Environment-friendly ceramic and preparation method thereof
A ceramic and environmental protection technology, applied in the field of ceramics, can solve the problems of unsatisfactory antibacterial effect, unsatisfactory bactericidal effect, poor antibacterial effect, etc., and achieve excellent antibacterial effect, good air purification effect, and excellent antibacterial performance.
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[0038] Specifically, the preparation method of calcium phosphate-based nano ceramic material comprises the following steps:
[0039] S1. Calcining shell powder at 800-1000°C for 3-4 hours;
[0040] S2. Mix the powder obtained by calcining S1 with phosphoric acid and water evenly, put it into a ball mill after cooling down to room temperature, and then put the rare earth element inorganic compound into the ball mill, and ball mill for 0.5-2 hours;
[0041] S3. Add silver salt solution into the ball mill, ball mill for 0.5-2 hours, dry, then send into the ultra-fine ball mill for ball milling for 0.5-1 hour, and pass through a 200-mesh sieve.
[0042] Specifically, the weight percent content of the rare earth element in the composite phosphate material is 1.5-2.5 times the weight percent content of the silver element.
[0043] Specifically, the preparation method of the modified clay is: weigh bauxite and kaolin according to the mass ratio of 5-10:2-6, mix them evenly, add a st...
Embodiment 1
[0045] This embodiment provides a kind of environment-friendly ceramics, and the preparation method comprises the following steps:
[0046] (1) Raw material pretreatment:
[0047] Calcinate potassium feldspar and albite at 1100°C for 5 hours, cool to room temperature, grind, and pass through a 200-mesh sieve; calcinate medical stone and spinel at 900°C for 8 hours, cool to room temperature, grind, and pass through a 200-mesh sieve screen;
[0048] Modification of clay: Mix bauxite and kaolin evenly at a mass ratio of 7:3, add an appropriate amount of 2M hydrochloric acid to acidify, heat to 60°C, keep warm for 1.5 hours, filter, wash until neutral, dry, and dry at 500 Calcining at ℃ for 1.5 hours, passing through a 120-mesh sieve; taking chitosan in acetic acid solution, preparing a chitosan colloidal solution with a concentration of 15%, and then adding chitosan colloidal solution with a percentage content of 5% silver nitrate and 4% activated carbon , 2% nano-titanium diox...
Embodiment 2
[0056] This embodiment provides an environment-friendly ceramic, which is different from Example 1 in that the steps for preparing the environment-friendly ceramic are slightly different.
[0057] Step (2): Take 40 parts by weight of composite phosphate material, 30 parts by weight of modified clay, 8 parts by weight of potassium feldspar, 10 parts by weight of albite feldspar, 15 parts by weight of medical stone and 5 parts by weight of spinel as blanks Raw materials are put into a ball mill, adding appropriate amount of water, grinding for 20 hours, removing impurities, pressing mud, and refining mud;
[0058] Step (3): pressing the billet prepared in step (2), drying, bisque firing at 850° C. for 10 hours, and cooling to room temperature;
[0059] Step (4): glaze the product obtained by bisque firing, and send it to a kiln for firing at 1100° C. to obtain environmentally friendly ceramics.
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