Online hydrogen supply system based on alcohol fuel reforming reaction

A technology of reforming reaction and alcohol fuel, which is applied in the field of hydrogen production, can solve the problems of only 40g/L, low technology maturity, and high energy consumption of dehydrogenation, and achieve small volume and weight of the device, wide source of raw materials, and high heat utilization rate high effect

Pending Publication Date: 2021-01-26
WUHAN MARINE ELECTRIC PROPULSION RES INST CHINA SHIPBUILDING IND CORP NO 712 INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantages of high-pressure gaseous hydrogen storage are high technical maturity, simple structure of hydrogen storage device, easy to carry and use, and fast hydrogen charging and discharging speed. The disadvantage is that the hydrogen storage density is low. The hydrogen density is only about 40g / L
In addition, the storage and use of high-pressure hydrogen storage has great potential safety hazards; solid material hydrogen storage technologies such as alloy hydrogen storage have the characteristics of high safety and good reliability, but their shortcomings lie in the high cost of hydrogen storage materials and the weight of hydrogen storage devices. Low density, difficult to meet the long-term hydrogen supply demand of high-power proton exchange membrane fuel cells
Organic liquid hydrogen storage technology has high material hydrogen storage density, and hydrogen fuel storage and transportation are convenient, but its disadvantages are high dehydrogenation energy consumption and low technology maturity
Its main disadvantages are that the pressure swing adsorption purification device has a large volume and weight, and the hydrogen separation efficiency is low, which limits the application of reforming hydrogen production technology in fuel cell distributed power generation systems, motorized power stations, new energy vehicles, etc.

Method used

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  • Online hydrogen supply system based on alcohol fuel reforming reaction

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A basic example of the present invention is figure 1 As shown, an on-line hydrogen supply system based on the reforming reaction of alcohol fuels includes a raw material tank 1, a heat exchanger 3 connected to the raw material tank 1 through a raw material metering pump 1.2 and a solenoid valve 1.1, a fuel metering pump 1.4 and a The hydrogen production-purification integrated reactor 4 connected with the electromagnetic valve 1.3 and the raw material box 1, the hydrogen production-purification integrated reactor 4 is connected with the air pump 2, the cooler 5 and the hydrogen storage tank 6 connected with the cooler 5, The heat exchanger 3 is connected to the outside through the stop valve 3.1, and the hydrogen storage tank 6 is connected to the outside through the stop valve 6.2 and the back pressure valve 6.3 in turn.

[0018] The hydrogen production-purification integrated reactor 4 includes a vaporization chamber 4.1, a reforming reaction chamber 4.2, a catalytic ...

Embodiment 2

[0020] Further embodiment on the basis of Example 1: its alcohol fuel is a mixture of methanol and ethanol, the raw material stored in the raw material box is a mixture of methanol, ethanol and deionized water, and its alcohol fuel reforming reaction temperature is 450 ℃, the reaction pressure is 0.5 MPa, the alcohol water raw material stored in the raw material box 1 is used as the reaction raw material and the catalytic combustion fuel at the same time, and is transported to the hydrogen production-purification integrated reactor 4 through the raw material metering pump 1.2 and the fuel metering pump 1.4 respectively. The reforming reaction chamber 4.2 and the vaporization chamber 4.1, the vaporization chamber 4.1 of the hydrogen production-purification integrated reactor 4 are connected with the catalytic combustion chamber 4.3, and the alcohol water raw material used as catalytic combustion is simultaneously in the vaporization chamber 4.1 and the catalytic combustion chambe...

Embodiment 3

[0022] Further embodiment on the basis of embodiment 2. The difference from Example 2 is that the alcohol fuel is ethanol, the raw material stored in the raw material box is a mixture of ethanol and deionized water, the reforming reaction temperature is 550°C, the reaction pressure is 4.0MPa, and the reaction temperature of catalytic combustion is 600°C, the catalyst set in the vaporization chamber 4.1 and the catalytic combustion chamber 4.3 is Pd / Al 2 o 3 , The hydrogen purification chamber is equipped with a membrane tube type palladium alloy purification component, and the cooling method of pure hydrogen generated by the reforming reaction is water cooling.

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Abstract

The invention discloses an online hydrogen supply system based on alcohol fuel reforming reaction. The system comprises a raw material box, a heat exchanger connected with the raw material box througha raw material metering pump, a hydrogen production- purification integrated reactor connected with the raw material box through a fuel metering pump, an air pump connected to the hydrogen production-purification integrated reactor, a cooler and a hydrogen storage tank connected to the cooler, wherein the hydrogen production-purification integrated reactor comprises a vaporization chamber, a reforming reaction chamber, a catalytic combustion chamber, a hydrogen purification chamber, a temperature sensor and a reforming product gas conveying coil, and the reforming reaction chamber, the catalytic combustion chamber and the hydrogen purification chamber are of cylindrical sleeve type structures and are sequentially arranged from outside to inside. The hydrogen supply system has the advantages of being high in hydrogen storage density, small in size and weight, wide in raw material source, wide in application range, capable of producing and using hydrogen immediately and the like.

Description

technical field [0001] The invention belongs to the technical field of hydrogen production, and relates to an online hydrogen supply system based on the hydrogen production reaction of alcohol fuel reforming. Background technique [0002] A hydrogen fuel cell is a high-efficiency power generation device that directly converts the chemical energy in hydrogen fuel and oxidant into electrical energy by electrochemical means. Proton exchange membrane fuel cells have the advantages of high energy conversion efficiency, suitable working temperature, low vibration and noise, and environmental friendliness. They have been widely used in new energy vehicles, distributed power stations, emergency power supplies, and national defense and military industries. For example, in the civilian field, fuel cell vehicles represented by Japan’s Toyota “Mirai”, Honda “Clarity” and South Korea’s Hyundai “ix35” have achieved large-scale mass production; Millions of households. In the military fie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B3/32H01M8/0612
CPCC01B3/326H01M8/0618C01B2203/0233C01B2203/066C01B2203/0822C01B2203/1217C01B2203/1223C01B2203/1229C01B2203/1288Y02E60/50
Inventor 吴飞刘强吴骁谭波黄润伍
Owner WUHAN MARINE ELECTRIC PROPULSION RES INST CHINA SHIPBUILDING IND CORP NO 712 INST
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