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Treatment process and treatment device for high-concentration hydrogen sulfide gas

A gas treatment and hydrogen sulfide technology, applied in gas treatment, combined device, combustible gas purification, etc., can solve problems such as personal safety threats to staff, long production shutdown and recovery period, and secondary air pollution.

Pending Publication Date: 2020-06-16
河南中白环境科学技术研究院有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

h 2 S is a gas with a highly irritating and suffocating smell of rotten eggs. In industrial production, H 2 The existence of S gas will cause problems such as equipment and pipeline corrosion and catalyst poisoning, while H in the environment 2 S gas will pose a serious threat to the personal safety of staff
[0003] H in gas 2 Common treatment methods for S include: combustion method, adsorption method, liquid absorption method, oxidation method, electrochemical method, biological method and combined process purification method, among which liquid absorption method and biological method have become the main methods for hydrogen sulfide treatment at present, but The biological method has disadvantages such as poor operation stability, long shutdown and recovery period, and large floor area; while the liquid absorption method is mainly sprayed with alkali solution in a spray tower, which has insufficient purification accuracy and absorbs hydrogen sulfide volatilized from sulfide in the liquid. will cause secondary air pollution

Method used

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  • Treatment process and treatment device for high-concentration hydrogen sulfide gas
  • Treatment process and treatment device for high-concentration hydrogen sulfide gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] The hydrogen sulfide concentration in the hydrogen sulfide exhaust gas is 200ppm. After the gas is sprayed with 5% (mass fraction) hydrogen peroxide, the hydrogen sulfide concentration drops to 20ppm. The gas enters the ion exchange fiber purification unit after passing through the dust removal device.

[0071] The filter layer is purified by ion-exchange fibers whose surface functional groups are amine groups, and the air volume is controlled at 1000m 3 / h, the wind speed of gas passing through the purification filter layer is 5m / min. Within 25 minutes after the start of adsorption, the concentration of purified gas was detected to be 0ppm; turn on the regeneration solution spray pump, and spray 3% sodium carbonate solution for regeneration for 3 minutes; Add hydrogen peroxide, reflux and stir for 15 minutes; after repeating this 15 times, the concentration of purified gas remains at 0ppm after testing, and the concentration of hydrogen sulfide in the air above the sat...

Embodiment 2

[0074] The hydrogen sulfide concentration in the hydrogen sulfide waste gas is 500ppm. After the gas is sprayed with 20% (mass fraction) hydrogen peroxide, the hydrogen sulfide concentration drops to 70ppm. The gas enters the ion exchange fiber purification unit after passing through the dust removal device.

[0075] The filter layer is purified by ion-exchange fibers whose surface functional groups are amine groups, and the air volume is controlled at 500m 3 / h, the wind speed of gas passing through the purification filter layer is 2.5m / min. Within 20 minutes after the start of adsorption, the concentration of purified gas was detected to be 0ppm; turn on the regeneration solution spray pump, and spray 5% sodium hydroxide solution for regeneration for 1 minute; 1 Add hydrogen peroxide, reflux and stir for 15 minutes; after repeating this 15 times, the concentration of purified gas remains at 0ppm after testing, and the concentration of hydrogen sulfide in the air above the sa...

Embodiment 3

[0078] The hydrogen sulfide concentration in the hydrogen sulfide waste gas is 1000ppm. After the gas is sprayed with 10% (mass fraction) hydrogen peroxide, the hydrogen sulfide concentration drops to 50ppm. The gas enters the ion exchange fiber purification unit after passing through the dust removal device.

[0079] The filter layer is purified by ion-exchange fibers whose surface functional groups are amine groups, and the air volume is controlled at 100m 3 / h, the wind speed of gas passing through the purification filter layer is 0.5m / min. Within 30 minutes after the start of adsorption, the concentration of purified gas was detected to be 0 ppm; turn on the regeneration solution spray pump, and spray 0.5% sodium hydroxide solution for regeneration for 5 minutes; 1 Add hydrogen peroxide, reflux and stir for 20 minutes; after repeating this 15 times, the concentration of purified gas remains at 0ppm after testing, and the concentration of hydrogen sulfide in the air above t...

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Abstract

The invention provides a treatment process for high-concentration hydrogen sulfide gas which comprises the following steps: A) sequentially carrying out hydrogen peroxide spraying and dust removal onhydrogen sulfide waste gas to obtain dust-removed gas; with the concentration of hydrogen sulfide in the hydrogen sulfide waste gas being 100-1000 ppm; B) adsorbing the dedusted gas through purification equipment, discharging the gas, spraying a regeneration liquid to a purification filter layer saturated in adsorption for regeneration, and then performing the next round of adsorption, with the purification equipment comprising a plurality of purification filter layers, the purification filter layers being made of fibers or non-woven fabrics with basic functional groups on the surfaces, and the basic functional groups being one or more of amino groups, quaternary ammonium groups and pyridyl groups; and C) adding hydrogen peroxide into the sprayed regenerated liquid, and utilizing the regeneration liquid after reaction for the next round of spraying. The process can eliminate secondary pollution, protect the fiber structure of the purification filter layer from being damaged, and effectively prolong the service life of the purification filter layer. The invention also provides a treatment device for high-concentration hydrogen sulfide gas.

Description

technical field [0001] The invention belongs to the technical field of air pollution prevention and control, and in particular relates to a treatment process and a treatment device for high-concentration hydrogen sulfide gas. Background technique [0002] With the continuous improvement of people's requirements for living environment, the problem of stench caused by various odors has been widely concerned and valued by various countries. Odor pollution is a kind of sensory pollution. It not only stimulates people's sensory organs and makes people feel disgusted, but also some harmful substances such as hydrogen sulfide (H2S) contained in odor 2 S) etc. are directly harmful to human health, so odor pollution has been considered as one of the six major public hazards next to noise. h 2 S is a gas with a highly irritating and suffocating smell of rotten eggs. In industrial production, H 2 The existence of S gas will cause problems such as equipment and pipeline corrosion and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D47/06B01D53/78B01D50/00B01D53/52B01D53/04B01J20/34
CPCB01D47/06B01D53/78B01D53/52B01D53/04B01D53/0407B01J20/3425B01J20/3475B01D2257/304B01D50/60
Inventor 段文杰田振邦王民川李振峰赵亮贾俊俊黄做华黄伟庆赵可江王俊
Owner 河南中白环境科学技术研究院有限公司
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