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74 results about "Activity coefficient" patented technology

An activity coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures can be expressed directly in terms of simple concentrations or partial pressures of the substances present e.g. Raoult's law. Deviations from ideality are accommodated by modifying the concentration by an activity coefficient. Analogously, expressions involving gases can be adjusted for non-ideality by scaling partial pressures by a fugacity coefficient.

Method for removing titanium in molten iron

ActiveCN103695589AStable titanium removal effectGuaranteed titanium removal efficiencyManufacturing convertersAlkalinitySlag
The invention discloses a method for removing titanium in molten iron and belongs to the field of metallurgy continuous casting. The method comprises the following steps: adding a titanium removal agent into a torpedo ladle before tapping in ironworks, and tapping, so that the titanium removal agent and the molten iron are reacted completely, and the titanium removal product floats upwards; adding the titanium removal agent into a ladle in front of a torpedo ladle station in the ironworks, carrying out oxidizing reaction between the titanium removal agent and the molten iron by virtue of steel flow impact during tapping, and removing the titanium; removing titanium removal residues in front of a sulfur removal station before sulfur removal, and performing molten iron sulfur removal and converter blowing. According to the method, the titanium removal agent can be respectively added into the torpedo ladle and the ladle, and the addition amount of the titanium removal agent is adjusted according to the temperature of the molten iron and alkalinity of molten iron slag, so that the titanium removal efficiency is guaranteed. In addition, the titanium removal is influenced due to an activity coefficient of TiO2 in the slag, and the effect of removing titanium in the molten iron can be effectively stabilized.
Owner:SHOUGANG ZHIXIN QIAN AN ELECTROMAGNETIC MATERIALS CO LTD

Synergistic additive of natural-gas as welding and cutting gas

InactiveCN102604699AEasy to cutLow oxygen consumption per unitGaseous fuelsCeriumRare earth
The invention discloses a synergistic additive of natural-gas as welding and cutting gas, and relates to the technical field of the synergistic additives of the natural-gas as the welding and cutting gas, wherein a preparation process of the synergistic additive comprises the following steps: uniformly mixing ethanol with petroleum ether for later use; adding tetrahydrofuran into a reaction kettle, adding bis(cyclopentadienyl) iron and a liquid cerium-aluminum composite rare earth catalyst into the reaction kettle to stir, and mixing with the mixed solution after dissolving completely; and standing for 4 hours and discharging clear liquid through a liquid discharge valve at the side of the reaction kettle, and filling the clear liquid into a package bucket to obtain the synergistic additive. The synergistic additive combines a catalytic activation principle of the cerium-aluminum composite rare earth and special organic chemical materials to play roles of increasing the temperature and assisting the combustion in the natural gas, resisting against explosion and increasing the flame temperature of the combustion of the natural gas in oxygen. In addition, the synergistic additive can be gasified under certain pressure and mixed with the natural gas to increase the activity coefficient index of the natural gas and increase the temperature of the combustion of the natural gas in oxygen to about 3430 DEG C, which is at an advanced level in the industry. The synergistic additive can completely replace acetylene in cutting, welding, baking and flame spraying functions.
Owner:赵志鑫 +3

Method for preparing machine-transplanted rice seedling raising substrate by taking rice straw fermentation product as raw material

ActiveCN106565357AHigh nutrient content of the substrateImprove water retentionBio-organic fraction processingFungiComing outPeat
The invention discloses a method for preparing a machine-transplanted rice seedling raising substrate by taking a rice straw fermentation product as a raw material. According to the preparation method, rice straw wastes are used as a raw material and are fermented by using a variety of beneficial microorganisms for 40-60 days to obtain a microbial organic fertilizer which is used for preparing the rice seedling raising substrate together with perlite, vermiculite, peat, a water retention agent and biocontrol bacteria in proportion, and the substrate is small in volume weight, is convenient to carry, is good in water holding capacity to reduce the irrigation frequency and reduce the water consumption, and has rich nutrient substances to avoid additional fertilizer in the whole seedling raising period; rice seedlings come out neatly and are high in root system activity coefficient; and the substrate is low in cost and strong in compatibility with a machine-transplanting technology, and can not only reduce the usage amount of paddy field soil, but also avoid the risk of causing pollution to the environment due to improper treatment of straws.
Owner:NANJING INST OF ENVIRONMENTAL SCI MINIST OF ECOLOGY & ENVIRONMENT OF THE PEOPLES REPUBLIC OF CHINA

