24 results about "Hydrogen density" patented technology

The invention discloses a composite hydrogen storage device and a fuel cell. The composite hydrogen storage device comprises a first reaction chamber and a second reaction chamber, the first reaction chamber is arranged in the second reaction chamber, the first reaction chamber is used for preparing hydrogen through a hydrolysis reaction, and the second reaction chamber is used for preparing hydrogen or storing hydrogen through an endothermic reaction. The first reaction chamber and the second reaction chamber are respectively used for being connected with a fuel cell. The fuel cell comprises the composite hydrogen storage device. The first reaction chamber and the second reaction chamber of the composite hydrogen storage device are respectively connected with a fuel cell so as to provide a hydrogen source for the fuel cell. According to the composite hydrogen storage device, a hydrogen storage or hydrogen production mode, such as organic liquid hydrogen storage, methanol reforming hydrogen production, solid hydrogen storage and the like, which can only react after heat absorption is set, so that heat released by hydrolysis reaction in the first reaction chamber is recycled, the energy utilization efficiency is improved, and meanwhile, the hydrogen storage density of the system is improved.

The invention discloses a control method and device of a material moisture online monitoring system and a storage medium, and relates to the technical field of material moisture monitoring, and the method comprises the steps: starting a neutron generator assembly, and starting a neutron detector assembly and a gamma detector when the starting duration of the neutron generator assembly is greater than or equal to the preheating preset duration; based on a detection result of the neutron detector assembly, determining an accumulated scattering neutron share of the detected material, and obtaining a corresponding target hydrogen density matched with the accumulated scattering neutron share from a preset association library; based on a gamma detector, counting the monitored gamma rays in a classified manner according to the pulse amplitude, generating a gamma-ray energy spectrum, and extracting a water hydrogen characteristic peak area from the gamma-ray energy spectrum; according to the target hydrogen density, the water-hydrogen characteristic peak area and the energy spectrum calibration coefficient of the gamma-ray energy spectrum, the curing hydrogen ratio is determined; and determining the free water content of the detected material according to the cured hydrogen ratio. According to the invention, through dual-mode cooperative detection, the problem of low accuracy of moisture monitoring is solved.

The utility model discloses a composite hydrogen supply system and hydrogen using equipment. The composite hydrogen supply system comprises a methanol storage device, a water storage device, a mixing device, a reaction chamber, a catalytic burner and a hydrogen storage device, the methanol storage device and the water storage device are connected to the mixing device in parallel, the mixing device is connected with the reaction chamber, the reaction chamber is used for being connected with hydrogen using equipment, and the catalytic burner is connected with the hydrogen storage device. The reaction chamber is used for carrying out reforming hydrogen production reaction or organic liquid hydrogen storage and desorption reaction, the catalytic burner is connected to the reaction chamber and used for maintaining the temperature needed by the reaction chamber, and the hydrogen storage device is used for being connected with hydrogen using equipment and used for providing hydrogen for the hydrogen using equipment in the cold start stage of the system. The water storage device is further used for being connected with hydrogen using equipment so as to collect water generated by the hydrogen using equipment. The composite hydrogen supply system provided by the utility model can solve the problem of slow cold start of methanol reforming hydrogen production in the prior art, and improves the hydrogen storage density of the whole system at the same time.

The invention discloses a flow measurement method and device for hydrogen-containing mixed gas based on thermal conductivity, and belongs to a flow measurement technology for hydrogen-containing mixed gas. According to the method, firstly, zero gas is adopted for calibration and reference so as to obtain hydrogen mass flowmeter data under the condition that hydrogen is not contained, and hydrogen mass flowmeter data under different flows are obtained by adjusting a float flowmeter; then acquiring data under different hydrogen contents and different flows by adopting hydrogen-containing mixed gases with different volumes, a hydrogen float flowmeter and a hydrogen mass flowmeter, synchronously recording gas path temperature and pressure in a measurement process, and fitting to obtain a slope and concentration relationship through volume-mass flow relationship curves of gases with different concentrations; and finally, deducing a volume flow calculation formula of the mixed hydrogen by utilizing the compensated parameters such as the density and the heat conductivity of the mixed gas and combining hydrogen density and mass flow data in a standard state. According to the invention, a reliable calibration basis is provided for the flow measurement of the hydrogen mixed gas.

