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Anti-aging PC-ABS alloy material and preparation method thereof

A PC-ABS and alloy material technology, applied in the field of anti-aging PC-ABS alloy material and its preparation, can solve the problems of reducing the impact resistance of composite materials, reducing the durability of resin, increasing the thermal energy of resin, etc. The effect of reducing the amount of hydroxyl groups and increasing the crosslinking density

Pending Publication Date: 2020-07-03
东莞市高能高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polycarbonate (PC) is a tough thermoplastic resin, but it is not resistant to ultraviolet light and is easily exposed to external ultraviolet light, which increases the internal heat energy of the resin and reduces the strength of the resin from both light and heat. increased resin durability
Acrylonitrile-butadiene styrene copolymer (ABS) is a thermoplastic polymer material with high strength, good toughness and easy processing. It has excellent heat resistance and can improve the heat resistance of polycarbonate. performance, but the photoaging problem caused by its anti-ultraviolet radiation has not been solved. Therefore, in the anti-aging phenomenon of PC / ABS composite materials, it is basically to add ultraviolet absorbers and light stabilizers to the composite materials to solve the aging problem, but due to The dispersibility of UV absorbers and light stabilizers in the composite material system is low, making it necessary to add more UV absorbers and light stabilizers to play an anti-aging effect, but at the same time, the excessive addition of UV absorbers and light stabilizers It will reduce the impact resistance of the composite material and cause certain damage to the strength of the material.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:

[0043] PC resin 28 parts

[0044] ABS resin 55 parts

[0045] Anti-aging agent 3 parts

[0046] 10 parts epoxy acrylate resin

[0047] 1 part of ethyl 2,4,6-trimethylbenzoylphosphonate

[0048] Compatibilizer 3 parts

[0049] Toughener 3 parts

[0050] Filler 2 parts.

[0051] The PC resin is bisphenol A polycarbonate with a weight average molecular weight of 17000g / mol, specifically Hunan Petrochemical PC-1100; the weight average molecular weight of the ABS resin is 80000g / mol, specifically South Korea Kumho Petrochemical Co., Ltd. The ABSP / D150 of the company; the epoxy acrylate resin is novolac epoxy acrylate with an epoxy value of 0.54eq / 100g, specifically the 5327 model novolac epoxy acrylate of Tianjin Heinz Technology Development Co., Ltd.

[0052] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:

[00...

Embodiment 2

[0064] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:

[0065] PC resin 30 parts

[0066] ABS resin 58 parts

[0067] Anti-aging agent 3.5 parts

[0068] Epoxy acrylate resin 11 parts

[0069] 1.2 parts of ethyl 2,4,6-trimethylbenzoylphosphonate

[0070] Compatibilizer 4 parts

[0071] Toughener 4 parts

[0072] 3 servings of filler.

[0073] The PC resin is a bisphenol A polycarbonate with a weight average molecular weight of 20,000 g / mol, specifically L-1225Y produced by Teijin Chemical; Co., Ltd. ABS P / D190; the epoxy acrylate resin is novolac epoxy acrylate with an epoxy value of 0.52eq / 100g, specifically the 9760 model novolac epoxy acrylate of DSM DSM.

[0074] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:

[0075] Step A: Add the modifier to the mixed solvent, mix and disperse evenly, and then let it stand for 1.2 hours to prepare a modifier solution;

...

Embodiment 3

[0086] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:

[0087] PC resin 32 parts

[0088] ABS resin 60 parts

[0089] Anti-aging agent 4 parts

[0090] Epoxy acrylate resin 13 parts

[0091] 1.5 parts of ethyl 2,4,6-trimethylbenzoylphosphonate

[0092] Compatibilizer 5 parts

[0093] Toughener 5 parts

[0094] Filler 4 parts.

[0095] The PC resin is bisphenol A polycarbonate with a weight average molecular weight of 23000g / mol, specifically Dow PC-201-10; the weight average molecular weight of the ABS resin is 120000g / mol, specifically Takahashi Petrochemical ABS8391; the epoxy acrylate resin is a novolac epoxy acrylate with an epoxy value of 0.51eq / 100g, specifically the 9760 model novolac epoxy acrylate of DSM DSM.

[0096] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:

[0097] Step A: Add the modifier to the mixed solvent, mix and disperse evenly, and then ...

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Abstract

The invention relates to the technical field of modified materials, and concretely relates to an anti-aging PC-ABS alloy material and a preparation method thereof. The PC / ABS alloy material comprises,by weight, 28-35 parts of PC resin, 55-65 parts of ABS resin, 3-5 parts of an anti-aging agent, 10-15 parts of epoxy acrylate resin, 1-2 parts of 2,4,6-trimethylbenzoyl ethyl phosphonate, 3-8 parts of a compatilizer, 3-8 parts of a flexibilizer and 2-6 parts of a filler. The anti-aging PC-ABS alloy material disclosed by the invention is high in anti-aging performance, high in strength, high in impact resistance and excellent in comprehensive performances. The preparation method of the anti-aging PC-ABS alloy material is simple to operate, convenient to control, low in production cost and highin product quality, so that the prepared anti-aging PC-ABS alloy material is stable in performances, high in photo-thermal resistance and resistant to aging, and can be used for large-scale production.

Description

technical field [0001] The invention relates to the technical field of modified materials, in particular to an anti-aging PC-ABS alloy material and a preparation method thereof. Background technique [0002] Polycarbonate (PC) is a tough thermoplastic resin, but it is not resistant to ultraviolet light and is easily exposed to external ultraviolet light, which increases the internal heat energy of the resin and reduces the strength of the resin from both light and heat. the durability of the resin. Acrylonitrile-butadiene styrene copolymer (ABS) is a thermoplastic polymer material with high strength, good toughness and easy processing. It has excellent heat resistance and can improve the heat resistance of polycarbonate. performance, but the photoaging problem caused by its anti-ultraviolet radiation has not been solved. Therefore, in the anti-aging phenomenon of PC / ABS composite materials, it is basically to add ultraviolet absorbers and light stabilizers to the composite ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L69/00C08L63/10C08L51/06C08L51/00C08L23/08C08L53/02C08K13/06C08K9/06C08K7/26C08K7/20C08K5/375C08K5/132C08K5/5333C08K5/3492C08K3/36C08K3/26C08K3/34
CPCC08L55/02C08L2201/08C08L2205/025C08L2205/035C08K2003/265C08L69/00C08L63/10C08L51/06C08K13/06C08K9/06C08K7/26C08K7/20C08K5/375C08K5/132C08K5/5333C08K5/34926C08L51/003C08L23/0869C08K3/36C08L53/02C08K3/26C08K3/34
Inventor 刘光锋
Owner 东莞市高能高分子材料有限公司
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