Control method for oxygen argon decarbonization converter end point temperature end point carbon

The invention relates to a method for controlling endpoint temperature and endpoint carbon of an argon oxygen decarburization converter. An endpoint carbon and endpoint temperature mathematic model is constructed to achieve the best control effect. The model constructing steps comprise: (a) chemical components of C, Mn, Si, Cr, Ni and P of molten steel in the converter and the initial furnace condition temperature are read from basic automatic level; (b) according to data and mathematic models, a least square method is used for working out reaction rate constant Ki, activity coefficient Fi of components in liquid steel, mass transfer coefficient Ni of the components in the molten steel during the slag liquid phase reaction and equilibrium constants Kco, Kcr2o3 and Ksio2, and values worked out according to working conditions are written into a database during the automation of the production process; (c) the direct oxidation heat releasing in unit time of a reaction surface is worked out according to the models; (d) the temperature change of the molten steel and the concentration change of the components in the molten steel within the time step of delta t are worked out according to the heat balance in the converter. The method of the controlling endpoint temperature and the endpoint carbon of the argon oxygen decarburization converter prolongs the service life of the converter, reduces blow losses of chromium and achieves the function of removing carbon to protect chromium.
Owner:BAOSTEEL ENG & TECH GRP

Method for accurately testing content of salt in seawater desalination liquid based on ion concentration and equipment special for method

The invention relates to a method for accurately testing the content of salt in seawater desalination liquid based on ion concentration and equipment special for the method. By the method, an activity coefficient is corrected, measuring accuracy is improved, and the application range is expanded. Values of standard potential E<0> and slope S can be obtained through correction, a functional relation between the concentration of sodium ions in the seawater desalination liquid and the electromotive force of NaCl in the seawater desalination liquid is deduced according to a Nernst equation. During use, two indicating electrodes, namely a chloride ion selective electrode and a sodium ion glass electrode are used as a positive electrode and a negative electrode and are connected with an instrument to form a primary battery, the electromotive force of the seawater desalination liquid with unknown concentration is measured and substituted into the functional relation, and the display instrument can directly display the accurate concentration of the sodium ions in the seawater desalination liquid. The method is suitable for measuring low concentration in a narrow range, and is also suitable for accurately measuring the content of the salt in the seawater desalination liquid with high salt concentration, the accuracy of the method is higher than that of the conventional method, and a standard buffer solution is not required to be added in a linear range.
Owner:NANJING UNIV

Preparation method of mechanical transplanting rice seedling raising substrate

ActiveCN106518401AHigh nutrient content of the substrateImprove water retentionExcrement fertilisersGrowth substratesPeatPaddy soils
The invention discloses a preparation method of a mechanical transplanting rice seedling raising substrate, and especially relates to applications of a biological agent. According to the preparation method, straw waste is taken as a raw material, fermentation with a plurality of beneficial microorganisms is carried out for 40 to 60 days, an obtained microbial organic fertilizer is mixed with perlite, vermiculite, peat, and a water-retaining agent at a certain ratio so as to prepare a rice seedling raising substrate, and the biological agent phomopsis HQ285146 prepared from corn flour is added. The obtained mechanical transplanting rice seedling raising substrate is light in volume-weight, is convenient to carry, is excellent in water-retaining property, is capable of reducing irrigation times, saving water, and is abundant in nutrients; no extra topdressing is needed in the whole rice seedling raising process; obtain seedlings are uniform; root system activity coefficient is high; cost is low; compatibility with mechanical transplanting technology is high; using amount of paddy soil is reduced; and environment pollution caused by improper treatment of straw is avoided.
Owner:NANJING INST OF ENVIRONMENTAL SCI MINIST OF ECOLOGY & ENVIRONMENT OF THE PEOPLES REPUBLIC OF CHINA

Simplified weighted repeat pseudo-median filtering method with negative coefficients