A system and a method for stabilizing hydrogen flow to a downstream process in a facility determining a hydrogen density and pressure profiles in the hydrogen storage unit for different target net hydrogen flows at different time intervals of a time horizon of a renewable power availability profile, determining an operating target net hydrogen flow of a hydrogen feed to the downstream process, determining a target direct hydrogen flow of a hydrogen feed and a target stored hydrogen flow of a hydrogen feed to the downstream process, and controlling the operation of the downstream process based on the operating target hydrogen flows.

This invention discloses a high-hydrogen-density liquid organic hydrogen carrier and its applications, belonging to the field of hydrogen energy storage and utilization technology. The liquid organic hydrogen carrier is a composite system of a functionalized nitrogen-containing heterocyclic compound and a metal-organic framework material supported on a non-precious metal catalyst. The nitrogen-containing heterocyclic framework is connected with electron-donating and electron-withdrawing groups, constructing an intramolecular electron push-pull system. The non-precious metal catalyst is supported inside the pores or on the surface of the metal-organic framework material. Through molecular structure design and catalyst system optimization, this invention achieves a hydrogen storage density of not less than 7.0 wt%, a dehydrogenation onset temperature of not more than 150℃, and a dehydrogenated hydrogen purity of not less than 99.99%, with excellent cycle stability and low catalyst cost. This liquid organic hydrogen carrier can be widely used in renewable energy storage, long-distance hydrogen transportation, vehicle-mounted hydrogen sources, and distributed energy supply systems.

The invention discloses a supercritical hydrogen energy storage system which comprises a supercritical hydrogen storage bottle and a liquid nitrogen tank, the liquid nitrogen tank is composed of an inner barrel and an outer barrel, the inner barrel is installed in the outer barrel, a vacuum interlayer is arranged between the inner barrel and the outer barrel, liquid nitrogen is stored in the inner barrel, the supercritical hydrogen storage bottle is installed in the inner barrel through a supporting structure, and the supercritical hydrogen storage bottle is installed in the outer barrel through the supporting structure. And a gap is reserved between the supercritical hydrogen storage bottle and the inner barrel. According to the supercritical hydrogen energy storage system, the supercritical hydrogen storage bottle is soaked in liquid nitrogen, a stable low-temperature environment is formed through liquid nitrogen soaking, heat invasion is effectively restrained, and the evaporation rate of hydrogen approaches zero under static storage. The temperature of the liquid nitrogen is-196 DEG C, the temperature of the liquid hydrogen is-253 DEG C, the energy consumption of refrigerating to-196 DEG C is far lower than that of liquefying to-253 DEG C, and the liquid nitrogen is low in cost and easy to obtain; under the composite storage condition of 70MPa and-196 DEG C, the hydrogen can be easily maintained in a supercritical state, and the hydrogen density can exceed 70kg / m, is superior to normal-temperature high-pressure gaseous hydrogen storage, and reaches or exceeds the normal-pressure liquid hydrogen level.

A sensitive detection device for hydrogen leakage of a hydrogen-containing medium pipeline flange comprises a pinnacle gas-collecting hood arranged right above the pipeline flange, and the inner wall of the pinnacle gas-collecting hood forms a flow guide space converging towards the top and is used for collecting hydrogen leaked from the pipeline flange and guiding the hydrogen to the top; the hydrogen detection sensor mounted at the top detects the hydrogen concentration of the collected gas in real time; the discharge pipeline is communicated with the pinnacle gas-collecting hood, and the detected gas is safely discharged to avoid local accumulation; the control system is electrically connected with the sensor through a cable and receives concentration signals in real time. According to the device, leaked gas is naturally converged through the pinnacle gas collection structure by using hydrogen density difference, the gas concentration of a sensor detection area is improved, the gas is safely discharged through a discharge pipeline after being detected by a sensor, and a control system can quickly give an early warning when the hydrogen concentration exceeds a threshold value. The device solves the problem of insufficient hydrogen detection sensitivity in an open environment, has the advantages of simple structure, quick response, safety and reliability, is suitable for hydrogen leakage monitoring in industrial fields such as synthesis ammonia and the like, and effectively guarantees the production safety.

