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Labeling adhesive for glass bottles and preparation method thereof

A technology for labeling glue and glass bottles, which is applied in the field of labeling glue, can solve the problems of polyvinyl alcohol starch glue warping and sticking, bad problems, etc., and achieve the effect of accelerating drying time, fast drying time, and enhancing viscosity

Active Publication Date: 2021-08-03
中山金诚粘合剂有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] When using the above glues for labeling on glass bottles, if it runs on a slow labeling machine, it performs well, but if it is applied to a fast labeling machine, there will be some defects, for example: There will be a lot of drawing when running on the standard machine, and the polyvinyl alcohol starch glue will have poor adhesion such as warping caused by too slow drying time

Method used

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  • Labeling adhesive for glass bottles and preparation method thereof
  • Labeling adhesive for glass bottles and preparation method thereof
  • Labeling adhesive for glass bottles and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0081] This embodiment provides a kind of labeling glue for glass bottles, in parts by weight, its preparation raw materials are as follows:

[0082]

[0083]

[0084] Wherein, the preparation method of polyvinyl alcohol aqueous solution is as follows:

[0085] Add 85 parts of tap water to the reaction kettle, then add 0.1 part of antifoaming agent Rhodia 691, and then add 15 parts of polyvinyl alcohol 1788, stir evenly, heat to 95°C, keep warm and dissolve for half an hour to obtain polyethylene Alcoholic solution.

[0086] The preparation method of synthetic emulsion is as follows:

[0087] (1) Preparation of pre-emulsion: Dilute 0.618 parts of emulsifier nonylphenol polyoxyethylene ether NP10 with 1.11 parts of water in the pre-emulsification pot, then add 0.069 parts of ammonia water to adjust the pH value to 3-4, stir for 10 minutes, add 20.8 Part of butyl acrylate and 23.1 parts of styrene, stirred for 30 minutes to make pre-emulsion;

[0088] (2) Polymerization...

Embodiment 2

[0093] This embodiment provides a kind of labeling glue for glass bottles, in parts by weight, its preparation raw materials are as follows:

[0094]

[0095] Wherein, the preparation method of polyvinyl alcohol aqueous solution is as follows:

[0096] Add 85 parts of tap water into the reaction kettle, then add 0.1 part of antifoaming agent (Rhodia 691), then add 15 parts of polyvinyl alcohol 1788, stir evenly, heat to 95°C, keep warm and dissolve for half an hour, and obtain polyvinyl alcohol solution.

[0097] The preparation method of synthetic emulsion is as follows:

[0098] (1) Preparation of pre-emulsion: Dilute 0.618 parts of emulsifier nonylphenol polyoxyethylene ether NP10 with 1.11 parts of water in the pre-emulsification pot, then add 0.069 parts of ammonia water to adjust the pH value to 3-4, stir for 10 minutes, add 20.8 Part of butyl acrylate and 23.1 parts of styrene, stirred for 30 minutes to make pre-emulsion;

[0099] (2) Polymerization reaction: Add ...

Embodiment 3

[0104] This embodiment provides a kind of labeling glue for glass bottles, in parts by weight, its preparation raw materials are as follows:

[0105]

[0106] Wherein, the preparation method of polyvinyl alcohol aqueous solution is as follows:

[0107] Add 85 parts of tap water to the reaction kettle, then add 0.1 part of antifoaming agent Rhodia 691, and then add 15 parts of polyvinyl alcohol 1788, stir evenly, heat to 95°C, keep warm and dissolve for half an hour to obtain polyethylene Alcoholic solution.

[0108] The preparation method of synthetic emulsion is as follows:

[0109] (1) Preparation of pre-emulsion: dilute 0.618 parts of emulsifier nonylphenol polyoxyethylene ether NP10 with 1.11 parts of water in the pre-emulsification pot, then add 0.069 parts of 25% ammonia water to adjust the pH value to 3-4, and stir for 10 minutes , add 20.8 parts of butyl acrylate and 23.1 parts of styrene, and stir for 30 minutes to make a pre-emulsion;

[0110] (2) Polymerizatio...

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Abstract

The invention relates to a labeling glue for glass bottles and a preparation method thereof. In parts by weight, the labeling glue is prepared from raw materials comprising the following components: 10-20 parts of casein, 45-65 parts of polyvinyl alcohol aqueous solution, 3-9 parts of synthetic emulsion, 1-6 parts of starch, 10 parts of water -20 parts, 0.2-0.8 parts of ammonia water, 0.05-0.8 parts of defoamer, 0.01-0.5 parts of adhesion promoter; the mass percentage of polyvinyl alcohol in the polyvinyl alcohol aqueous solution is 10-30%; the synthetic emulsion Prepared from raw materials including the following components: polymerized monomers, emulsifiers, water, pH regulators, buffers, initiators, alkalis; the polymerized monomers are selected from butyl acrylate, styrene, methyl methacrylate At least one of ester, hydroxyethyl acrylate and N-methylol acrylamide. It also has a good labeling effect when it is used for quick labeling of glass bottles. The labeling process does not draw, the drying time is fast, and the corners are not warped.

Description

technical field [0001] The invention relates to the field of labeling glue, in particular to a labeling glue for glass bottles and a preparation method thereof. Background technique [0002] The labeling glues used for soy sauce bottles and similar glass bottles mainly include casein glue and polyvinyl alcohol starch glue. Casein glue is also called casein glue or casein glue. The main components of polyvinyl alcohol / starch adhesive are polyvinyl alcohol and starch. The adhesive has a simple process, low cost, moderate viscosity, good mechanical properties, high strength, degradable products, no pollution, and strong practicability. . [0003] When using the above glues for labeling on glass bottles, if they run on a slow labeling machine, they perform well, but if they are applied to a fast labeling machine, there will be some defects, for example: There will be a lot of drawing when running on the standard machine, and the polyvinyl alcohol starch glue will have poor bo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J189/00C09J11/08C09J129/04C09J125/14C09J103/04C08F212/08C08F220/18C08F220/14C08F220/28C08F220/58C08F2/30
CPCC08F212/08C09J11/08C09J189/005C08L29/04C08L25/14C08L3/04C08F2/30
Inventor 伍中平赵晓云罗荣
Owner 中山金诚粘合剂有限公司
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