A preparation method of an ozone catalytic oxidation catalyst and an ozone catalytic oxidation catalyst prepared by the method
An ozone catalytic oxidation and catalyst technology, which is applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc. It can achieve the effects of excellent catalytic activity, improved internal pore structure, and increased mechanical strength.
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[0039]According to an aspect of the embodiments of the present invention, a method for preparing an ozone catalytic oxidation catalyst is provided, which specifically includes the following steps:
[0040] The shaped activated carbon carrier doped with graphene was pretreated by acid oxidation to prepare the shaped activated carbon carrier;
[0041] After fully and uniformly absorbing the mixed solution of zinc salt and cerium salt on the shaped activated carbon carrier, drying, microwave treatment and roasting are carried out to obtain an ozone catalytic oxidation catalyst loaded with multiple composite metal oxides.
[0042] Specifically, graphene is added in the kneading process before activated carbon extrusion molding, so that graphene is uniformly doped in activated carbon, and then kneaded and extruded to obtain a shaped activated carbon uniformly doped with graphene, wherein the graphene The mass fraction is 0.1-1%. The shaped activated carbon doped with graphene is i...
Embodiment 1
[0050] In the present embodiment, the preparation method of ozone catalytic oxidation catalyst comprises the following steps:
[0051] Configuration potassium nitrate mass fraction is 0.5%, and the mixed solution that nitric acid mass fraction is 10%;
[0052] Put the shaped activated carbon with a graphene mass fraction of 0.5% into the prepared mixed solution of potassium nitrate and nitric acid, and at the same time ultrasonically treat it for 60 minutes, take out the shaped activated carbon and dry it at 105°C for 6 hours to obtain the shaped activated carbon carrier; wherein, the shaped activated carbon Cylindrical particles with a diameter of 3mm and a length of 2cm, wherein the activated carbon is selected from coal-based activated carbon;
[0053] The shaped activated carbon carrier is uniformly impregnated in an appropriate amount of mixed solution of zinc and cerium metal ions by equal volume impregnation method; the molar ratio of Zn and Ce is 3:1, the total molar c...
Embodiment 2
[0056] In the present embodiment, the preparation method of ozone catalytic oxidation catalyst comprises the following steps:
[0057] Configuration potassium nitrate mass fraction is 0.1%, and the mixed solution that nitric acid mass fraction is 20%;
[0058] Put the shaped activated carbon with a graphene mass fraction of 0.1% into the prepared mixed solution of potassium nitrate and nitric acid, and at the same time ultrasonically treat it for 120 minutes, take out the shaped activated carbon and dry it at 105°C for 6 hours to obtain the shaped activated carbon carrier; wherein, the shaped activated carbon Cylindrical particles with a diameter of 5 mm and a length of 1 cm, wherein the activated carbon is selected from wood activated carbon;
[0059] The formed activated carbon carrier is uniformly impregnated in an appropriate amount of zinc-cerium metal ion mixed solution by excessive impregnation method, wherein the molar ratio of Zn and Ce is 1:2, the total molar concent...
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