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A preparation method of an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method

An ozone catalytic oxidation and catalyst technology, which is applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc. It can achieve the effects of excellent catalytic activity, improved internal pore structure, and increased mechanical strength.

Active Publication Date: 2021-05-04
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] However, there are the following problems in the actual use of various catalysts: first, the low catalytic activity of the catalyst cannot meet the demand, and the use cost is high; secondary pollution; third, the continuous loss of catalyst active substances leads to a reduction in the catalytic efficiency and capacity of the catalyst, and the effective service life of the catalyst is greatly reduced

Method used

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  • A preparation method of an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method
  • A preparation method of an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method
  • A preparation method of an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method

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preparation example Construction

[0039]According to an aspect of the embodiments of the present invention, a method for preparing an ozone catalytic oxidation catalyst is provided, which specifically includes the following steps:

[0040] The shaped activated carbon carrier doped with graphene was pretreated by acid oxidation to prepare the shaped activated carbon carrier;

[0041] After fully and uniformly absorbing the mixed solution of zinc salt and cerium salt on the shaped activated carbon carrier, drying, microwave treatment and roasting are carried out to obtain an ozone catalytic oxidation catalyst loaded with multiple composite metal oxides.

[0042] Specifically, graphene is added in the kneading process before activated carbon extrusion molding, so that graphene is uniformly doped in activated carbon, and then kneaded and extruded to obtain a shaped activated carbon uniformly doped with graphene, wherein the graphene The mass fraction is 0.1-1%. The shaped activated carbon doped with graphene is i...

Embodiment 1

[0050] In the present embodiment, the preparation method of ozone catalytic oxidation catalyst comprises the following steps:

[0051] Configuration potassium nitrate mass fraction is 0.5%, and the mixed solution that nitric acid mass fraction is 10%;

[0052] Put the shaped activated carbon with a graphene mass fraction of 0.5% into the prepared mixed solution of potassium nitrate and nitric acid, and at the same time ultrasonically treat it for 60 minutes, take out the shaped activated carbon and dry it at 105°C for 6 hours to obtain the shaped activated carbon carrier; wherein, the shaped activated carbon Cylindrical particles with a diameter of 3mm and a length of 2cm, wherein the activated carbon is selected from coal-based activated carbon;

[0053] The shaped activated carbon carrier is uniformly impregnated in an appropriate amount of mixed solution of zinc and cerium metal ions by equal volume impregnation method; the molar ratio of Zn and Ce is 3:1, the total molar c...

Embodiment 2

[0056] In the present embodiment, the preparation method of ozone catalytic oxidation catalyst comprises the following steps:

[0057] Configuration potassium nitrate mass fraction is 0.1%, and the mixed solution that nitric acid mass fraction is 20%;

[0058] Put the shaped activated carbon with a graphene mass fraction of 0.1% into the prepared mixed solution of potassium nitrate and nitric acid, and at the same time ultrasonically treat it for 120 minutes, take out the shaped activated carbon and dry it at 105°C for 6 hours to obtain the shaped activated carbon carrier; wherein, the shaped activated carbon Cylindrical particles with a diameter of 5 mm and a length of 1 cm, wherein the activated carbon is selected from wood activated carbon;

[0059] The formed activated carbon carrier is uniformly impregnated in an appropriate amount of zinc-cerium metal ion mixed solution by excessive impregnation method, wherein the molar ratio of Zn and Ce is 1:2, the total molar concent...

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Abstract

The invention discloses a method for preparing an ozone catalytic oxidation catalyst and the catalyst prepared by the method. The preparation method comprises the following steps: pretreating a graphene-doped shaped activated carbon to prepare a shaped activated carbon carrier after acidic oxidation pretreatment; The shaped activated carbon carrier fully and uniformly absorbs the mixed solution of the zinc salt and the cerium salt, and then is dried, treated with microwaves, and roasted to obtain an ozone catalytic oxidation catalyst loaded with multiple composite metal oxides. The catalyst prepared by the method of the present invention has high catalytic activity, the active component and the carrier are firmly combined, and the added graphene can provide more macropores and a rich pore size distribution, and at the same time, it can strengthen the riveting of the formed activated carbon carrier and the transition metal oxide. Combined, reducing seepage, the catalytic activity of the catalyst always maintains high stability in the case of treating wastewater for a long time, the removal rate of organic matter and the effective service life of the catalyst are significantly improved, the preparation process is simple, the raw materials are wide, and the cost is appropriate, which is suitable for industrial production and application.

Description

technical field [0001] The invention belongs to the technical field of wastewater treatment, and in particular relates to a method for preparing an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method. Background technique [0002] While the society is flourishing, the problem of environmental pollution has attracted more and more attention. Among them, the problem of domestic sewage and industrial wastewater treatment needs to be solved urgently. A large amount of toxic and harmful organic substances exist in the sewage system. human living space. At present, the effective removal of organic pollutants in water has become a hot research direction in the field of water treatment. [0003] In the field of water treatment, ozone itself has strong oxidizing properties and can react with some organic matter to disinfect, decolorize, and deodorize sewage. However, the cost of ozone generation is relatively high and a single ozone o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/10C02F1/78C02F1/72C02F101/30
CPCB01J23/002B01J23/10C02F1/725C02F1/78C02F2101/30
Inventor 朱吉钦周栋波易珊孟启宇
Owner BEIJING UNIV OF CHEM TECH
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