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High-energy-storage power battery and preparation method

A power battery and high energy storage technology, which is applied in the field of electrochemistry, can solve the problems of volume expansion, the first charge and discharge efficiency has not been effectively improved, and achieve the effect of high specific energy, excellent cycle life, and increased charge and discharge cycle times

Inactive Publication Date: 2021-03-05
SHANDONG JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although the volume expansion problem of silicon has been solved, the efficiency of the first charge and discharge has not been effectively improved
Publication No. CN109686941A "A Method for Preparing Silicon-Carbon Negative Material for Lithium-ion Power Batteries" uses the activity of magnesium powder to reduce silicon oxide by ball milling, and compound-coats the composite material obtained by ball milling through the hydrothermal reaction of glucose aqueous solution After treatment, the obtained electrode material maintains a high capacity level in a long cycle, but silicon still has the problem of volume expansion during the charging and discharging process of the battery.

Method used

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Embodiment 1

[0049] The preparation steps of the power battery of the present invention are as follows:

[0050] Step 1: Prepare the positive electrode part. Specifically include the following steps:

[0051] Step 11: The step of preparing the positive electrode sheet. The raw materials used in the preparation of positive electrodes mainly include: N-methylpyrrolidone (NMP), polyvinylidene fluoride (PVDF), carbon nanotubes, activated carbon, graphene, and aluminum foil.

[0052] Step 111: Prepare PVDF binder: dry a certain amount of PVDF powder in a vacuum oven at 80°C for 2 hours to remove moisture, then mix it with a certain amount of NMP, and stir at 60°C for 1 hour to form a transparent gel binder.

[0053] Step 112: Aluminum foil with a thickness of 15 μm is used as the matrix material when preparing the positive electrode sheet, and the carbon composite material is used as a reinforcement material to enhance the discharge performance of the positive electrode. When preparing, fir...

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Abstract

The invention discloses a high-energy-storage power battery and a preparation method thereof. The high-energy-storage power battery is formed by assembling a positive electrode part, a negative electrode part, electrolyte and a diaphragm. The positive electrode part, the diaphragm and the negative electrode part are sequentially arranged from bottom to top, and the positive electrode part comprises a positive electrode piece protective layer, a positive electrode active substance layer and a positive electrode piece which are sequentially stacked from bottom to top. The negative electrode partcomprises a negative electrode plate, a negative electrode active material layer and a negative electrode plate protective layer which are sequentially stacked from bottom to top, the positive electrode plate comprises a positive electrode part base material and a carbon composite material, the negative electrode plate comprises a negative electrode part base material and a carbon composite material, and the positive electrode active material layer comprises lithium nickel cobalt manganate, lithium iron phosphate and high-specific-volume tantalum powder. The negative electrode active materiallayer includes a carbon-silicon composite material. The high-energy-storage power battery disclosed by the invention can achieve the effects of no short-circuit fault, no melting combustion fault andno burning explosion fault, the charging target value is more than 85% of the rated capacity within 15-30 minutes, and the minimum charging and discharging cycle is more than 3000 times.

Description

technical field [0001] The invention relates to the technical field of electrochemistry, in particular to a high energy storage power battery and a preparation method. Background technique [0002] Clean energy such as solar energy and wind energy is widely used around the world and is the main form of next-generation energy utilization, but their disadvantage is the intermittent energy supply problem; energy storage for field facilities (such as communication base stations) is also an urgent problem to be solved. Therefore, it is particularly important to find energy storage devices with high specific capacity. On the other hand, with the strengthening of people's awareness of environmental protection and the continuous consumption of fossil non-renewable resources, it has become an inevitable trend of development for electric vehicles to replace traditional vehicles, which also increases the demand for high energy density and high power density power batteries. [0003] M...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0525H01M4/38H01M4/587H01M4/62H01M10/058
CPCH01M10/0525H01M4/386H01M4/587H01M4/625H01M4/628H01M10/058Y02E60/10Y02P70/50
Inventor 王明雨王兆坤张少君
Owner SHANDONG JIAOTONG UNIV
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