The invention provides flame-retardant heat-insulating resin and a hydrogen storage cylinder flame-retardant heat-insulating composite material winding layer prepared from the same. The flame-retardant heat-insulating resin comprises the following components in parts by weight: 30-50 parts of halogenated epoxy resin, 10-20 parts of a flame retardant, 10-20 parts of an inorganic filler, 4-20 parts of a curing agent and 0.5-5 parts of a curing accelerator. The flame-retardant and heat-insulating resin is used for preparing a flame-retardant and heat-insulating composite material winding layer of the hydrogen storage cylinder and the hydrogen cylinder. According to the method, synchronous curing of the internal winding layer and the flame-retardant and heat-insulating winding layer can be achieved, so that the production period is shortened, and the cost is reduced; moreover, the fireproof winding layer can play a role in flame retardance and heat insulation and can also provide certain mechanical strength, and the hydrogen storage density of the hydrogen storage cylinder per unit mass is far higher than that of a traditional scheme.

The invention relates to a metal hydride / high-pressure composite hydrogen storage tank based on a vanadium-based solid hydrogen storage alloy, and belongs to the technical field of hydrogen energy. The chemical formula of the vanadium-based solid hydrogen storage alloy is VxTiyCrz, the range of x is 50-80, the range of y is 4-12, and the range of y / z is 0.15-0.37; the vanadium-based solid hydrogen storage alloy is composed of a body-centered cubic single phase. The volume hydrogen storage density of the metal hydride composite hydrogen storage tank is 65-118 g / L, and the mass hydrogen storage density of the metal hydride composite hydrogen storage tank is 3.1-2.5 wt.%; the filling rate of the vanadium-based solid hydrogen storage alloy is 31%-70%. The obtained metal hydride composite hydrogen storage tank has the excellent performance that the high-volume hydrogen storage density is larger than or equal to 60 gH2 / L and the high-mass hydrogen storage density is larger than or equal to 2.3 wt.%.

The application discloses a hydrogenation and dehydrogenation system and a control method thereof, wherein the hydrogenation and dehydrogenation system comprises a hydrogen / oil combination chamber, a hydrogen oil tank, a reaction chamber, a hydrogen purification chamber, a purification chamber, an impurity storage chamber and a hydrogen-using equipment; wherein the power P of the hydrogen-using equipment and the hydrogen oil liquid level height h in the reaction chamber have the following relationship: h=Pt / (ρS*Wt%*ηQ), wherein ρ is the hydrogen density, S is the cross-sectional area of the reaction chamber, Wt% is the mass ratio of hydrogen to hydrogen oil in the hydrogen oil mixture, η is the effective conversion efficiency of hydrogen, Q is the heat value of hydrogen, and t is the time for hydrogen flowing from the reaction chamber to the hydrogen-using equipment. The application purifies hydrogen oil and hydrogen generated by storage, improves hydrogenation and hydrogen utilization efficiency, adjusts the actual height of the hydrogen oil liquid level in the reaction chamber according to the mathematical relationship between the hydrogen-using equipment power and the hydrogen oil liquid level height in the reaction chamber, and realizes automatic adjustment of the hydrogen-using equipment power and the hydrogen oil amount in the reaction chamber of the hydrogenation and dehydrogenation system.