The invention discloses a simplified weighted repeat pseudo-median filtering method with negative coefficients. The method comprises the following steps: taking the frequency response characteristics of an approximation same-order finite impulse response (FIR) filter as an objective, designing weighting coefficients containing negative numbers for weighted pseudo-median computation of filtering window data by an MALLOWS comprehensive method, adjusting the window data by the weighting coefficients; simultaneously, computing weighting coefficients based on the slopes of a group of special structures designed for the filter, computing the overall slope of the window data repeatedly by the weighted pseudo median, carrying out linear transformation on the window data by the slope; and finally carrying out weighted computation on the transformed data by the pseudo-median weighting coefficients to obtain the output value of weighted repeat pseudo-median filtering. The method realizes a better frequency selection characteristic than that of the existing negative coefficient weighted median or pseudo-median filtering method, and simplifies computation in the algorithm to meet the requirement of systems with finite resources, such as a wireless sensor and the like for low power consumption.
Owner:CENT SOUTH UNIV

Polypropylene fiber-reinforced alkali slag cementing material

InactiveCN106699099ASmall unit volumeReduce volumeSlagPotassium
The invention relates to a polypropylene fiber-reinforced alkali slag cementing material. When thicker steel fibers are subjected to tensile test, the phenomenon that the thicker steel fibers are pulled out due to larger size exists. The polypropylene fiber-reinforced alkali slag cementing material comprises the following slag chemical compositions in percentage by weight: 36.9 percent of silicon dioxide, 15.66 percent of aluminum oxide, 37.57 percent of calcium oxide, 9.3 percent of magnesium oxide and 0.36 percent of ferric oxide; active indexes are shown as follows: the mass coefficient is 1.69, the alkaline coefficient is 0.97, and the activity coefficient is 0.42; potassium water glass of which M is equal to 1.0, and M is equal to 2.0, sodium hydroxide with a mass fraction of greater than or equal to 96.0 percent, a polypropylene fiber with an elastic modulus of 42 GPa and tap water are adopted; the compressive and flexural strengths of an alkali slag cementing material gel sand part doped with the polypropylene fiber are improved along with the prolonging of maintenance time, and the flexural strength of the alkali slag cementing material containing 12 percent of alkali and 35 percent of water is improved. The invention can be used for the preparation of polypropylene fiber-reinforced alkali slag cementing material.
Owner:HARBIN UNIV OF SCI & TECH

AC filter considered machine set action coefficient determining method

The invention proposes an AC filter considered machine set action coefficient determining method, which belongs to the field of fault analysis of a generator. Considering that in a traditional method for analyzing the action coefficient of a machine set, the influence of the AC filter on the circuit is neglected, the invention is based on the analysis of the secondary synchronous oscillation to determine the action coefficient of the machine set and introduces a double-tuned wave AC filter to the system, which includes: adding a multi-tuned AC harmonic filter to the rectifying side in a high-voltage DC converter system; considering the influence of the multi-tuned AC harmonic filter on the capacity reactive power compensation of a DC transmission system; through the short circuit calculation, obtaining the new three-phase short-circuit current across the AC bus between a DC transmission rectifier station and the generator set; and improving the method for calculating the three-phase short circuit capacity of the DC transmission rectifier station's AC bus so as to further improve the method for determining the action coefficient of the machine set and to increase the measurement precision for action coefficient of the machine set. The method is very reliable, and in the practicing process of the method, the risks of secondary synchronous oscillation can be greatly reduced.
Owner:STATE GRID LIAONING ELECTRIC POWER RES INST +2

Multiple fluid phase mixed system chemical equilibrium calculating system

The invention relates to a multiple fluid phase mixed system chemical equilibrium calculating system. The calculating system comprises a data input module, a multiple mixed system chemical equilibrium calculating module, a system thermodynamic property calculating module and a calculating result output module; when the influence caused by the structures and shapes of particles are not needed to consider, the amount of parent materials of various reaction and generation species and the reference state mole Gibbs free energy are known, the minimal value of the Gibbs free energy of the whole mixed system can be calculated by gradually planning an optimization algorithm at the second time by calculating the Gibbs free energy of the system and the activity coefficients of various species and the amount {Xi} of the multiple chemical equilibrium state substances of various reactants and products through a thermodynamic model, so as to calculate the property of the equilibrium state of the mixed system; the calculating system does not need to perform experience trying when the chemical equilibrium is calculated, and a plurality of mixed system thermodynamic properties including the concentrations, activity, and activity coefficients and the like of all reactants and products can be high-efficiently and quickly calculated in the multiple chemical equilibrium by the optimized procedure and algorithm.
Owner:GUIZHOU EDUCATION UNIV
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