24 results about "Ammonium dinitramide" patented technology

The invention discloses a fuel gas rock cracking agent and a preparation method thereof, and belongs to the technical field of gunpowder. In order to solve the technical problems of danger in reprocessing of propellant powder, low utilization rate, environmental pollution and the like, the invention provides a gas rock cracking agent which comprises the following components: 25-75% of main charge, 20-70% of performance regulator and 2-5% of curing agent, the main charge is at least one of single-base propellant powder, double-base propellant powder or three-base propellant powder, the performance regulator is at least one of ammonium nitrate, potassium nitrate, sodium nitrate and ammonium dinitramide, and the curing agent is nitrocotton. The gas rock cracking agent is stable and free of overall explosion hazard, has the characteristics of low vibration, controllable flying rocks, clean products and the like when being used for rock cracking, and can well meet rock cracking operation under sensitive environments and various special working conditions; by adopting a wet mixing process, the fire blast risk caused by friction and static electricity in the mixing process of the propellant powder and the performance regulator can be effectively reduced.

The invention relates to the technical field of ammonium dinitramide preparation methods, in particular to an ammonium dinitramide coating material and a preparation method and application thereof.The preparation method comprises the following steps that under the protective atmosphere, an acetic acid solution, trialdehyde phloroglucinol, ammonium dinitramide and an amino compound are mixed and subjected to a Schiff base reaction, and an intermediate material is obtained; and depositing a fluorocarbon on the surface of the intermediate material to prepare the ammonium dinitramide coated material. According to the invention, trialdehyde phloroglucinol reacts with an amino compound to generate an interlinked interlayer microporous material (COFs framework material), and the interlinked interlayer microporous material has good compatibility with strong-polarity ammonium dinitramide and a non-polar fluorocarbon compound, so that transition of ammonium dinitramide (strong-polarity)-microporous material (moderate-polarity)-fluorocarbon (non-polarity) is formed; the abrupt change of interfacial tension when the surface of ammonium dinitramide is directly coated with the fluorocarbon is relieved.

The invention relates to the technical field of solid propellants, in particular to an integrated coating material based on moisture absorption prevention and synergistic energy release as well as a preparation method and application of the integrated coating material. The ternary core-shell structure sequentially comprises an ammonium dinitramide core, an energy-containing covalent organic framework middle layer and a polytetrafluoroethylene nano-film outer layer from inside to outside, and the energy-containing covalent organic framework middle layer is combined with the surface of the ammonium dinitramide core through hydrogen bonds or p-pi conjugation; and the polytetrafluoroethylene nano-film outer layer coats the outer side of the energetic covalent organic framework middle layer in a continuous nano-scale film form. The problems that in the prior art, ADN is high in hygroscopicity and energy-containing characteristics are reduced due to a traditional coating technology are solved, long-term moisture absorption prevention of ADN is achieved, the long-term stability is improved, and meanwhile the combustion performance of ADN is improved.

The invention discloses an application of 3-aminopropyltriethoxysilane modified graphene oxide in reduction of ADN (adenosine diphosphate) sensitivity and an application of the 3-aminopropyltriethoxysilane modified graphene oxide in reduction of ADN sensitivity. According to the invention, the 3-aminopropyltriethoxysilane modified graphene oxide is used, so that the impact sensitivity of ammonium dinitramide is reduced, the decomposition of ADN is promoted, and the thermal decomposition performance is improved. The further prepared compound not only can reduce the impact sensitivity and friction sensitivity of the ADN, but also can promote decomposition of the ADN and improve the mass loss of the ADN.

The invention provides an SH-SiGO / ADN / GAP-ETPE compound as well as a preparation method and application thereof. The compound is prepared from sulfydryl silicon functionalized graphene oxide, ammonium dinitramide and a glycidyl azide polymer based energetic thermoplastic elastomer through a solvent evaporation method. The average molecular weight of the glycidyl azide polymer based energy-containing thermoplastic elastomer is 20000 to 30000; the mass ratio of the sulfydryl silicon functionalized graphene oxide to the ammonium dinitramide to the glycidyl azide polymer based energy-containing thermoplastic elastomer is 1: (4-8): (90-190). According to the prepared SH-SiGO / ADN / GAP-ETPE compound, the explosion heat and the combustion heat of original GAP-ETPE can be improved, the explosion heat is improved by 63.1 J / g-470.2 J / g, the combustion heat is improved by 1060.0 J / g-2155.7 J / g, the impact sensitivity of the GAP-ETPE can be reduced, and the impact sensitivity is reduced from 9J to 51 J-76J.

