Preparation method of sunshade net with self-cleaning function

A technology of self-cleaning and sunshade nets, which is applied in the direction of sunshade, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of low photocatalytic degradation rate and limit practical application, and achieve less process , easy to control, and mild reaction conditions

Active Publication Date: 2020-11-13
JIANGSU HUACHANG YARNS & FABRICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the band gap region of titanium dioxide is mainly in the ultraviolet region, resulting in a low photocatalytic degradation rate, which limits the practical application.

Method used

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  • Preparation method of sunshade net with self-cleaning function

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A method for preparing a sunshade net with self-cleaning function, comprising the following steps:

[0024] 1) To prepare a composite titanium dioxide photocatalyst, add zinc chloride to ethylene glycol until the solid is completely dissolved to form a solution, add sodium citrate and sodium acetate to the solution until the solid is completely dissolved to form a mixed solution, ethylene glycol and chlorine The volume molar ratio of zinc chloride is 2L: 1mol; copper sulfate is dissolved in ethylene glycol to make a 6mol / L solution, and silver nitrate is dissolved in ethylene glycol to make a 6mol / L solution; Diol and ethylene glycol dissolved in silver nitrate were added to the mixture, stirred evenly, and finally tetrabutyl titanate was added, and the temperature was raised to 200°C in a closed reaction kettle for 12 hours. After the reaction was completed, it was cooled to room temperature, and the solid product was separated. , washed once with ethanol and distilled...

Embodiment 2

[0028] A method for preparing a sunshade net with self-cleaning function, comprising the following steps:

[0029] 1) To prepare a composite titanium dioxide photocatalyst, add zinc sulfate to ethylene glycol until the solid is completely dissolved to form a solution, add sodium citrate and sodium acetate to the solution until the solid is completely dissolved to form a mixed solution, ethylene glycol and zinc sulfate The volume molar ratio is 2L:1mol; Dissolve copper chloride in ethylene glycol to make a 6mol / L solution, and dissolve silver nitrate in ethylene glycol to make a 6mol / L solution; Diol and ethylene glycol dissolved in silver nitrate are added to the mixture, stirred evenly, and finally tetrabutyl titanate is added, and the temperature is raised to 150°C in a closed reaction kettle for 16 hours. After the reaction is completed, it is cooled to room temperature and the solid product is separated. , washed once with ethanol and distilled water, and calcined at 400°C...

Embodiment 3

[0033] A method for preparing a sunshade net with self-cleaning function, comprising the following steps:

[0034] 1) To prepare a composite titanium dioxide photocatalyst, add zinc nitrate to ethylene glycol until the solid is completely dissolved to form a solution, add sodium citrate and sodium acetate to the solution until the solid is completely dissolved to form a mixed solution, ethylene glycol and zinc nitrate The volume molar ratio is 2L: 1mol; Copper nitrate is dissolved in ethylene glycol to make a 6mol / L solution, and silver nitrate is dissolved in ethylene glycol to make a 6mol / L solution; Copper nitrate dissolved in ethylene glycol and Ethylene glycol dissolved with silver nitrate was added to the mixture, stirred evenly, and finally tetrabutyl titanate was added, and the temperature was raised to 250°C in a closed reaction kettle for 8 hours. After the reaction was completed, it was cooled to room temperature, and the solid product was separated. Wash once with ...

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Abstract

The invention relates to the field of agricultural functional materials, and discloses a preparation method of a sunshade net with a self-cleaning function. The preparation method comprises the following steps: dissolving soluble zinc salt, sodium citrate, sodium acetate, soluble copper salt and silver nitrate in ethylene glycol to prepare a solution, adding a titanium source, keeping the temperature at 150-250 DEG C for 8-16 hours, cooling to the room temperature after the reaction is finished, separating out a solid product, washing, and calcining at 400-600 DEG C for 2-5 hours to obtain a composite titanium dioxide photocatalyst; wherein the molar ratio of the soluble zinc salt to the sodium citrate to the sodium acetate to the soluble copper salt to the silver nitrate to the titanium source is (10-20): (1-3): (25-40): (0.5-2): (0.5-2): (30-60); uniformly mixing polyethylene particles and the composite titanium dioxide photocatalyst according to a mass ratio of (100-200): 1, and adding the mixture into a wire drawing machine for wire drawing to obtain self-cleaning polymer fibers; and weaving the self-cleaning polymer fibers into the sunshade net with a self-cleaning function ina visible light area by a net weaving machine.

Description

technical field [0001] The invention belongs to the field of agricultural functional materials, and in particular relates to a method for preparing a sunshade net with self-cleaning function. Background technique [0002] Self-cleaning materials can achieve the purpose of saving energy and water. Therefore, the research and development of self-cleaning materials has attracted people's attention. At present, the self-cleaning of fabrics is mainly realized by two technologies: superhydrophobic surface and photocatalytic self-cleaning. Among them, the photocatalytic technology is to load materials with photocatalytic effect on the fabric to realize the self-cleaning of the fabric. Titanium dioxide, a commonly used photocatalyst, is widely used in the field of photocatalysis due to its good photocatalytic activity, non-toxicity, good biocompatibility and low price. However, the band gap region of titanium dioxide is mainly in the ultraviolet region, resulting in a low photoca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/89E04F10/02
CPCB01J35/004B01J23/002B01J23/8953E04F10/02B01J2523/00B01J2523/17B01J2523/27B01J2523/18B01J2523/47Y02A40/25
Inventor 李俊叶咏梅韩国志
Owner JIANGSU HUACHANG YARNS & FABRICS CO LTD
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