The invention provides a
zinc-doped aluminum
oxide-
metal lithium composite negative
electrode and a preparation method thereof, and belongs to the field of
lithium battery negative electrodes. The method comprises the steps that an HEDP solution serves as an
electrolyte, a pretreated aluminum sheet serves as an
anode, and an oxidation film is formed on the surface of the aluminum sheet through constant-current gradient
anodic oxidation; the aluminum sheet is arranged at the bottom of a tank and buried in
zinc impregnation
powder for hot
zinc impregnation, and a zinc-doped
aluminum substrate with a zinc impregnation face is obtained;
coating the sherardizing surface with resin,
polishing the back surface of the sherardizing surface to remove an oxidation film and
expose an aluminum base, and
welding an aluminum wire to form a lead; a NaCl solution is adopted as an
electrolyte, the zinc-doped
aluminum substrate is adopted as an
anode, constant-
voltage electrolysis is performed to achieve membrane-substrate separation, after current returns to zero, the
aluminum substrate is taken out, resin is removed, and zinc-doped aluminum
oxide with a three-dimensional porous framework is obtained; and molten
lithium is in contact with the edge of the zinc-doped aluminum
oxide for 3-5 min. According to the invention, the zincizing
alumina film is integrated into the battery negative
electrode as a three-dimensional porous skeleton, so that the problems of obvious volume fluctuation and
lithium dendrite growth of the existing
lithium battery negative
electrode in charge-
discharge circulation are solved.