The utility model relates to the field of seawater electrolysis of a nuclear power plant, in particular to a hydrogen discharging system of an electrolysis room, which is characterized in that a plurality of air extracting devices are arranged in a plurality of mounting holes of a top plate of the electrolysis room at intervals along a second horizontal direction according to the characteristic of small hydrogen density, and the air extracting devices are in one-to-one correspondence with the mounting holes; a plurality of ventilation openings are formed in the bottoms of the side plates of the electrolysis chamber at intervals, and the air extractor of the top plate of the electrolysis chamber and the ventilation openings in the bottoms of the side plates of the electrolysis chamber form forced convection, so that hydrogen escaping from the sodium hypochlorite storage tank is discharged out of the electrolysis chamber from the air extractor, and the influence of natural factors on the hydrogen discharging effect is avoided; and the situation that the concentration of hydrogen in the electrolysis chamber is high due to the fact that escaped hydrogen is sucked in the hydrogen discharging process is avoided. The air extractor is covered with the rain cover, rainwater is prevented from entering the electrolysis room from the air extractor at the top to corrode instruments in the electrolysis room, and the rain cover is prevented from hindering normal hydrogen discharge of the air extractor by forming the air outlet holes in the rain cover.

The invention discloses a solid hydrogen storage and transportation system based on a solid hydrogen storage alloy. The solid hydrogen storage and transportation system comprises a hydrogen storage unit, a peripheral hydrogen pipeline, a heating medium circulating system and a control system, the hydrogen storage unit comprises a heating medium buffer tank provided with a hydrogen storage tank body, hydrogen storage alloy is loaded in the hydrogen storage tank body, and the hydrogen storage tank body is detachably connected with an external hydrogen source or hydrogen using equipment through a peripheral hydrogen pipeline; the heating medium circulating system comprises a heating medium storage box connected with the heating device, the heating medium storage box is connected with a heating medium buffer box through a heating medium circulating pump, the heating medium storage box is connected with a cooler and the heating medium buffer box through a three-way valve, and the cooler is connected with the heating medium buffer box and the heating medium circulating pump and detachably connected with the heating medium buffer box; the control system is used for achieving dynamic adjustment of the heating medium circulating pump, the heating device and the cooler. The hydrogen storage device has the advantages in the aspects of safety, volume hydrogen storage density and mass hydrogen storage density, higher hydrogen storage density can be realized with lower hydrogen storage pressure, and the hydrogen storage device is convenient to transport and can be recycled.

This invention relates to a method and system for calculating and compensating the State of Charge (SOC) of a hydrogen storage system. The invention includes: real-time acquisition of the pressure and temperature of hydrogen gas within the storage container; correction of the pressure based on the pressure and temperature to obtain a standard pressure at 20°C; calculation of the initial SOC value using the pressure-temperature method based on the 20°C standard pressure; acquisition of the heat transfer coefficient, heat exchange area, real-time hydrogen storage mass, and hydrogen specific heat capacity at constant pressure within the storage container, and calculation of a thermal effect compensation coefficient based on the pressure change rate and temperature change rate; thermal effect compensation of the initial SOC value based on the thermal effect compensation coefficient to obtain a thermally compensated SOC value; correction of the hydrogen density based on the second virial coefficient of hydrogen, the real-time absolute pressure within the storage cylinder, and the real-time thermodynamic temperature to obtain a density correction coefficient; and correction of the thermally compensated SOC value based on the density correction coefficient to obtain the final SOC value. This invention improves the accuracy and stability of SOC calculation for hydrogen storage systems.

The application discloses a hydrogen and electricity system with multiple solid-state hydrogen storage materials coupling for super-high quality hydrogen storage density, and belongs to the technical field of hydrogen and electricity. The hydrogen and electricity system comprises a solid-state hydrogen storage system, a fuel cell stack and a modular solid-state hydrogen storage unit which are arranged in the solid-state hydrogen storage system, the modular solid-state hydrogen storage unit comprises a first hydrogen storage unit (a solid-state hydrogen storage material pyrolysis unit) and a second hydrogen storage unit (a solid-state hydrogen storage material hydrolysis unit) which are arranged in the first hydrogen storage unit; hydrogen outlets of the first hydrogen storage unit and the second hydrogen storage unit are connected to a hydrogen inlet of the fuel cell stack through a pipeline and a third hydrogen storage unit; and an anode tail gas outlet of the fuel cell stack is connected to a water inlet of the second hydrogen storage unit through a pipeline. The application adopts a coupling method to realize integrated design of hydrogen production by pyrolysis of solid-state hydrogen storage material, hydrogen production by hydrolysis and a fuel cell power generation system, realizes efficient utilization and release of water, heat and electricity, and realizes a hydrogen and electricity system solution with super-high energy density.

