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Preparation method and application of nano carbon dioxide trapping agent

A carbon dioxide and scavenger technology, applied in chemical instruments and methods, separation methods, other chemical processes, etc., can solve problems such as inability to directly use plant leaves, limited adsorption capacity, and unsuitable high temperature use.

Active Publication Date: 2021-05-14
BEIJING FAIRVIEW NEW TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Non-carbonaceous adsorbents include: zeolite and quartz, the advantages are cheap, the disadvantages are easy moisture absorption, high regeneration energy consumption, and poor adsorption performance; metal organic framework MOFs, the advantage is that the pore size is easy to control, the disadvantage is high cost, not suitable for high temperature Use, alkali metal-based materials K, Na, etc., the advantage is that it can absorb carbon dioxide in a humid environment, the disadvantage is poor adsorption performance, high desorption energy consumption, metal oxide carbonate materials CaO, MgO, etc., the advantage is that the adsorbent before combustion, The disadvantage is the need for continuous addition of adsorbent
[0005] Carbonaceous adsorbents include: ordered porous carbon, which has the advantages of high chemical stability, easy modification of pore size and surface, and uniform pore size distribution. The disadvantage is poor selectivity. Activated carbon fibers ACFs have the advantages of nanostructure and many micropores, but It is only used to treat granular and powder materials. Activated carbon has the advantages of unique water resistance, stability, and easy regeneration. The disadvantage is that the adsorption capacity is limited and the particle size is large.
[0006] Neither non-carbonaceous adsorbents nor carbonaceous adsorbents can be directly used on plant leaves; in addition, liquid amine and alcohol amine solutions are currently used to directly absorb carbon dioxide. This method has high adsorption capacity, good selectivity, and high efficiency. There are still inherent shortcomings such as high cost, corrosion of equipment, difficulty in recovery, easy volatility, and poor cycle performance.

Method used

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  • Preparation method and application of nano carbon dioxide trapping agent
  • Preparation method and application of nano carbon dioxide trapping agent
  • Preparation method and application of nano carbon dioxide trapping agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The preparation method of nano carbon dioxide capture agent specifically comprises the following steps:

[0045] 1. The first step: according to the ratio of m (diatomaceous earth): m (dodecyltrimethylammonium bromide (DTAB))=3:1, dissolve them in deionized water with a mass volume ratio of 11g / L, and add In a reaction kettle with a heating jacket, the rotation speed is 600r / min, heated and stirred at 80°C for 1h, and the pH=8 is adjusted with ethanolamine (MEA) to obtain dodecyltrimethylammonium bromide (DTAB) modified organic diatomite ;

[0046] 2. The second step: Dissolve chitosan in acetic acid (concentration 5%) according to the proportion (mass volume ratio 100g / L), add it into the reaction kettle with heating jacket, rotate at 500r / min, heat and stir at 60°C completely Dissolve; according to the ratio m (chitosan): m (dodecyltrimethylammonium bromide (DTAB)) = 9: 1, rotate at 450r / min, heat and stir at 70°C for 1h to dissolve completely, add ethanolamine (MEA ...

Embodiment 2

[0051] The preparation method of nano carbon dioxide capture agent specifically comprises the following steps:

[0052] 1. The first step: according to the ratio m (kaolin): m (octadecyltrimethylammonium bromide (CTMAB)) = 1:1, dissolve them in deionized water (mass volume ratio 14g / L), add In a reaction kettle with a heating jacket, rotate at 500r / min, heat and stir at 70°C for 2h, adjust pH=8 with diethanolamine (DEA), and obtain octadecyltrimethylammonium bromide (CTMAB) modified organic kaolin;

[0053] 2. The second step: Dissolve chitosan in acetic acid (concentration 5%) in proportion (mass volume ratio 100g / L), add it to the reaction kettle with heating jacket, rotate at 500r / min, heat and stir at 70°C completely Dissolve; according to the ratio of m (chitosan): m (octadecyltrimethylammonium bromide (CTMAB)) is 11:1, the rotation speed is 500r / min, heated and stirred at 60°C to dissolve completely, dropwise add diethanolamine (DEA ) until completely dissolved, adjust ...

Embodiment 3

[0058] The preparation method of nano carbon dioxide capture agent specifically comprises the following steps:

[0059] 1. The first step: according to the ratio of m (bentonite): m (cetyltrimethylammonium bromide (CTAB)) is 2:1, dissolve in (12g / L) deionized water respectively, add the heating clamp In a reaction kettle with a cover, the rotation speed is 500r / min, heated and stirred at 70°C for 2h, and the pH=8 is adjusted with tetraethylenepentamine (TEPA) to obtain cetyltrimethylammonium bromide (CTAB) modified organobentonite;

[0060]2. The second step: Dissolve chitosan in acetic acid (concentration 5%) according to the proportion (100g / L), add it into the reaction kettle with heating jacket, rotate at 500r / min, heat and stir at 60°C to dissolve completely; press The ratio of m (chitosan): m (cetyltrimethylammonium bromide (CTAB)) is 10:1, the rotation speed is 500r / min, heated and stirred at 60°C to dissolve completely, and cetyltrimethylammonium bromide (CTAB) is adde...

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Abstract

The invention relates to a preparation method and application of a nano carbon dioxide capturing agent, and the preparation method of the nano carbon dioxide capturing agent comprises the following steps: taking cationic surface active agent modified bentonite as a carrier; the CO2 nano capturing agent prepared from the loaded cationic surface active agent modified chitosan, graphene oxide and loaded organic alkali modified hydrotalcite has the photocatalytic effect of a nano material, captures and combines carbon dioxide in air to be enriched around leaves and stems for crop absorption and utilization, enhances photosynthesis, improves the photosynthetic rate, and inhibits light respiration at night; the chlorophyll is synthesized for crop growth, three elements of carbon, hydrogen and oxygen necessary for crop growth are accumulated, organic components such as nitrogen, phosphorus and potassium in soil are effectively absorbed, synthesized and converted, inoculation, growth and maturity of crops are fully promoted, and yield and income are increased. The CO2 trapping agent can be used for facility crops and field crops, and the CO2 trapping agent at normal temperature and normal pressure has wide application.

Description

technical field [0001] The invention relates to a carbon dioxide capture agent, in particular to a preparation method of a nanometer carbon dioxide capture agent and its application in plant photosynthesis, and belongs to the field of carbon dioxide capture agents. Background technique [0002] Global warming has become one of the most serious problems facing the world. The massive emission of greenhouse gases is the main cause of global warming. The greenhouse effect gases mainly include carbon dioxide (CO 2 ), methane (CH 4 ), nitrous oxide (N 2 O) and other gases, carbon dioxide has the greatest effect on the greenhouse effect and the largest emission, so reducing carbon dioxide emissions is the key to slowing down global warming, so capturing and storing CO 2 is of great importance, on the other hand CO 2 is a potential chemical resource, so how to recover CO efficiently and economically 2 have important economic and social significance. [0003] At present, the met...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/24B01J20/30B01D53/02
CPCB01J20/24B01D53/02B01D2257/504Y02C20/40B01J20/0207B01J20/043B01J20/3021B01J20/12B01J20/3085B01J20/14B01J20/205C05D9/00
Inventor 苏斌苏文锦苏文雯
Owner BEIJING FAIRVIEW NEW TECH CO LTD
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