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Texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of silicon wafer and texturing method

A technology of additives and silicon wafers, which is applied in chemical instruments and methods, crystal growth, single crystal growth, etc., can solve the problems that the texturing liquid cannot be handled, and achieve the conversion of easy hydrophilicity and hydrophobicity, simple operation process, and meet the processing needs. Effect

Inactive Publication Date: 2020-11-03
杭州聚力氢能科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at the shortcoming that the texturing liquid in the prior art cannot handle the hydrophilicity and hydrophobicity of silicon wafers according to the needs of processing and manufacturing, and provides a texturing additive and a texturing method that can regulate the hydrophilicity and hydrophobicity of silicon wafers. It is only necessary to add polyglycol methyl ether to the formula, so that the silicon wafer after texturing can reach a hydrophobic state after being pickled with hydrofluoric acid, and the hydrophilicity and hydrophobicity of the silicon wafer can be easily adjusted

Method used

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  • Texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of silicon wafer and texturing method
  • Texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of silicon wafer and texturing method
  • Texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of silicon wafer and texturing method

Examples

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Embodiment 1

[0032] Preparation of hydrophilic texturizing additives: Weigh the following substances by weight in order for ultrasonic dissolution: 0.05% sodium lignosulfonate, 0.0001% sodium methylene bis-naphthalenesulfonate and the rest of water;

[0033] Add the above-mentioned texturizing additive into 1.8% sodium hydroxide or potassium hydroxide solution, mix evenly at a temperature of 20°C, wherein the mass ratio of the texturing additive to the alkali solution is 1:100, and obtain the texturing liquid.

[0034] The method for making texture on the surface of monocrystalline silicon comprises the following steps:

[0035] Step 1: Pre-treat the monocrystalline silicon wafer. The pretreatment process is as follows: the first step, put the monocrystalline silicon wafer in absolute ethanol for 8 minutes, and clean it with deionized water; the second step, put the monocrystalline silicon wafer Put the wafer in propanol for 8 minutes and clean it with deionized water; in the third step, p...

Embodiment 1a

[0038] In Example 1a, the surface texturing temperature of monocrystalline silicon is 80° C., the texturing time is 1200 s, and other parameters are the same as in Example 1.

Embodiment 1b

[0040] In Example 1b, the texturing temperature on the surface of the monocrystalline silicon was 83° C., the texturing time was 900 s, and other parameters were the same as in Example 1.

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Abstract

The invention relates to the technical field of monocrystalline silicon wafer texturing agents, in particular to a texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of a silicon wafer and a texturing method. A texturing additive capable of regulating and controlling hydrophilicity and hydrophobicity of a silicon wafer comprises a hydrophilic formula and a hydrophobic formula, wherein the hydrophilic formula comprises the following components in percentage by weight: 0.05-0.1% of sodium lignin sulfonate, 0.0001-0.001% of sodium methylene bis-naphthalenesulfonate and the balance of water; the hydrophobic formula comprises the following components in percentage by weight: 0.05%-0.1% of sodium lignin sulfonate, 0.0001%-0.001% of sodium methylene bis-naphthalene sulfonate, 0.03-0.1% of polyethylene glycol monomethyl ether, and the balance of water. According to the texturing additive and the texturing method, the hydrophilicity and hydrophobicity ofthe silicon wafer can be effectively regulated and controlled as required, the textured silicon wafer can reach a hydrophobic state after being subjected to hydrofluoric acid pickling only by additionally adding polyethylene glycol monomethyl ether into a hydrophilic formula, the operation process is simple, the conversion of the hydrophilicity and hydrophobicity can be simply and conveniently realized, and different processing requirements are met.

Description

technical field [0001] The invention relates to the technical field of monocrystalline silicon wafer texturing agents, in particular to a texturing additive and a texturing method capable of regulating the hydrophilicity and hydrophobicity of silicon wafers. Background technique [0002] In nature, the content of silicon in the earth's crust is second only to oxygen, and it generally exists in the form of silicon dioxide or silicate; for elemental silicon, its chemical properties are not active, and at room temperature, except for reaction with F2 and HF strong alkali In addition, it does not react with other substances and is a good semiconductor material. [0003] With the rapid development of microelectronics technology, semiconductor silicon materials have been rapidly developed in the energy field due to their abundant resources and excellent characteristics. Texturing is an important process in the production of solar cells. Using the principle of anisotropic corrosio...

Claims

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Application Information

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IPC IPC(8): C30B33/10C30B29/06
CPCC30B29/06C30B33/10
Inventor 李然范云堂程寒松闫缓
Owner 杭州聚力氢能科技有限公司
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