Liquid catalyst for room-temperature catalytic ozonolysis as well as preparation method and application thereof

A liquid catalyst, ozone decomposition technology, applied in the direction of catalyst activation/preparation, metal/metal oxide/metal hydroxide catalyst, physical/chemical process catalyst, etc., to achieve the effect of low cost, wide application range and simple process

Active Publication Date: 2020-11-17
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]Aiming at the deficiencies existing in the catalytic decomposition of ambient ozone by catalysts with conventional structures, our solution is to design and synthesize stable high-activity, high-specific surface metal oxide liquid catalysts, Through the atomization and spraying loading method, a uniformly dispersed and firm high-activity catalyst film is formed on the surface of a support with any structure, so that it is not limited by the form of the support, and the support with any shape and structure can be turned into a catalyst, making full use of the reaction space and effectively Improve the contact surface between ambient ozone and catalyst, improve catalytic efficiency, this is a new environmental ozone treatment program

Method used

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  • Liquid catalyst for room-temperature catalytic ozonolysis as well as preparation method and application thereof
  • Liquid catalyst for room-temperature catalytic ozonolysis as well as preparation method and application thereof
  • Liquid catalyst for room-temperature catalytic ozonolysis as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Mix 7.55g manganese sulfate with 1.46g EDTA, 2.75×10 -3 g sodium pyrophosphate plus 22.7mL water to form a solution, put it in a 70°C water bath and stir for 20min, add 37.8mL water and absolute ethanol mixture (volume ratio 1:1) after cooling and transfer to a crystallization kettle, place at 180°C Crystallize in an oven for 3 hours, and then carry out suction filtration after cooling to room temperature. Add 55mL of ethanol to the obtained solid to disperse, and obtain a concentration of 5×10 -2 g / mL manganese oxide room temperature ozonolysis liquid catalyst.

Embodiment 2

[0040] 6.30g manganese chloride, 10.10g ferric nitrate and 6.75g oxalic acid, 8.29×10 -2 g sodium tripolyphosphate plus 49.2mL water to form a solution, placed in a 90°C water bath and stirred for 30min, after cooling, added 164mL water and ethylene glycol mixture (volume ratio 1:1) and transferred to a crystallization kettle, placed at 120°C Crystallize in an oven for 8 hours, and after cooling to room temperature, carry out suction filtration, add 4140mL of water to the obtained solid to disperse, and obtain a concentration of 1×10 -3 g / mL ferromanganese binary composite oxide liquid catalyst for ozonolysis at room temperature.

Embodiment 3

[0042] 14.32g manganese nitrate, 8.08g ferric nitrate, 1.09g cerium nitrate and 12.0g citric acid, 7.32×10 -2g sodium hexametaphosphate plus 2.3mL water to form a solution, add 164.4mL of absolute ethanol and transfer to a crystallization kettle, place in a 140°C oven for crystallization for 4 hours, cool to room temperature and perform suction filtration, and add 180mL of acrylic acid to the obtained solid Alcohol is dispersed to obtain a concentration of 2×10 -2 g / mL manganese-iron-cerium ternary composite oxide liquid catalyst for ozonolysis at room temperature.

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Abstract

A liquid catalyst for room-temperature catalytic ozonolysis is disclosed. The catalyst is prepared by the following method: dissolving metal salt in water, adding a complexing agent and a surfactant,and uniformly stirring to obtain a mixed solution; and stirring the obtained mixed solution at a temperature in a range of room temperature to 95 DEG C for 0-40 minutes, adding a solvent, crystallizing at 120-200 DEG C for 1-8 hours, cooling to room temperature, carrying out suction filtration, filtering out solid, and dispersing the solid in the solvent to obtain the catalyst. The process is simple, the cost is low, and the application range is wide. The prepared active spraying liquid does not need roasting, theoretically, atomization spraying loading can be flexibly carried out on the surfaces of objects in any shape and made of any material, the objects can be endowed with the ozone catalytic decomposition capacity after drying, the space is fully utilized to allow ozone to be in fullcontact with a catalytic material as much as possible, so that environmental ozone is efficiently decomposed, and the purpose of treating ozone pollution is achieved.

Description

technical field [0001] The invention relates to a liquid catalyst for catalyzing ozone decomposition at room temperature, a preparation method and application thereof. Background technique [0002] Air is an essential substance that human beings cannot live without for a moment, and its quality directly affects human production and life. In recent years, the problem of excessive ozone in my country has become increasingly prominent, and it has become another important regional air pollutant after PM2.5. As a strong oxidizing gas, ozone has a corrosive effect on human skin and eyes, and can strongly stimulate the mucous membrane tissue of the body. When the concentration exceeds 1×10 -7 (volume ratio) will cause discomfort to the human body, leading to cardiopulmonary problems such as asthma, bronchitis, heart disease, and further increase in concentration may even lead to death. In addition, ozone can also cause damage to the ecological environment, for example, causing ne...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/34B01J23/889B01J35/12B01J37/08B01D53/86B01D53/66
CPCB01J23/34B01J23/8892B01J23/002B01J35/12B01J37/08B01D53/8675B01J2523/00B01J2523/17B01J2523/3712B01J2523/72B01J2523/842B01J2523/847Y02A50/20
Inventor 卢晗锋陈晓周瑛胡中恒耿俊
Owner ZHEJIANG UNIV OF TECH
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