Formaldehyde-removing antibacterial coating based on titanium-based metal organic framework material and preparation method of formaldehyde-removing antibacterial coating

An organic skeleton, antibacterial coating technology, used in antifouling/underwater coatings, coatings, biocide-containing paints, etc.

Inactive Publication Date: 2021-06-01
三棵树(上海)新材料研究有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

MIL-125-NH with TiO clusters as nodes and 2-aminoterephthalic acid as organic ligands in metal-organic frameworks 2 With high specific surface area and good visible light absorption, the material is only born in the laboratory and has not been practically applied in industrial production

Method used

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  • Formaldehyde-removing antibacterial coating based on titanium-based metal organic framework material and preparation method of formaldehyde-removing antibacterial coating
  • Formaldehyde-removing antibacterial coating based on titanium-based metal organic framework material and preparation method of formaldehyde-removing antibacterial coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A aldehyde-removing antibacterial coating based on a titanium-based metal-organic framework material, which is prepared from the following components according to the following mass-number ratios: 20 parts of water, 0.2 parts of hydroxyethyl cellulose, 0.1 part of a pH regulator, and an aqueous dispersant 0.4 parts, 0.1 parts of water-based wetting agent, 0.4 parts of water-based defoamer, 16 parts of titanium dioxide, 7 parts of calcined kaolin, 10 parts of heavy calcium carbonate, 7 parts of silicon micropowder, titanium-based metal organic framework MIL-125-NH 2 4 parts, 20 parts of emulsion, 0.6 part of antifreeze, 0.5 part of coalescent and 0.1 part of preservative.

[0023] A method for preparing an anti-aldehyde coating based on a titanium-based metal-organic framework material, comprising the steps of:

[0024] At a speed of 500 rpm, add water, water-based dispersant, pH regulator, preservative, water-based wetting agent and part of defoamer, and stir for 3 minu...

Embodiment 2

[0029] A aldehyde-removing antibacterial coating based on a titanium-based metal-organic framework material, which is prepared from the following components according to the following mass-number ratios: 27 parts of water, 0.5 parts of hydroxyethyl cellulose, 0.3 parts of a pH regulator, and an aqueous dispersant 0.7 parts, 0.3 parts of water-based wetting agent, 0.7 parts of water-based defoamer, 21 parts of titanium dioxide, 11 parts of calcined kaolin, 18 parts of heavy calcium carbonate, 12 parts of silicon micropowder, titanium-based metal organic framework MIL-125-NH 2 4 parts, 28 parts of emulsion, 1.5 parts of antifreeze, 1 part of coalescent and 0.2 parts of preservative.

[0030] A method for preparing an anti-aldehyde coating based on a titanium-based metal-organic framework material, comprising the steps of:

[0031] At the speed of 500-700rpm, add water, water-based dispersant, pH regulator, preservative, water-based wetting agent and part of defoamer, and stir fo...

Embodiment 3

[0036] Adjust the rotating speed to 500rpm, add 24 parts of water, 0.3 parts of hydroxyethyl cellulose, 0.2 parts of water-based wetting agent, 0.4 parts of water-based dispersant, and 0.4 parts of water-based defoamer.

[0037] Increase the rotating speed to 900rpm, add 18 parts of titanium dioxide, 10 parts of calcined kaolin, 12 parts of heavy calcium carbonate, 8 parts of silicon micropowder, and 24 parts of titanium-based metal organic framework MIL-125-NH.

[0038]Continue to increase the rotation speed to 1300rpm, stir for 20min, after mixing evenly, reduce the rotation speed to 900rpm, continue to add 21 parts of emulsion, 0.8 parts of antifreeze, 0.6 parts of film-forming aid, 0.3 parts of water-based defoamer, and stir for 15 minutes. Get this product.

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Abstract

The invention relates to a formaldehyde-removing antibacterial coating based on a titanium-based metal organic framework material and a preparation method of the formaldehyde-removing antibacterial coating. The formaldehyde-removing antibacterial coating is prepared from the following components in parts by mass: 20 to 27 parts of water, 0.2 to 0.5 part of hydroxyethyl cellulose, 0.1 to 0.3 part of a pH regulator, 0.4 to 0.7 part of a water-based dispersing agent, 0.1 to 0.3 part of a water-based wetting agent, 0.4 to 0.7 part of a water-based defoaming agent, 16 to 21 parts of titanium dioxide, 7 to 11 parts of calcined kaolin, 10 to 18 parts of ground calcium carbonate, 7 to 12 parts of silica powder, 2 to 4 parts of a titanium-based metal organic framework MIL-125-NH2, 20 to 28 parts of an emulsion. 0.6 to 1.5 parts of an anti-freezing agent, 0.5 to 1 part of a coalescing agent and 0.1 to 0.2 part of a preservative. The formaldehyde removal efficiency reaches 91%, and the durability reaches 86.7%; and the toluene removal efficiency reaches 64%, and the durability reaches 54%.

Description

technical field [0001] The invention relates to a aldehyde-removing antibacterial coating based on a titanium-based metal organic framework material and a preparation method thereof. Background technique [0002] With the development of social economy and the improvement of people's living standards, everyone's awareness of health and environmental protection is gradually increasing, and the requirements for the safety of the living environment are also getting higher and higher. In the indoor environment, volatile organic compounds (VOCs) are the main cause of indoor air pollution, and among various VOCs, formaldehyde (HCHO) is the main harmful indoor air pollutant (Build.Environ.,2017,117,118- 126), the presence of formaldehyde is a major hazard to human health, and long-term exposure to formaldehyde may cause serious health problems, such as skin and eye irritation, neurodegenerative diseases, leukemia, pneumonia, brain tumors, and even nasopharyngeal cancer (Appl .Catal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D201/00C09D5/14C09D7/65C09D7/61
CPCC08K2003/2241C08K2003/265C09D5/14C09D201/00C09D7/61C09D7/65C08L87/00C08K3/22C08K3/346C08K3/26C08K3/36
Inventor 杨鹏飞莫世广付绍祥洪杰
Owner 三棵树(上海)新材料研究有限公司
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