The application provides a kind of ammonium dinitramide-based liquid propellant combustion simulation data labeling method and system based on digital twinning, by collating and refining the combustion physical law of ammonium dinitramide-based liquid propellant in different combustion environments and multi-batch historical labeling data, a labeling correlation map is constructed, the newly generated combustion simulation data by the digital twinning system through iteration simulation is compared with the labeling correlation map, the coverable combustion state description items are extracted and the corresponding labeling labels are reused, the new combustion state description items not matched to the labeling correlation map are separated synchronously, the newly added labeling labels are labeled pertinently, the combustion state description item-labeling label correlation corresponding record of the labeling correlation map is updated, the adaptability of all combustion simulation historical labeling data generated in the early stage is calibrated, the original labeling label content is updated, and the combustion simulation data labeling benchmark library of the digital twinning system is updated synchronously. The application can improve the fit of simulation and labeling.

The invention discloses an application of graphene oxide in reducing the sensitivity of ammonium dinitramide, the graphene oxide is used as a raw material, the impact sensitivity and friction sensitivity of ADN (ammonium dinitramide) are reduced through reasonable process treatment, and the thermal stability and thermal decomposition performance of the ADN are also improved. Furthermore, the prepared graphene oxide / ADN compound solid is of a blocky structure, corners are smooth, particles are small and uniform, the impact sensitivity and friction sensitivity of the ADN can be reduced through the compound, the thermal performance of the ADN can be improved, and the mass loss can be improved.

The invention discloses a modified ammonium dinitramide crystal and a preparation method thereof, the method comprises the following steps: step 1, adding a formula amount of melamine powder into ammonium dinitramide powder, and uniformly stirring to obtain mixed powder; step 2, adding the mixed powder into a granulation kettle filled with a dispersion medium, heating to the melting temperature of ammonium dinitramide, and stirring until the mixed powder is molten and dispersed in the dispersion medium; and step 3, stirring at a set stirring speed, and carrying out cooling crystallization to obtain the modified ammonium dinitramide crystal. According to the method, melamine is added into ammonium dinitramide (ADN), the crystallization temperature of ADN is remarkably increased, the supercooling degree of ADN is inhibited, DSC tests show that the crystallization temperature of ADN is increased to 40 DEG C from 20.7 DEG C, the supercooling degree is effectively inhibited, and the stability of ADN crystallization is greatly improved.

The invention provides an NH-SiGO / ADN / GAP-ETPE compound as well as a preparation method and application thereof. The compound is prepared from amino silicon functionalized graphene oxide, ammonium dinitramide and a glycidyl azide polymer based energetic thermoplastic elastomer through a solvent evaporation method. The average molecular weight of the glycidyl azide polymer based energy-containing thermoplastic elastomer is 20000 to 30000; the mass ratio of the amino silicon functionalized graphene oxide to the ammonium dinitramide to the glycidyl azide polymer based energy-containing thermoplastic elastomer is 1: (3-7): (90-190). According to the prepared NH-SiGO / ADN / GAP-ETPE compound, the explosion heat and the combustion heat of original GAP-ETPE can be improved, the explosion heat is improved by 173.5 J / g-589.0 J / g, the combustion heat is improved by 757.9 J / g-1255.4 J / g, the impact sensitivity of the GAP-ETPE can be reduced, and the impact sensitivity is reduced to 68 J-100 J from 9 J.

The present invention relates to a temperature-controlled rapid extraction device and process for ammonium dinitramide, comprising a plurality of cylinders connected sequentially from top to bottom, each of which is provided with a temperature-controlled jacket on the outside. The upper side of the uppermost cylinder is connected to a pressure control line, a sample supply line, and a water supply line. Filter assemblies are provided between adjacent cylinders. A flange hemisphere is connected to the lower side of the lowermost cylinder, and a filter assembly is also provided between the lowermost cylinder and the flange hemisphere. An output line with a liquid outlet valve is provided on the lower side of the flange hemisphere. Each cylinder is filled with activated carbon. The device of the present invention has a simple structure, is easy to install and disassemble, and is easy to scale up. The extraction and elution processes are carried out under temperature and pressure control conditions, and activated carbon of different particle sizes can be used for filling as needed. The overall operation is simple, efficient, and fast, making it particularly suitable for the industrial production of ammonium dinitramide.

