Preparation method of environment-friendly organic-inorganic compound fertilizer
An environment-friendly, compound fertilizer technology, applied in the direction of inorganic fertilizers, calcium fertilizers, fertilization devices, etc., can solve the problems that are not conducive to large-scale promotion and use, high hydrothermal reaction temperature, and low soluble silicon content, etc. Environmental protection, short reaction process and low price
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[0036] The invention provides a method for preparing an environment-friendly organic-inorganic compound fertilizer, which comprises the following steps:
[0037] (1) Putting silicon-rich substances and calcium-rich substances into lye, and obtaining a slurry with a pH of 9 to 13 after hydrothermal reaction;
[0038] Specifically, step (1) includes:
[0039] (1.1) Putting silicon-rich substances and calcium-rich substances into lye, hydrothermally reacting, and obtaining an intermediate slurry with a pH of 9-13;
[0040] Specifically, the silicon-rich substance is a mineral or waste residue mainly composed of silicon dioxide, such as fly ash, coal gangue, clay or quartz, but is not limited thereto. The silicon-rich substance can also be a mixture of two, three or four of the above substances.
[0041] Calcium-rich substances are industrial raw materials or waste residues mainly composed of calcium oxide, such as calcium hydroxide, lime, etc., but not limited thereto. The cal...
Embodiment 1
[0068] This embodiment provides an environment-friendly organic-inorganic compound fertilizer, the preparation method of which is as follows:
[0069] (1) Combine fly ash and lime according to CaO / SiO 2 Put the molar ratio of 1 into 0.6mol / L NaOH solution, hydrothermally react for 5 hours, and the temperature is 220°C; after the reaction is completed, cool down to 90°C to obtain a slurry with a pH of 11.3;
[0070] (2) After the humus is crushed, sieve it with an 80-mesh sieve, take the sieve material and add it to the slurry, stir and react for 10 minutes, filter and wash to obtain the product; wherein the weight ratio of the humus to the solid product in the slurry is 8:2 .
Embodiment 2
[0072] This embodiment provides an environment-friendly organic-inorganic compound fertilizer, the preparation method of which is as follows:
[0073] (1) Mix kaolin and calcium hydroxide according to CaO / SiO 2 Put the molar ratio of 1.1 into 1mol / L NaOH solution, hydrothermally react for 2 hours, and the temperature is 180°C; after the reaction is completed, cool down to 65°C to obtain a slurry with a pH of 9;
[0074] (2) After crushing the crop straw, sieve it with a 40-mesh sieve, take the sieve material and add it to the slurry, stir and react for 60 minutes, filter and wash, and obtain the product; wherein the weight ratio of the crop straw to the solid product in the slurry is 5: 5.
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