Environment-friendly structural adhesive and preparation method thereof

A structural adhesive and environmental protection technology, applied in the direction of epoxy resin glue, adhesive, adhesive type, etc., can solve the problem of high price, achieve environmental protection and waterproof performance, excellent high and low temperature resistance, and low UV aging resistance Effect

Inactive Publication Date: 2020-12-29
冯国旭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the bonding strength, aging resistance and comprehensive performance of this structural adhesive need to be further improved, and molybdenum powder is used in it, resulting in a high price

Method used

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  • Environment-friendly structural adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] An environmentally friendly structural adhesive is characterized in that it includes A component and B component, wherein the weight ratio of A component to B component is 1:2; A component is composed of the following raw materials in parts by weight Made: 30 parts of trimethyl 4-phosphocrotonate / methyl vinyl bis(butanone oxime) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer, 20 parts of clay mineral powder, defoamer 0.5 parts, 13 parts of diluent; component B is made of the following raw materials in parts by weight: amino-terminated polyurethane / 4,6-bis(1-adamantyl)-1,3-diglycidyl ether benzene 25 parts of condensation polymer, 2 parts of 2,4,6-tris(4-aminophenyl)-1,3,5-triazine, N + 0.5 parts of organic nanometer antibacterial agent modified graphene quantum dots.

[0035] The preparation method of described trimethyl 4-phosphocrotonate / methylvinyl bis(butanone oxime base) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer comprises the steps...

Embodiment 2

[0045] An environmentally friendly structural adhesive is characterized in that it includes A component and B two components, wherein the weight ratio of A component to B component is 1:2.3; A component is composed of the following raw materials in parts by weight Made: 33 parts of trimethyl 4-phosphocrotonate / methyl vinyl bis(butanone oxime) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer, 22 parts of clay mineral powder, defoamer 0.7 parts, 15 parts of diluent; component B is made of the following raw materials in parts by weight: amino-terminated polyurethane / 4,6-bis(1-adamantyl)-1,3-diglycidyl ether benzene 28 parts of condensation polymer, 2.5 parts of 2,4,6-tris(4-aminophenyl)-1,3,5-triazine, N + 0.7 parts of organic nanometer antibacterial agent modified graphene quantum dots.

[0046] The preparation method of described trimethyl 4-phosphocrotonate / methylvinyl bis(butanone oxime base) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer comprises ...

Embodiment 3

[0055] An environmentally friendly structural adhesive is characterized in that it includes A component and B two components, wherein the weight ratio of A component to B component is 1:2.5; A component is composed of the following raw materials in parts by weight Made: 35 parts of trimethyl 4-phosphocrotonate / methyl vinyl bis(butanone oxime) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer, 25 parts of clay mineral powder, defoamer 1 part, 17 parts of diluent; component B is made of the following raw materials in parts by weight: amino-terminated polyurethane / 4,6-bis(1-adamantyl)-1,3-diglycidyl ether benzene 30 parts of condensation polymer, 3 parts of 2,4,6-tris(4-aminophenyl)-1,3,5-triazine, N + Organic nanometer antibacterial agent modified graphene quantum dot 0.8 parts.

[0056] The preparation method of described trimethyl 4-phosphocrotonate / methylvinyl bis(butanone oxime base) silane / 2-vinylmercaptopyrimidine / glycidyl acrylate copolymer comprises the steps...

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Abstract

The invention discloses an environment-friendly structural adhesive which is characterized by comprising a component A and a component B. The weight ratio of the component A to the component B is 1:(2-3). The component A is prepared from the following raw materials in parts by weight: 30-40 parts of a 4-phosphorus butenoic acid trimethyl ester/methyl vinyl di (diacetylketoxime) silane/2-ethylene mercaptopyrimidine/glycidyl acrylate copolymer, 20-30 parts of clay mineral powder, 0.5-1.5 parts of a defoaming agent and 13-20 parts of a diluent; and the component B is prepared from the following raw materials in parts by weight: 25-35 parts of amino-terminated polyurethane/4, 6-bis (1adamantyl)-1, 3-diglycidyl ether benzene polycondensate, 2-4 parts of 2, 4, 6-tri(4-aminophenyl)-1, 3, 5-triazine and 0.5-1 part of N+ organic nano antibacterial agent modified graphene quantum dots. The invention further discloses a preparation method of the environment-friendly structural adhesive. The environment-friendly structural adhesive disclosed by the invention is strong in adhesive force, excellent in comprehensive performance, mechanical property, weather resistance, high and low temperature resistance and chemical stability resistance, and good in waterproofness and environment-friendly performance.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to an environmentally friendly structural adhesive and a preparation method thereof. Background technique [0002] Structural adhesives, referred to as structural adhesives, generally refer to the components used to bond the body under stress, and are adhesives that require relatively high mechanical strength (especially impact peel strength) and durability. It is generally used for structural bonding of stressed parts such as tension, shear, impact and vibration. It has the advantages of high strength, anti-stripping, impact resistance, and simple construction technology. It is used in aerospace, rail vehicles, ships, and automobiles. have a wider range of applications. [0003] At present, there are epoxy resin, bismalay resin and cyanate resin structural adhesive films on the market, which can meet the application requirements in terms of mechanical strength, but the product h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J143/02C09J11/04C09J11/06
CPCC09J163/00C09J11/04C09J11/06C08L2201/08C08L2201/02C08L43/02C08K9/04C08K3/042C08K3/346C08K5/3492
Inventor 冯国旭
Owner 冯国旭
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