The invention discloses an ADN-based metal ion nitrogen-containing complex energetic material as well as a preparation method and application thereof. The preparation method comprises the following steps: uniformly mixing a solution containing a nitrogen-containing ligand and a mixed solution containing soluble metal salt and ammonium dinitramide, and standing to obtain the ADN-based metal ion nitrogen-containing complex energetic material. The ADN-based metal nitrogen-containing complex energetic material prepared by the invention has relatively high energy and moisture absorption resistance, and the preparation method is simple, low in cost and suitable for large-scale production.

The invention provides a continuous preparation method of an ammonium dinitramide ionic eutectic, which comprises the following steps: by taking ammonium dinitramide and a ligand as reactants, continuously preparing the ammonium dinitramide ionic eutectic by adopting a good solvent-poor solvent method, a good solvent-anti-solvent method and a cooling crystallization method. Wherein the continuous preparation is realized by adopting a micro-channel device. The preparation of the eutectic is combined with a micro-channel reaction technology, the defects that a traditional eutectic synthesis method is long in preparation period and cannot realize continuous preparation are overcome, the preparation of the narrow-particle-size-distribution ADN / ligand eutectic and the regulation and control of the ADN / ligand crystal morphology can be realized through different systems and preparation methods, and the finished product has high critical relative humidity and high specific surface area. The problem of moisture absorption of ADN can be effectively solved, and certain application potential is achieved in solid propellants.

The invention discloses a normal-temperature ultrasonic preparation method of spherical ammonium dinitramide, which comprises the following steps: adding ammonium dinitramide particles and an auxiliary agent into an organic solvent, and stirring for 10-30 minutes in a temperature range of 20-35 DEG C to obtain an ammonium dinitramide solution; putting the ammonium dinitramide solution into an ultrasonic instrument, and carrying out ultrasonic treatment for 5-15 minutes at set ultrasonic power and ultrasonic frequency; the preparation method comprises the following steps: under a stirring condition, dropwise adding an ammonium dinitramide solution into dichloromethane at a certain dropwise adding temperature, and after dropwise adding, filtering and drying to obtain the ammonium dinitramide. Wherein the mass ratio of the ammonium dinitramide to the organic solvent to the auxiliary agent to the dichloromethane is 1: (10-22) mL: (0.01-0.02) g: (80-100) mL. According to the method, normal-temperature ultrasonic crystallization is used for replacing melting granulation, operation is convenient, cost is low, operation is carried out at normal pressure, and large-scale production can be achieved. The melting temperature of the ammonium dinitramide provided by the invention is increased compared with that of the raw material ADN, the particle size of the spherical ADN is between 10 microns and 500 microns, the melting temperature is 89.2-92.30 DEG C, the sphericity is greater than or equal to 0.8, the impact sensitivity is 15.2-20.0 J, and the friction sensitivity is 74-81%.

The invention discloses an application of 3-mercaptopropyltriethoxysilane modified graphene oxide in reduction of AND (Intensity of Density) sensitivity and a preparation method of the 3-mercaptopropyltriethoxysilane modified graphene oxide. According to the invention, the 3-mercaptopropyltriethoxysilane modified graphene oxide is adopted, so that the impact sensitivity of ammonium dinitramide is reduced, the thermal stability of ADN is improved, and the thermal decomposition performance is improved. The further prepared compound not only can reduce the impact sensitivity and friction sensitivity of the ADN, but also can postpone the thermal decomposition temperature of the ADN and improve the mass loss.

This invention discloses a core-shell structured moisture-resistant ammonium dinitramide composite material, its preparation method, and its applications. The composite material uses ammonium dinitramide (ADN) as the core and methyl methacrylate-butyl acrylate copolymer (PMMA-BA) as the shell. A solvent-non-solvent method is used to precipitate and coat the PMMA-BA copolymer onto the ADN surface, resulting in the ADN@PMMA-BA core-shell structured composite material. This invention effectively shields the polar ionic sites on the ADN surface by constructing a dense hydrophobic polymer shell, significantly reducing its adsorption and permeation of water molecules. While maintaining the original thermal stability and energy performance of ADN, this material exhibits reduced moisture absorption and increased water contact angle, demonstrating excellent moisture-resistant properties. It is suitable for applications in humidity-sensitive explosives, propellants, and blasting agents, effectively extending the storage stability and safety of ADN-containing materials.

