Anti-aging PC-ABS alloy material and preparation method thereof
A PC-ABS and alloy material technology, applied in the field of anti-aging PC-ABS alloy material and its preparation, can solve the problems of reducing the impact resistance of composite materials, reducing the durability of resin, increasing the thermal energy of resin, etc. The effect of reducing the amount of hydroxyl groups and increasing the crosslinking density
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Embodiment 1
[0042] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:
[0043] PC resin 28 parts
[0044] ABS resin 55 parts
[0045] Anti-aging agent 3 parts
[0046] 10 parts epoxy acrylate resin
[0047] 1 part of ethyl 2,4,6-trimethylbenzoylphosphonate
[0048] Compatibilizer 3 parts
[0049] Toughener 3 parts
[0050] Filler 2 parts.
[0051] The PC resin is bisphenol A polycarbonate with a weight average molecular weight of 17000g / mol, specifically Hunan Petrochemical PC-1100; the weight average molecular weight of the ABS resin is 80000g / mol, specifically South Korea Kumho Petrochemical Co., Ltd. The ABSP / D150 of the company; the epoxy acrylate resin is novolac epoxy acrylate with an epoxy value of 0.54eq / 100g, specifically the 5327 model novolac epoxy acrylate of Tianjin Heinz Technology Development Co., Ltd.
[0052] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:
[00...
Embodiment 2
[0064] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:
[0065] PC resin 30 parts
[0066] ABS resin 58 parts
[0067] Anti-aging agent 3.5 parts
[0068] Epoxy acrylate resin 11 parts
[0069] 1.2 parts of ethyl 2,4,6-trimethylbenzoylphosphonate
[0070] Compatibilizer 4 parts
[0071] Toughener 4 parts
[0072] 3 servings of filler.
[0073] The PC resin is a bisphenol A polycarbonate with a weight average molecular weight of 20,000 g / mol, specifically L-1225Y produced by Teijin Chemical; Co., Ltd. ABS P / D190; the epoxy acrylate resin is novolac epoxy acrylate with an epoxy value of 0.52eq / 100g, specifically the 9760 model novolac epoxy acrylate of DSM DSM.
[0074] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:
[0075] Step A: Add the modifier to the mixed solvent, mix and disperse evenly, and then let it stand for 1.2 hours to prepare a modifier solution;
...
Embodiment 3
[0086] The anti-aging PC-ABS alloy material comprises the following raw materials in parts by weight:
[0087] PC resin 32 parts
[0088] ABS resin 60 parts
[0089] Anti-aging agent 4 parts
[0090] Epoxy acrylate resin 13 parts
[0091] 1.5 parts of ethyl 2,4,6-trimethylbenzoylphosphonate
[0092] Compatibilizer 5 parts
[0093] Toughener 5 parts
[0094] Filler 4 parts.
[0095] The PC resin is bisphenol A polycarbonate with a weight average molecular weight of 23000g / mol, specifically Dow PC-201-10; the weight average molecular weight of the ABS resin is 120000g / mol, specifically Takahashi Petrochemical ABS8391; the epoxy acrylate resin is a novolac epoxy acrylate with an epoxy value of 0.51eq / 100g, specifically the 9760 model novolac epoxy acrylate of DSM DSM.
[0096] Each part of the anti-aging agent is modified by nano-silica, and the specific steps include the following:
[0097] Step A: Add the modifier to the mixed solvent, mix and disperse evenly, and then ...
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