Slurry of high-performance aluminum nitride ceramic substrate and preparation method thereof
A high-performance technology of aluminum nitride ceramics, which is applied in the field of preparation of aluminum nitride ceramic substrates, can solve the problems of difficult processing, soft aluminum nitride ceramic substrates, etc., to solve the problem of being unfriendly to people and the environment, and to promote sintering density The effect of sintering and lowering the sintering temperature
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Embodiment 1
[0026] A slurry for a high-performance aluminum nitride ceramic substrate, consisting of the following components by mass: 100 parts of aluminum nitride powder, 1-8 parts of sintering aid, 0.1-4 parts of sialon particles, 1- 6 parts of dispersant, 38-68 parts of solvent, 3-12 parts of binder and 3-10 parts of plasticizer; the sintering aid is composed of the following parts by mass: 0-8 parts of Y 2 o 3 , 0-5 copies of Sm 2 o 3 , 0-1 part of La 2 o 3 and 0.05-3 parts of metal aluminum powder; the solvent is one or more of absolute ethanol, isopropanol and n-butanol.
[0027] Preferably, the sintering aid is composed of the following components in parts by mass: 1-6 parts of Y 2 o 3 , 0-5 copies of Sm 2 o 3 , 0-1 part of La 2 o 3 And 0.05-3 parts of metal aluminum powder.
[0028] More preferably, Y in the sintering aid 2 o 3 、Sm 2 o 3 and metallic aluminum powder according to Y 2 o 3 : Sm 2 o 3 : metal aluminum powder = 1: (0.1-0.5): (0.1-0.5) mixing; the pa...
Embodiment 2
[0033] A method for preparing a high-performance aluminum nitride ceramic substrate, comprising the following steps performed in sequence:
[0034] S1: Prepare the slurry for the above-mentioned high-performance aluminum nitride ceramic substrate: add aluminum nitride powder, sintering aid, dispersant and solvent into the ball mill tank according to the required mass parts, and : Sialon ceramic balls = 1:1-6 ratio, add Sialon ceramic balls to the ball mill jar, and add binder and plasticizer after ball milling for 6-20 hours at the ball milling speed of 250-500r / min , continue ball milling for 6-20h to obtain slurry.
[0035]S2: Defoaming: add 0.1-2 parts by mass of a defoaming agent to the slurry, vacuum negative pressure defoaming for 10-50 minutes, and then filter to obtain a casting slurry.
[0036] S3: Tape casting: transfer the casting slurry to a tape casting machine to form a green tape, after drying the green tape, punch and cut it to form a green body.
[0037] S4:...
Embodiment 3
[0040] A method for preparing a high-performance aluminum nitride ceramic substrate, comprising the following steps performed in sequence:
[0041] S1: Prepare the slurry for the above-mentioned high-performance aluminum nitride ceramic substrate: add aluminum nitride powder, sintering aid, dispersant and solvent into the ball mill tank according to the required mass parts, and : Sialon ceramic balls = 1:1-6 ratio, add Sialon ceramic balls to the ball mill jar, and add binder and plasticizer after ball milling for 6-20 hours at the ball milling speed of 250-500r / min , continue ball milling for 6-20h to obtain slurry, the viscosity of the slurry can be controlled at 7000-14500cps.
[0042] The sialon ceramic ball contains at least 39wt% alpha sialon phase. The sialon particles introduced by ball milling are used as a dispersion toughening system, which can effectively improve the mechanical properties of aluminum nitride ceramics and maintain high thermal conductivity. The add...
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