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Preparation method of modified polyacrylic resin and modified polyacrylic resin

A polyacrylic resin, modified technology, applied in the field of coatings, can solve problems such as mildew and bacterial growth

Inactive Publication Date: 2020-07-07
河南功能高分子膜材料创新中心有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional polyacrylate emulsion coatings are affected by environmental conditions during storage, transportation, and use, and mildew and bacterial growth often occur. It is imminent to research and develop leather coating materials with outstanding antibacterial properties and excellent hygienic performance.

Method used

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  • Preparation method of modified polyacrylic resin and modified polyacrylic resin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Prepare a modified polyacrylic acid resin:

[0021] Step 1: Prepare the solution

[0022] Acrylic acid, methyl acrylate, and Manuka essential oil were measured at a volume ratio of 1:10:5 and mixed with ultrasonic waves, and recorded as solution A;

[0023] Take by weighing ammonium persulfate, chitosan hydrochloride and be made into aqueous solution, wherein, the concentration of described ammonium persulfate is 20g / L, and the concentration of described chitosan hydrochloride is 30g / L, denoted as B 1 solution;

[0024] The preparation concentration is the sodium lauryl sulfate aqueous solution of 25g / L, denoted as B 2 solution;

[0025] Step 2: Mix nano-silver, nano-titanium dioxide, and n-butyl acrylate according to the weight ratio of 0.4:0.2:20 with ultrasonic waves, and record it as liquid C;

[0026] Step 3: First add 12 volume parts of C liquid into the reaction kettle, then add 6 volume parts of A solution and 15 volume parts of B 2 Solution, mix evenly; he...

Embodiment 2

[0028] Prepare a modified polyacrylic acid resin:

[0029] Step 1: Prepare the solution

[0030] Measure acrylic acid, methyl acrylate, and Manuka essential oil at a volume ratio of 1:10:10 and mix them with ultrasonic waves, and record it as solution A;

[0031] Take by weighing ammonium persulfate, chitosan hydrochloride and be made into aqueous solution, wherein, the concentration of described ammonium persulfate is 18g / L, and the concentration of described chitosan hydrochloride is 25 / L, denoted as B 1 solution;

[0032] The preparation concentration is the sodium lauryl sulfate aqueous solution of 22g / L, denoted as B 2 solution;

[0033] Step 2: Mix nano-silver, nano-titanium dioxide, and n-butyl acrylate according to the weight ratio of 0.4:0.3:25 with ultrasonic waves, and record it as liquid C;

[0034] Step 3: First add 12 volume parts of C liquid into the reaction kettle, then add 8 volume parts of A solution and 20 volume parts of B 2 solution, mix evenly; heat...

Embodiment 3

[0036] Prepare a modified polyacrylic acid resin:

[0037] Step 1: Prepare the solution

[0038] Acrylic acid, methyl acrylate, and Manuka essential oil were measured at a volume ratio of 1:15:5 and mixed with ultrasonic waves, and recorded as solution A;

[0039] Take by weighing ammonium persulfate, chitosan hydrochloride and be made into aqueous solution, wherein, the concentration of described ammonium persulfate is 25g / L, and the concentration of described chitosan hydrochloride is 35g / L, denoted as B 1 solution;

[0040] The preparation concentration is the sodium lauryl sulfate aqueous solution of 25g / L, denoted as B 2 solution;

[0041] Step 2: Mix nano-silver, nano-titanium dioxide, and n-butyl acrylate according to the weight ratio of 0.6:0.3:25 with ultrasonic waves, and record it as liquid C;

[0042] Step 3: First add 15 parts by volume of solution C to the reactor, then add 6 parts by volume of solution A and 15 parts by volume of B 2 Solution, mix evenly; h...

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PUM

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Abstract

The invention discloses a preparation method of modified polyacrylic resin. The preparation method comprises the following steps of preparing a solution A: uniformly mixing acrylic acid, methyl acrylate and manuka essential oil according to a volume ratio of 1: 10-15: 5-10, preparing a B1 solution from 18-25g / L of ammonium persulfate and 25-35g / L of chitosan hydrochloride, preparing 22-28g / L of lauryl sodium sulfate which is marked as a B2 solution, uniformly mixing nano-silver, nano-titanium dioxide and n-butyl acrylate according to a weight ratio of (0.4-0.6): (0.2-0.3): (20-25) to obtain asolution C, adding 12-15 parts by volume of the solution C into a reaction kettle, adding 6-8 parts by volume of the solution A and 15-20 parts by volume of the solution B2, and uniformly mixing, raising the temperature to 70 to 80 DEG C, stirring and dropwise adding 3-5 parts by volume of B1 solution, and heating to 80-85 DEG C, and keeping the temperature for 2-3 hours to obtain the modified polyacrylic resin. The invention further discloses the prepared modified polyacrylic resin. The modified polyacrylic resin is good in antibacterial property, high in elongation at break, high in tensilestrength and good in puncture resistance.

Description

technical field [0001] The invention belongs to the field of coatings, and in particular relates to a preparation method of a modified polyacrylic resin and the modified polyacrylic resin. Background technique [0002] Leather is denatured and non-perishable animal skin obtained through physical and chemical processing such as depilation and tanning. At present, the most used leather products are daily necessities such as leather shoes, leather clothes, and leather sofas. People often use leather coating to form a film on the leather surface to protect the fur. Polyacrylate emulsion has the characteristics of flexible and elastic film-forming, light resistance, aging resistance, and excellent wet rub resistance of the coating. It is a kind of leather textile coating material widely used at present. However, traditional polyacrylate emulsion coatings are affected by environmental conditions during storage, transportation, and use, and mildew and bacterial growth often occur...

Claims

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Application Information

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IPC IPC(8): C09D133/08C09D5/14C09D7/65C08F220/18C08F220/14C08F220/06C08F2/44
CPCC08F2/44C08F220/18C08K2003/0806C08K2003/2241C08K2201/011C08L2205/03C09D5/14C09D133/064C09D7/65C08L91/00C08L5/08C08K3/08C08K3/22
Inventor 李勇敢杨武涛郝自娟杜俊鹏袁永浩
Owner 河南功能高分子膜材料创新中心有限公司