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Slurry of high-performance aluminum nitride ceramic substrate and preparation method thereof

A high-performance technology of aluminum nitride ceramics, which is applied in the field of preparation of aluminum nitride ceramic substrates, can solve the problems of difficult processing, soft aluminum nitride ceramic substrates, etc., to solve the problem of being unfriendly to people and the environment, and to promote sintering density The effect of sintering and lowering the sintering temperature

Active Publication Date: 2021-02-19
GUANGDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to reduce the pollution problem of aluminum nitride ceramic substrate tape-casting molding process, and to solve the current problem of soft aluminum nitride ceramic substrate substrate and difficult processing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A slurry for a high-performance aluminum nitride ceramic substrate, consisting of the following components by mass: 100 parts of aluminum nitride powder, 1-8 parts of sintering aid, 0.1-4 parts of sialon particles, 1- 6 parts of dispersant, 38-68 parts of solvent, 3-12 parts of binder and 3-10 parts of plasticizer; the sintering aid is composed of the following parts by mass: 0-8 parts of Y 2 o 3 , 0-5 copies of Sm 2 o 3 , 0-1 part of La 2 o 3 and 0.05-3 parts of metal aluminum powder; the solvent is one or more of absolute ethanol, isopropanol and n-butanol.

[0027] Preferably, the sintering aid is composed of the following components in parts by mass: 1-6 parts of Y 2 o 3 , 0-5 copies of Sm 2 o 3 , 0-1 part of La 2 o 3 And 0.05-3 parts of metal aluminum powder.

[0028] More preferably, Y in the sintering aid 2 o 3 、Sm 2 o 3 and metallic aluminum powder according to Y 2 o 3 : Sm 2 o 3 : metal aluminum powder = 1: (0.1-0.5): (0.1-0.5) mixing; the pa...

Embodiment 2

[0033] A method for preparing a high-performance aluminum nitride ceramic substrate, comprising the following steps performed in sequence:

[0034] S1: Prepare the slurry for the above-mentioned high-performance aluminum nitride ceramic substrate: add aluminum nitride powder, sintering aid, dispersant and solvent into the ball mill tank according to the required mass parts, and : Sialon ceramic balls = 1:1-6 ratio, add Sialon ceramic balls to the ball mill jar, and add binder and plasticizer after ball milling for 6-20 hours at the ball milling speed of 250-500r / min , continue ball milling for 6-20h to obtain slurry.

[0035]S2: Defoaming: add 0.1-2 parts by mass of a defoaming agent to the slurry, vacuum negative pressure defoaming for 10-50 minutes, and then filter to obtain a casting slurry.

[0036] S3: Tape casting: transfer the casting slurry to a tape casting machine to form a green tape, after drying the green tape, punch and cut it to form a green body.

[0037] S4:...

Embodiment 3

[0040] A method for preparing a high-performance aluminum nitride ceramic substrate, comprising the following steps performed in sequence:

[0041] S1: Prepare the slurry for the above-mentioned high-performance aluminum nitride ceramic substrate: add aluminum nitride powder, sintering aid, dispersant and solvent into the ball mill tank according to the required mass parts, and : Sialon ceramic balls = 1:1-6 ratio, add Sialon ceramic balls to the ball mill jar, and add binder and plasticizer after ball milling for 6-20 hours at the ball milling speed of 250-500r / min , continue ball milling for 6-20h to obtain slurry, the viscosity of the slurry can be controlled at 7000-14500cps.

[0042] The sialon ceramic ball contains at least 39wt% alpha sialon phase. The sialon particles introduced by ball milling are used as a dispersion toughening system, which can effectively improve the mechanical properties of aluminum nitride ceramics and maintain high thermal conductivity. The add...

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PUM

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Abstract

The invention provides slurry of a high-performance aluminum nitride ceramic substrate and a preparation method thereof. The slurry is prepared from the following components in parts by mass: 100 parts of aluminum nitride powder, 1-8 parts of a sintering aid, 0.1-4 part of sialon particles, 1-6 parts of a dispersing agent, 38-68 parts of a solvent, 3-12 parts of a binder and 3-10 parts of a plasticizer. The sintering aid is prepared from the following components in parts by mass: 0-8 parts of Y2O3, 0-5 parts of Sm2O3, 0-1 part of La2O3 and 0.05-3 part of metal aluminum powder; wherein the solvent is one or more of absolute ethyl alcohol, isopropanol and n-butyl alcohol. Sialon particles are dispersed in a slurry system to play a toughening role; the multi-element sintering aid is helpful for reducing the sintering temperature and promoting the sintering compactness; the metal aluminum powder can react with oxygen impurities, the heat conductivity is effectively improved, generation ofaluminum nitride is facilitated in the nitrogen atmosphere, and sintering densification is further promoted. The product is applied to alcohol and other non-toxic, low-toxicity and low-cost solvents for replacing benzene, ketone and other toxic solvents, and the problem that preparation of the aluminum nitride ceramic is not friendly to human beings and the environment is solved.

Description

technical field [0001] The invention relates to the technical field of preparation of an aluminum nitride ceramic substrate, in particular to a slurry and a preparation method of a high-performance aluminum nitride ceramic substrate. Background technique [0002] With the development of high-power and ultra-large-scale integrated circuits, the heat dissipation requirements between integrated circuits and substrates are getting higher and higher, so substrate materials need to have higher thermal conductivity and resistivity. [0003] Aluminum nitride (A1N) is a covalent bond compound with a hexagonal wurtzite structure. It has high thermal conductivity, good high-temperature insulation and dielectric properties, high material strength at high temperatures, and a thermal expansion coefficient that matches semiconductor silicon materials. With a series of advantages such as non-toxicity, it has become an ideal heat dissipation material for electronic packaging and a high-perfo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/582C04B35/622C04B35/626C04B35/638C04B35/64
CPCC04B35/581C04B35/622C04B35/62625C04B35/6264C04B35/638C04B35/64C04B2235/3869C04B2235/3225C04B2235/3227C04B2235/3224C04B2235/402C04B2235/5436C04B2235/96C04B2235/9607
Inventor 伍尚华林坤吉丁达飞林立甫黎业华盛鹏飞李建斌
Owner GUANGDONG UNIV OF TECH
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