The invention provides a method for detecting the content of fluorine ions in perfluoroalkyl sulfonyl imine salts. The method comprises the following steps: preparing at least two fluorine ion standard test solutions with different fluorine ion concentrations, measuring the potential values of the standard test solutions, according to the Nernst equation, calculating the electrode constants (S); adding a total ion strength adjusting and buffering solution into perfluoroalkyl sulfonyl imine salts, diluting the solution by water, evenly mixing, measuring the potential value of the sample solution; then adding a fluorine ion standard stock solution into the sample solution, evenly mixing, measuring the potential value of the mixed solution; according to the Nernst equation, calculating the fluorine ion concentration of the sample solution, and finally calculating out the fluorine ion concentration of perfluoroalkyl sulfonyl imine salts. The provided method reduces the dependency of detection of fluorine ions in perfluoroalkyl sulfonyl imine salts on the ion chromatography, is capable of directly, accurately, and rapidly measuring the content of fluorine ions in perfluoroalkyl sulfonyl imine salts, and has the advantages of simple measurement process, high result precision, and wide measuring range.