The application belongs to the technical field of hydrogen energy, and particularly relates to a hydrogen supply system applied to a hydrogen refueling station, comprising: a cascade buffer storage system, comprising at least one cascade buffer storage tank and a hydrogen refueling machine corresponding to the cascade buffer storage tank; and an upstream gaseous hydrogen supply link and a liquid hydrogen supply link. The capacity of the cascade buffer storage tank is calculated according to the hydrogen density at the maximum and minimum pressures obtained by fitting a non-ideal gas model according to a preset maximum hydrogen refueling demand amount for a single time; and the compressor in the gaseous hydrogen supply link and the vaporizer in the liquid hydrogen supply link are both calculated according to the equivalent hydrogen peak flow calculated according to the preset maximum hydrogen refueling demand amount for a single time. The application effectively improves the hydrogen supply stability, equipment utilization rate and operation economy of the hydrogen refueling station in multiple scenarios by constructing a redundant architecture for parallel supply of gaseous hydrogen and liquid hydrogen and reasonably configuring the key components.

The invention discloses an efficient hydrogen discharging and ventilating method utilizing downward-pumping upward-feeding directional airflow. According to a traditional scheme, a top single-side main air pipe is adopted to be matched with an axial flow fan, or a single main air pipe is matched with evenly-distributed branch pipes, hydrogen is low in density and prone to being accumulated at the top, and a traditional side wall is low in even exhaust efficiency. The system comprises a main air pipeline, a branch pipeline, a vertical air pipe, a ventilation unit and a central controller, wherein the main air pipeline comprises a lower air draft main pipe and an upper air supply main pipe; the branch pipeline is connected with the lower air draft main pipe; the vertical air pipes are uniformly distributed at the tail ends of the branch pipelines; the ventilation unit is communicated with the upper air supply main pipe and arranged on the outer wall side of the storage battery chamber, and the ventilation unit comprises a main anti-explosion axial flow fan and a standby emergency hydrogen discharging fan. The device is used for efficient hydrogen discharge and ventilation of the storage battery chamber of the thermal power plant.

A system and method for stabilizing hydrogen flow to a downstream process in a facility determines a hydrogen density and pressure curve in a hydrogen storage unit for different target net hydrogen flow at different time intervals of a time range of a renewable energy availability curve, an operational target net hydrogen flow for the hydrogen feed to the downstream process is determined, a target direct hydrogen flow for the hydrogen feed to the downstream process and a target stored hydrogen flow for the hydrogen feed are determined, and operation of the downstream process is controlled based on the operational target hydrogen flow.

To provide a system and a method for stabilizing a hydrogen flow rate to a downstream process in a facility having a hydrogen storage unit and obtaining electric power from a low carbon energy source.SOLUTION: Determining a hydrogen density and pressure profile in the hydrogen storage unit for different target pure hydrogen flow rates at different time intervals in a time horizon of a profile of available renewable power, determining an operational target pure hydrogen flow rate of hydrogen supply to the downstream process, determining a target direct hydrogen flow rate of hydrogen supply and a target stored hydrogen flow rate of hydrogen supply to the downstream process, and controlling operation of the downstream process based on the operational target hydrogen flow rate.SELECTED DRAWING: Figure 1

The utility model relates to the technical field of hydrogen storage, and provides a light-weight high-pressure hydrogen tank, which comprises a sealing cover, an overpressure exhaust pipe, a tank body and a skirt, by adopting a high-strength and low-density composite material and combining with an optimally designed tank body structure, the mass hydrogen storage density of the hydrogen storage tank is improved, the storage time of hydrogen is prolonged, and the service life of the hydrogen storage tank is prolonged. The whole weight of the hydrogen storage tank is obviously reduced, the hydrogen storage tank is convenient to carry and replace, the transportation cost is reduced, the flexibility of hydrogen energy application is improved, the tank body is filled with a composite material and an anti-explosion agent, good air tightness and pressure resistance are achieved, and the safety of hydrogen in the storage and transportation process is ensured.