The application discloses a normal-temperature ultrasonic preparation method of spherical ammonium dinitramide, which comprises the following steps: adding ammonium dinitramide particles and an additive into an organic solvent, stirring for 10-30 minutes at a temperature of 20-35 DEG C to obtain an ammonium dinitramide solution; placing the ammonium dinitramide solution into an ultrasonic instrument, and ultrasonically treating for 5-15 minutes at a set ultrasonic power and frequency; and adding the ammonium dinitramide solution into dichloromethane at a certain dropping temperature under stirring, and obtaining the spherical ammonium dinitramide after filtration and drying; wherein the mass ratio of the ammonium dinitramide, the organic solvent, the additive and the dichloromethane is 1:10-22 mL:0.01-0.02 g:80-100 mL. The method of the application uses normal-temperature ultrasonic crystallization instead of melting granulation, and has the advantages of convenient operation, low cost, normal-pressure operation and large-scale production. The melting temperature of the ammonium dinitramide provided by the application is higher than that of raw material ADN, the particle size of the spherical ADN is between 10 mu m and 500 mu m, the melting temperature is 89.2-92.30 DEG C, the sphericity is greater than or equal to 0.8, the impact sensitivity is 15.2 J-20.0 J, and the friction sensitivity is 74%-81%.

The invention provides a dinitramide ammonium-based liquid propellant combustion simulation data labeling method and system based on digital twinning, and the method comprises the steps: constructing a labeling correlation map through combing and refining combustion physical rules and multi-batch historical labeling data of a dinitramide ammonium-based liquid propellant in different combustion environments; the method comprises the following steps: comparing new combustion simulation data generated by a digital twin system through iterative simulation with an annotation association map, extracting a covering combustion state description item and multiplexing a corresponding annotation label, synchronously separating a new combustion state description item which is not matched with the annotation association map, performing targeted annotation to obtain a newly added annotation label, and performing annotation on the newly added annotation label to obtain a new combustion state description item; and updating a combustion state description item-labeling label association corresponding record of the labeling association map, performing adaptive calibration on all combustion simulation historical labeling data generated in an early stage, updating original labeling label contents, and synchronously updating a combustion simulation data labeling reference library of the digital twin system. According to the method, the integrating degree of simulation and labeling can be improved.

The invention provides a dinitramide ammonium-based high-energy ion eutectic and a preparation method thereof, the eutectic is named as ADN / OHD eutectic and is composed of dinitramide ammonium and oxalyl dihydrazine, dinitramide ammonium molecules and oxalyl dihydrazine molecules are combined through intermolecular hydrogen bonds, and the dinitramide ammonium-based high-energy ion eutectic belongs to a monoclinic system and a P21 / c space group. Two strategies can be adopted for preparation: the first strategy is as follows: ammonium dinitramide and oxalyl dihydrazine are mixed in water, and the mixture is left to stand or stirred until eutectic crystals are separated out; and the second method comprises the following steps: mixing ammonium dinitramide and oxalyl dihydrazine, dropwise adding the solvent, and mechanically grinding until the solid becomes uniform white powder and the solvent is completely volatilized to obtain the ADN / OHD eutectic crystal. The critical relative humidity of the dinitramide ammonium-based high-energy ion eutectic prepared by the preparation method disclosed by the invention is as high as 70%; meanwhile, the eutectic crystal also has the characteristics of high specific impulse and high energy, the oxygen balance of the eutectic crystal based on CO is high (4.37%), and the theoretical specific impulse of the eutectic crystal is up to 251.28 N * S / kg through NASA software calculation. And the preparation method is simple, green and environment-friendly.

The application discloses application of graphene oxide in reducing sensitivity of ammonium dinitramide, and the graphene oxide is used as raw material, and through reasonable process treatment, impact sensitivity and friction sensitivity of ADN are reduced, thermal stability of ADN is improved, and thermal decomposition performance is improved. Further, the prepared graphene oxide / ADN composite solid has a block structure, edges and corners are relatively smooth, and particles are small and uniform, the composite can reduce impact sensitivity and friction sensitivity of ADN, and can improve thermal performance of ADN and improve mass loss.

