Wear-resistant impact-resistant waterborne epoxy floor paint and preparation method thereof

An epoxy floor paint, impact-resistant technology, applied in the direction of epoxy resin coatings, biocide-containing paints, antifouling/underwater coatings, etc., can solve the problem of affecting the appearance of epoxy floors and the use feeling In order to improve the degree of densification, strengthen the mechanical properties and stability, and optimize the wear resistance and impact resistance of the epoxy floor, it can solve problems such as better reinforcement effect and comprehensive performance of epoxy floor.

Pending Publication Date: 2021-08-06
SUZHOU SAIRONG CONSTITUTION&DECORATION ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to further improve the wear resistance and compressive strength of epoxy floor paint, people often choose to add some fillers (such as mica powder, glass powder, etc.) to epoxy floor paint to reinforce epoxy floor paint. , but these fillers themselves have a certain degree of inertness, and their compatibility with epoxy floor paint systems is poor. Too much filler content will affect the overall performance of epoxy floors, and too little addition will not achieve the desired effect. good reinforcing effect
At the same time, due to the long-term use of epoxy floor paint, chemical bonds will break due to factors such as friction, light, heat, and oxygen, resulting in aging and yellowing of the epoxy floor, which will affect the appearance and use experience of the epoxy floor. , the fillers in the epoxy floor will also gradually detach with the aging of the epoxy floor paint, which will affect the comfort of use

Method used

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  • Wear-resistant impact-resistant waterborne epoxy floor paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] S1. Preparation of allyltriphenylphosphine bromide / graphene oxide composite:

[0040] 1) Add 15 parts of sodium ion solution to 60 parts of sulfuric acid solution, stir evenly, add 40 parts of graphene oxide, under low pressure, ultrasonically oscillate for 20 minutes, suction filter and dry at 30°C for 10 minutes to obtain a treatment oxidation Graphene;

[0041] 2) Place 30 parts of allyl triphenylphosphine bromide in 70 parts of deionized water and stir evenly, then add 15 parts of graphene oxide for primary treatment, 0.5 parts of hydrochloric acid solution with a mass fraction of 25%, and adjust the rotation speed to 700r / min, and heated at a constant temperature at 35° C., stirred for 1 h, and allowed to stand for 10 min to obtain an allyltriphenylphosphine bromide / graphene oxide composite.

[0042] S2. Preparation of quaternary ammonium salt polymer intermediate:

[0043] 1) Add 20 parts of N,N-dimethyldodecyl tertiary amine to 70 parts of epichlorohydrin, sti...

Embodiment 2

[0053] S1. Preparation of allyltriphenylphosphine bromide / graphene oxide composite:

[0054] 1) Add 20 parts of sodium ion solution to 65 parts of sulfuric acid solution, stir evenly, add 45 parts of graphene oxide, under low pressure conditions, ultrasonically shake for 30 minutes, suction filter and dry at 35°C for 15 minutes to obtain a primary treatment oxidation Graphene;

[0055] 2) After placing 45 parts of allyltriphenylphosphine bromide in 80 parts of deionized water and stirring evenly, add 20 parts of primary treatment graphene oxide, 0.8 parts of hydrochloric acid solution with a mass fraction of 30%, and adjust the speed to 800r / min, and heated at a constant temperature at 40° C., stirred for 1.5 h, and allowed to stand for 15 min to obtain an allyltriphenylphosphine bromide / graphene oxide composite.

[0056] S2. Preparation of quaternary ammonium salt polymer intermediate:

[0057] 1) Add 25 parts of N,N-dimethyldodecyl tertiary amine to 80 parts of epichloroh...

Embodiment 3

[0067] S1. Preparation of allyltriphenylphosphine bromide / graphene oxide composite:

[0068] 1) Add 25 parts of sodium ion solution to 70 parts of sulfuric acid solution, stir evenly, add 50 parts of graphene oxide, under low pressure, ultrasonically oscillate for 40 minutes, suction filter and dry at 40°C for 20 minutes to obtain a treatment oxidation Graphene;

[0069] 2) Put 60 parts of allyltriphenylphosphine bromide in 90 parts of deionized water and stir evenly, then add 25 parts of primary treatment graphene oxide and 1 part of hydrochloric acid solution with a mass fraction of 35%, and adjust the rotation speed to 900r / min, and heated at a constant temperature at 45° C., stirred for 2 h, and allowed to stand for 20 min to obtain an allyltriphenylphosphine bromide / graphene oxide composite.

[0070] S2. Preparation of quaternary ammonium salt polymer intermediate:

[0071] 1) Add 30 parts of N,N-dimethyldodecyl tertiary amine to 100 parts of epichlorohydrin, stir and ...

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Abstract

The invention discloses wear-resistant impact-resistant waterborne epoxy floor paint and a preparation method thereof. The preparation method comprises the following steps: S1, preparing an allyltriphenylphosphonium bromide/graphene oxide compound; s2, preparing a quaternary ammonium salt polymer intermediate; and S3, preparing the wear-resistant impact-resistant waterborne epoxy floor paint. According to the invention, allyltriphenylphosphonium bromide is introduced into a graphene oxide sheet layer, and an allyltriphenylphosphonium bromide molecular chain can be utilized to expand the sheet layer structure of the graphene oxide, so that the interface bonding force between the allyltriphenylphosphonium bromide/graphene oxide compound and an epoxy floor paint system is increased; the wear resistance and the impact resistance of the epoxy floor are optimized; and the special phenylphosphine structure of the allyl triphenyl phosphonium bromide has high thermal stability, so that the weather resistance of the epoxy floor paint can be greatly improved, the aging of the epoxy floor paint is prevented, and the service life of the epoxy floor paint is greatly prolonged.

Description

technical field [0001] The invention relates to the technical field of epoxy floor paint, in particular to a wear-resistant and impact-resistant water-based epoxy floor paint and a preparation method thereof. Background technique [0002] Epoxy floor paint mainly adopts the overall polymer surface layer, which is a particularly beautiful and long-lasting floor paint. Its main content is epoxy resin and curing agent, which has excellent acid and alkali corrosion resistance, waterproof, non-slip, and It is widely used in electronics factories, hardware factories, hospitals, aviation, offices, laboratories and other occasions. The surface is smooth and easy to clean, which can meet people's high requirements for cleanliness. [0003] In order to further improve the wear resistance and compressive strength of epoxy floor paint, people often choose to add some fillers (such as mica powder, glass powder, etc.) to epoxy floor paint to reinforce epoxy floor paint. , but these fille...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/14C09D7/62C09D7/63
CPCC09D163/00C09D5/14C09D7/62C09D7/63C08L79/04C08K9/02C08K3/042C08K5/50
Inventor 江勇
Owner SUZHOU SAIRONG CONSTITUTION&DECORATION ENG CO LTD
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