Lithium ferromanganese phosphate/carbon coated ternary material and preparation method thereof, lithium ion battery positive electrode and lithium ion battery

A lithium-ion battery and ternary material technology, applied in battery electrodes, positive electrodes, secondary batteries, etc., can solve the problems of difficult control of material phase purity, reduce side reactions in direct contact, low energy consumption, easy to use The effect of the operation

Active Publication Date: 2020-07-03
沁新集团(天津)新能源技术研究院有限公司
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  • Abstract
  • Description
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Problems solved by technology

[0004] The ternary material is (LiNi x co y mn 1-x-y o 2 ), due to the synergistic effect of the three metals, the performance of the material is better than that of any single metal oxide, and its stable cycle performance, high energy density and high capacity have attracted widespread attention, and the material has been identified as a hybrid electric vehicle One of the best candidates for the positive electrode material of th

Method used

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  • Lithium ferromanganese phosphate/carbon coated ternary material and preparation method thereof, lithium ion battery positive electrode and lithium ion battery
  • Lithium ferromanganese phosphate/carbon coated ternary material and preparation method thereof, lithium ion battery positive electrode and lithium ion battery
  • Lithium ferromanganese phosphate/carbon coated ternary material and preparation method thereof, lithium ion battery positive electrode and lithium ion battery

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[0054] Example 1

[0055] Preparation of LiMn by two-step solid phase method 0.6 Fe 0.4 PO 4 / C composite material, weigh 0.2molFe according to the stoichiometric ratio 2 O 3 , 0.2mol Mn 3 O 4 And 1mol LiH 2 PO 4 , And then weighed according to Fe 2 O 3 , Mn 3 O 4 , LiH 2 PO 4 2wt% of the theoretical mass of anhydrous glucose calculated by the number of moles, a certain amount of distilled water was sequentially added to the ball mill tank for wet ball milling for 2 hours, the ball milled slurry was spray-dried to obtain precursor 1, and the precursor 1 was placed in Precursor 2 was obtained by oxidizing at 420°C for 4 hours in an air atmosphere, and then the precursor 2 and the precursor 2 weight of 9wt% anhydrous glucose were wet ball milled and mixed for 2 hours. After spray drying, the precursor 3 was obtained. Finally, in a nitrogen atmosphere, Calcined at 700℃ for 4h, the heating rate is 10℃ / min, the final product LiMn is obtained 0.6 Fe 0.4 PO 4 / C Composite materials.

[00...

Example Embodiment

[0062] Example 2

[0063] Preparation of LiMn by two-step solid phase method 0.6 Fe 0.4 PO 4 / C composite material, weigh 0.2molFe according to the stoichiometric ratio 2 O 3 , 0.2mol Mn 3 O 4 And 1mol LiH 2 PO 4 , And then weighed according to Fe 2 O 3 , Mn 3 O 4 , LiH 2 PO 4 2wt% of the theoretical mass of anhydrous glucose calculated by the number of moles, a certain amount of distilled water was sequentially added to the ball mill tank for wet ball milling for 2 hours, the ball milled slurry was spray-dried to obtain precursor 1, and the precursor 1 was placed in Precursor 2 was obtained by oxidizing at 450°C for 4 hours in an air atmosphere. Then the precursor 2 and the precursor 2 weight 10wt% anhydrous glucose were wet ball milled and mixed for 2 hours. After spray drying, the precursor 3 was obtained, and finally in an argon atmosphere , Calcined at 720℃ for 4h, the heating rate is 10℃ / min, the final product LiMn 0.6 Fe 0.4 PO 4 / C Composite materials. The performance of ...

Example Embodiment

[0067] Example 3

[0068] Preparation of LiMn by two-step solid phase method 0.7 Fe 0.3 PO 4 / C composite material, weigh 0.35molFe according to the stoichiometric ratio 2 O 3 , 0.1mol Mn 3 O 4 And 1mol LiH 2 PO 4 , And then weighed according to Fe 2 O 3 , Mn 3 O 4 , LiH 2 PO 4 The theoretical mass of 5wt% anhydrous glucose calculated by the number of moles, a certain amount of distilled water was sequentially added to the ball mill tank for wet ball milling for 2 hours, the ball milled slurry was spray-dried to prepare precursor 1, and the precursor 1 was placed in Precursor 2 was obtained by oxidizing at 500°C for 2 hours in an air atmosphere, and then the precursor 2 was wet ball milled and mixed with 10wt% anhydrous glucose by weight of the precursor 2 for 2 hours, and spray-dried to obtain the precursor 3, and finally under a nitrogen atmosphere, Calcined at 730℃ for 4h, the heating rate is 10℃ / min, the final product LiMn is obtained 0.7 Fe 0.3 PO 4 / C Composite materials. T...

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Abstract

The invention discloses a lithium iron manganese phosphate/carbon-coated ternary material and a preparation method thereof, a lithium ion battery positive electrode and a lithium ion battery. The method comprises the following steps: 1) carrying out first ball milling on Fe2O3, Mn3O4, LiH2PO4 and a first organic carbon source, and carrying out first drying to obtain a precursor 1; 2) placing the precursor 1 in an air atmosphere, and carrying out heat treatment to obtain a precursor 2; 3) carrying out second ball milling on the precursor 2 and a second organic carbon source, and carrying out second drying to obtain a precursor 3; 4) sintering the precursor 3 at a constant temperature under the protection of an inert atmosphere to obtain a LiMn(1-x)FexPO4/C composite material; 5) dispersingthe LiMn(1-x)FexPO4/C composite material, a binder and a conductive agent in an oil solvent to prepare slurry, and 6) coating the surface of an electrode sheet prepared from a ternary material with the slurry, and drying The preparation method is simple and easy to operate, low in cost and excellent in product electrical property.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and specifically relates to a lithium manganese iron phosphate / carbon coated ternary material and a preparation method thereof, a positive electrode of a lithium ion battery and a lithium ion battery. Background technique [0002] Since the pioneering work done by Goodenough et al. on phosphate system cathode materials, people have conducted extensive research on lithium iron phosphate cathode materials and industrialized them. LiFePO 4 As a cathode material for lithium-ion batteries, it has received extensive attention due to its advantages such as high safety performance, good thermal stability, good electrochemical performance, abundant raw material reserves, and low cost. However, olivine-type LiFePO with a low voltage platform of 3.4V, poor electronic conductivity, and weak ion diffusion 4 The field of its application is limited. Although LiMnPO 4 with LiFePO 4 The structu...

Claims

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Application Information

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IPC IPC(8): H01M4/62H01M4/58H01M4/136H01M10/0525
CPCH01M4/136H01M4/5825H01M4/625H01M4/628H01M10/0525H01M2004/021H01M2004/028Y02E60/10
Inventor 王宏栋冯明燕
Owner 沁新集团(天津)新能源技术研究院有限公司
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