A liquid catalyst for room-temperature catalytic ozonolysis is disclosed. The catalyst is prepared by the following method: dissolving metal salt in water, adding a complexing agent and a surfactant,and uniformly stirring to obtain a mixed solution; and stirring the obtained mixed solution at a temperature in a range of room temperature to 95 DEG C for 0-40 minutes, adding a solvent, crystallizing at 120-200 DEG C for 1-8 hours, cooling to room temperature, carrying out suction filtration, filtering out solid, and dispersing the solid in the solvent to obtain the catalyst. The process is simple, the cost is low, and the application range is wide. The prepared active spraying liquid does not need roasting, theoretically, atomization spraying loading can be flexibly carried out on the surfaces of objects in any shape and made of any material, the objects can be endowed with the ozone catalytic decomposition capacity after drying, the space is fully utilized to allow ozone to be in fullcontact with a catalytic material as much as possible, so that environmental ozone is efficiently decomposed, and the purpose of treating ozone pollution is achieved.