A system and a method for stabilizing hydrogen flow to a downstream process in a facility determining a hydrogen density and pressure profiles in the hydrogen storage unit for different target net hydrogen flows at different time intervals of a time horizon of a renewable power availability profile, determining an operating target net hydrogen flow of a hydrogen feed to the downstream process, determining a target direct hydrogen flow of a hydrogen feed and a target stored hydrogen flow of a hydrogen feed to the downstream process, and controlling the operation of the downstream process based on the operating target hydrogen flows.

The invention relates to the technical field of fuel cells, and discloses a fuel cell commercial vehicle accumulated equivalent hydrogen consumption amount and equivalent hydrogen consumption calculation method, which comprises the following steps: acquiring pressure signals of each hydrogen storage tank in a vehicle hydrogen storage system and temperature signals of each hydrogen storage tank in the hydrogen storage system; the average pressure and the average temperature of the vehicle hydrogen storage system are calculated; based on the relationship between the high-pressure hydrogen temperature and pressure and the density, the hydrogen density in the state is obtained, and the mass of hydrogen stored in the vehicle hydrogen storage system is calculated; the SOC change of the power battery is converted into corresponding hydrogen consumption according to the equivalent hydrogen consumption calculation model of the power battery in the running process; and according to the initial hydrogen storage amount and the hydrogen storage amount at the end of the hydrogen storage system in the driving mileage and the equivalent hydrogen consumption amount of the power battery in the process, the hydrogen consumption per hundred kilometers of the whole vehicle is calculated.

The invention discloses a single-pool structure, a multi-pool combined structure, a combined system, a control system and an external circulation heat exchange system of a solid hydrogen pool. The single-pool structure and the multi-pool combined structure of the solid hydrogen pool are included; the multi-pool combined structure is arranged in the shell; the plurality of cooling cavity inlet distribution manifolds are connected with the cooling cavity liquid inlets in the multi-pool combined structure; the plurality of cooling cavity outlet distribution manifolds are connected with the cooling cavity liquid outlets in the multi-pool combined structure; a hydrogen confluence output port is formed in the upper end of the shell, and a hydrogen cavity purging inlet and a hydrogen cavity purging outlet are formed in the shell; a hydrolysate inlet and a hydrolysate outlet are formed in the bottom of the shell. The solid hydrogen storage density can be effectively improved through the solid hydrogen pool of the multi-cavity composite polar plate, meanwhile, water can be added to release an unstable high-hydrogen-storage-density material, the release rate of hydrogen can be effectively controlled, meanwhile, released heat in the hydrogen release process is controllable, safety accidents are reduced, and safety is improved.

The utility model relates to the technical field of solid hydrogen storage and transportation, in particular to a magnesium-based metal solid hydrogen storage device. In order to solve the technical problems in the prior art, the utility model provides a magnesium-based metal solid hydrogen storage device which is high in mass hydrogen storage density, large in hydrogen storage capacity, high in heat exchange efficiency and good in safety. The hydrogen storage device comprises a tank body and a hydrogen supply pipe, wherein one end of the hydrogen supply pipe is inserted into the tank body, a hole is formed in the pipe wall, and the other end of the hydrogen supply pipe extends out of the tank body; a plurality of U-shaped heat exchange tubes are arranged in the tank body, the vertical parts of all the U-shaped heat exchange tubes are uniformly distributed at intervals in the circumferential direction, the central points of the horizontal parts are located on the axis of the tank body, and two ports of each U-shaped heat exchange tube extend out of the tank body; the U-shaped heat exchange tube is used for adjusting the temperature in the tank body; a plurality of layers of heat exchange fin groups are distributed in the tank body along the axis direction; magnesium-based hydrogen storage alloy is filled in the tank body to serve as a solid hydrogen storage material.