The present invention discloses a core-shell ammonium dinitramide-based composite material and a preparation method thereof, including the following component mass ratios: 0.02 to 0.24 parts of the intermediate layer, 4 parts of the solvent, and 0.04 parts of ADN. By adopting the above-mentioned core-shell ammonium dinitramide-based composite material and the preparation method thereof, the saturated moisture absorption rate is extremely low, the surface coating layer is complete, the preparation method is simple, and mass production can be achieved.

The invention relates to the technical field of energetic materials and crystal engineering, in particular to a novel high-energy oxidant eutectic and a preparation method thereof. The co-crystal of the oxidizing agent is characterized in that the basic structure of the co-crystal of the oxidizing agent comprises an ammonium dinitramide molecule and a 3, 4-diamino furazan molecule; the moisture absorption resistance is excellent, the moisture absorption resistance is lower than 0.2% in the environment with the temperature of 25 DEG C and the relative humidity of 75.0%, the mechanical sensitivity is low, the impact sensitivity can reach 17 J, and the friction sensitivity can reach 288 N; the material has the characteristics of high specific impulse and high energy, meanwhile, the preparation method is simple and rapid, the material can be directly prepared by using water and ethanol as solvents and even can be directly obtained by a mechanical method without using any solvent, the preparation method is green and environment-friendly, different preparation, processing and application requirements can be met, and the material has great application potential in the field of energetic materials.

The invention discloses a green and clean ADN-based electric control gel propellant and a preparation method thereof, and belongs to the field of special liquid propellants. The electrically controlled gel propellant comprises: 65%-75% of an ADN solution; 10%-15% of ammonium nitrate; 10%-20% of fuel; 5%-10% of a gelling agent; and 0.2%-2% of a functional additive. According to the ADN-based electrogel propellant, ammonium dinitramide serves as a main oxidizing agent, and the propellant has the electrical excitation trigger ignition characteristic and has the advantages of being continuously adjustable in thrust and clean in combustion product. Through optimization of formula design and process innovation, the problems of high pollution, high toxicity, limited ignition technology, high maintenance difficulty and the like of a traditional propellant are solved, and the propellant can be applied to the technical field of space micro-propulsion of a spaceflight micro-propulsion system and the like.

The invention provides a GO / ADN / GAP-ETPE compound as well as a preparation method and application thereof. The compound is prepared from graphene oxide, ammonium dinitramide and a glycidyl azide polymer-based energetic thermoplastic elastomer through a solvent evaporation method. The average molecular weight of the glycidyl azide polymer based energy-containing thermoplastic elastomer is 20000 to 30000; the mass ratio of the graphene oxide to the ammonium dinitramide to the glycidyl azide polymer based energy-containing thermoplastic elastomer is 1: (3-8): (90-200). According to the GO / ADN / GAP-ETPE compound prepared by the invention, the explosion heat and the combustion heat of the original GAP-ETPE can be improved, the explosion heat is improved by 105.9 J / g-532.1 J / g, the combustion heat is improved by 297.9 J / g-354.7 J / g, and the impact sensitivity of the GAP-ETPE can be reduced from 9J to 36J-50J.

This invention provides an NH-SiGO / ADN / GAP-ETPE composite, its preparation method, and its application. The composite is prepared by solvent evaporation using amino-silicon functionalized graphene oxide, ammonium dinitramide, and poly(azide glycidyl ether) energetic thermoplastic elastomer. The average molecular weight of the poly(azide glycidyl ether) energetic thermoplastic elastomer is 20,000 to 30,000. The mass ratio of amino-silicon functionalized graphene oxide, ammonium dinitramide, and poly(azide glycidyl ether) energetic thermoplastic elastomer is 1:(3-7):(90-190). The NH-SiGO / ADN / GAP-ETPE composite prepared by this invention can improve the heat of explosion and heat of combustion of the original GAP-ETPE by 173.5 J / g to 589.0 J / g and the heat of combustion by 757.9 J / g to 1255.4 J / g. It can also reduce the impact sensitivity of GAP-ETPE from 9 J to 68 J to 100 J.