethanol and petroleum ether to remove the reaction raw materials and by-products, followed by CH 2 Cl 2 and H 2O was extracted for further purification, and finally the organic phase was spin-dried to obtain 295 mg of pale yellow solid [Ir(ppz) 2 ( μ -Cl) 2 ] 2 (57.2%).
[0039] (2) Synthesis of auxiliary ligand 6,7-dihydrodibenzo-1,10-phenanthroline:
[0040] figure 1 A is the synthetic route o...
Embodiment 2
[0052] Step (1) and step (2) are the same as in Example 1, and other steps are as follows:
[0053] Step 3. Synthesis of iridium-benzophenanthroline:
[0054] In a 50 ml reaction flask, add 100 mg of 6,7-dihydrodibenzo-1,10-phenanthroline and 183 mg of iridium dimer, add 15 mL of dichloromethane and 10 mL of methanol, and finally add 70 mg potassium hexafluorophosphate, pass nitrogen into the bottle for 30 minutes for protection, in an oxygen-free environment protected from light, stir and reflux in an oil bath at 85 °C for 24 hours, add silica gel to the reaction solution and spin dry, and finally separate by column chromatography, spin dry, Iridium-benzophenanthroline was obtained as a solid (73 mg).
[0055] Step 4. Crystal room temperature diffusion culture of iridium-benzophenanthroline:
[0056] According to the ratio of metal iridium complex solid: dichloromethane: buffer layer: n-hexane = 1 mmol: 1 mL: 0.6 ml: 3 mL, the iridium-benzophenanthroline synthesized in step...
Embodiment 3
[0060] Step 1 and step 2 are the same as in embodiment 1, and other steps are as follows:
[0061] Step 3. Synthesis of iridium-benzophenanthroline:
[0062] In a 50 ml reaction flask, add 100 mg of 6,7-dihydrodibenzo-1,10-phenanthroline and 183 mg of iridium dimer, then add 10 mL of dichloromethane and 10 mL of methanol, and finally add 70 mg of hexamethylene Potassium fluorophosphate, pass nitrogen into the bottle for 30 minutes for protection, in an oxygen-free environment protected from light, stir and reflux in an oil bath at 85°C for 24 hours, add silica gel to the reaction solution and spin dry, and finally separate by column chromatography and spin dry to obtain 72 mg iridium-benzophenanthroline solid.
[0063] Step 4. Crystal room temperature diffusion culture of iridium-benzophenanthroline:
[0064] According to the ratio of metal iridium complex solid: dichloromethane: buffer layer: n-hexane = 1 mmol: 1 mL: 0.6 ml: 3 mL, the iridium-benzophenanthroline synthesized...
PUM
| Property | Measurement | Unit |
|---|---|---|
| transmittivity | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to view more - R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap