Low-cost shale gas fracturing flow-back fluid treatment system and treatment method
A technology of treatment system and flowback liquid, applied in mining wastewater treatment, chemical instruments and methods, water/sewage multi-stage treatment, etc., can solve problems such as high cost and low recovery rate
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Embodiment 1
[0042] Such as figure 1 As shown, a low-cost shale gas fracturing flowback fluid treatment system includes a gel breaking and impurity removal system 2, a high-pressure nanofiltration membrane system 4 and a high-pressure reverse osmosis membrane system 7, and the input terminal of the gel breaking and impurity removal system 2 is connected to Through the fracturing flowback fluid delivery pipeline, its output end is connected to the high-pressure nanofiltration membrane system 4, and the figure 1 Among them, the input end of the gel breaking and impurity removal system 2 is connected to the raw water tank 1, and its output end is connected to the high-pressure nanofiltration membrane system 4 through the first intermediate water tank 3. The raw water tank 1 is used for temporarily storing the fracturing flowback fluid. At the same time, it is convenient to output a stable flow of fracturing flowback fluid to the gel breaking and impurity removal system 2. Correspondingly, the...
Embodiment 2
[0059] Example 2 is the same as Embodiment 1, except that the gel breaker added in the process of breaking and removing impurities is a composite gel breaker of sodium hypochlorite and active agent B, and the mass ratio of sodium hypochlorite to active agent B is 2.25:1. The dosage of compound gel breaker is 1.45%. Under the condition of reaction temperature of 20-35℃, the gel breaking reaction time is 1.6h. The viscosity of wastewater is 3.4mPa·S, which can directly enter the impurity removal membrane system to remove oil and suspended solids and other impurities.
Embodiment 3
[0061] Embodiment 3 is identical with implementation 1, and its difference is that, high-pressure nanofiltration membrane is high-pressure roll-type nanofiltration membrane, and the membrane area of high-pressure roll-type nanofiltration membrane is far greater than disc tube type nanofiltration membrane, can obviously save investment, and The operating pressure can also reach 40-100bar, and the recovery rate can reach 85%-90%. In Example 3, the COD concentration of the fracturing flowback fluid is above 4300mg / L, calcium is 3000mg / L, magnesium is 280mg / L, sulfate radical is 54mg / L, and chloride ion is about 12700mg / L. After separation, small molecular organic matter and chloride in the water enter the product water through the membrane, and the COD in the product water is reduced to 550mg / L, calcium 25mg / L, magnesium 2.8mg / L, and sulfate radical is less than 5mg / L. Most of the organic matter, Calcium, magnesium, sulfate, etc. are trapped in the concentrated solution, which ...
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