Perdeuterated ammonium dinitramide and preparation method thereof
A technology of ammonium dinitramide and deuterated nitric acid is applied in the synthesis field of deuterated energetic materials, which can solve the problems of catalyst poisoning and deactivation, cumbersome operation process, increasing preparation difficulty, etc., and achieves reduction of production cost, simple purification, The effect of increasing the scope of application
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0018] Place a three-port pressure-resistant device with a volume of 250mL and 39.9g of phosphoric anhydride in a high-precision low-temperature circulating bath at -40°C, and drop 62.7g of phosphoric anhydride at a rate of 5mL / min through a constant pressure dropping funnel. 95% deuterated nitric acid, start stirring at a rate of 150rpm after the dropwise addition, and slowly add 13.3g of deuterated sodium sulfamate to the above solution in batches after the phosphoric anhydride is completely dissolved, and keep the temperature of the mixed solution not higher than -30°C; After the sodium deuterated sulfamate is completely dissolved, seal the reaction device, raise the temperature of the solution to -10°C, keep stirring for 0.5 hours to obtain solution B;
[0019] Place a three-port pressure-resistant device with a volume of 500mL and 12.3g of deuterated N-hydroxyacetamidine in a high-precision medium-temperature circulating bath at 15°C, slowly add 125.8g of deionized water t...
Embodiment 2
[0024] Place a three-port pressure-resistant device with a volume of 500mL and 101.4g of phosphoric anhydride in a high-precision low-temperature circulating bath at -40°C, and drop 147.4g of phosphoric anhydride at a rate of 7mL / min through a constant pressure dropping funnel. 95% deuterated nitric acid, start stirring at a rate of 150rpm after the dropwise addition, and slowly add 26.3g of deuterated lithium sulfamate to the above solution in batches after the phosphoric anhydride is completely dissolved, and keep the temperature of the mixed solution not higher than -30°C; After the lithium deuterated sulfamate is completely dissolved, seal the reaction device, raise the temperature of the solution to -12°C, and keep stirring for 40 minutes to obtain solution B;
[0025]Place a three-port pressure-resistant device with a volume of 1L and 34.0g of deuterated N-hydroxyacetamidine in a high-precision medium-temperature circulating bath at 15°C, slowly add 381.2g of deionized wa...
Embodiment 3
[0030] Place a three-port pressure-resistant device with a volume of 500mL and 139.6g of phosphoric anhydride in a high-precision low-temperature circulating bath at -38°C, and drop 308.4g of phosphoric anhydride at a rate of 10mL / min through a constant pressure dropping funnel. 96% deuterated nitric acid, start stirring at a rate of 200rpm after the dropwise addition, and slowly add 44.8g of deuterated sodium sulfamate to the above solution in batches after the phosphoric anhydride is completely dissolved, keeping the temperature of the mixed solution not higher than -30°C; After the sodium deuterated sulfamate is completely dissolved, seal the reaction device, raise the temperature of the solution to -15°C, and keep stirring for 45 minutes to obtain solution B;
[0031] Place a three-port pressure-resistant device with a volume of 2L and 59.3g of deuterated N-hydroxyacetamidine in a high-precision medium-temperature circulating bath at 10°C, slowly add 734.8g of deionized wat...
PUM
Property | Measurement | Unit |
---|---|---|
Crystal density | aaaaa | aaaaa |
Crystal density | aaaaa | aaaaa |
Crystal density | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com