Magnesium-calcium gunning material suitable for smelting clean steel and its preparation method and application

A magnesia-calcium, gunning material technology, applied in the field of refractory materials, can solve the problems of short mixing time, uneven water and material, low service life, etc., to reduce the content and particle size of inclusions, burst resistance and corrosion resistance Excellent performance, the effect of improving high temperature performance

Active Publication Date: 2022-04-08
ZHEJIANG ZILI HIGH TEMPERATURE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN200910097752.2 relates to a formula of gunning material for converters, the main raw materials are forsterite, dolomite, mid-grade magnesia and binder, and there is a problem of low service life
Because the matrix contains a large amount of clay, bentonite or sodium silicate, a large amount of low-melt phase is formed at high temperature, and the amount of water added is high, which is not conducive to the corrosion resistance of molten steel and slag resistance, resulting in poor service life of the gunning material
[0005] In addition, the micropowder, binder and admixture in the semi-dry gunning material matrix are dispersed and added. Due to the difference in mixing equipment, the components in the matrix are unevenly distributed. Short, easy to cause muzzle blockage, uneven water material, cause gunning material to fall and collapse, thus affecting gunning effect

Method used

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  • Magnesium-calcium gunning material suitable for smelting clean steel and its preparation method and application
  • Magnesium-calcium gunning material suitable for smelting clean steel and its preparation method and application
  • Magnesium-calcium gunning material suitable for smelting clean steel and its preparation method and application

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Embodiment 1~5

[0040] In terms of parts by mass, 10 parts of magnesium binder (Yixing Zili Micro Powder Material Technology Co., Ltd., LIMAGEL-75 high-strength magnesium binder, particle size not greater than 5 μm, MgO content ≥ 77.00wt% in its composition, SiO 2 Content ≥ 13.00wt%, loss on ignition at 950°C ≤ 6.0wt%), 2.0 parts of sodium hexametaphosphate, 1 part of sodium tripolyphosphate, 2 parts of hydrated lime powder (particle size 5-10 μm), 0.2 parts of carboxymethyl cellulose and 0.2 parts of organic fibers were co-milled in a high-energy ball mill for 3 hours, and the speed of the ball mill was 200r / min to obtain a magnesium silicate coagulant whose particle size was not greater than 3 μm.

[0041]In terms of parts by mass, the raw material composition of magnesia-calcium gunning material is shown in Table 1. Magnesia-calcium sand (the total content of MgO and CaO is not less than 92wt%), magnesia material (MgO content ≥ 95wt%) and the above-mentioned The prepared magnesium silicate...

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Abstract

The invention discloses a magnesium-calcium gunning material suitable for smelting clean steel, a preparation method thereof and an application in smelting clean steel. In terms of parts by mass, the raw materials of magnesium-calcium gunning materials include: 10-40 parts of magnesia-calcium sand, 40-90 parts of magnesia material, 10-26 parts of magnesium silica gel coagulant; The raw materials of the agent include: 5-15 parts of magnesium binder, 2-5 parts of phosphate binder, 1-4 parts of slaked lime powder, 0.05-0.5 parts of thickener, 0.05-1.5 parts of explosion-proof agent; The particle size is not more than 5μm, and the MgO content in its composition is ≥77.00wt%, SiO 2 The content is ≥13.00wt%, and the loss on ignition at 950°C is ≤6.0wt%. The magnesium silica gel is obtained by co-grinding the raw materials that make it up, and the particle size is not greater than 3μm. The preparation method comprises: stirring evenly the raw materials constituting the magnesia-calcium gunning material including magnesia-calcium sand, magnesia material and magnesium-silica coagulant in a mixer to obtain the magnesia-calcium gunning material.

Description

technical field [0001] The invention relates to the technical field of refractory materials, in particular to a magnesium-calcium gunning material suitable for smelting clean steel and its preparation method and application. Background technique [0002] With the continuous development of steelmaking technology, it is important to promote high-performance advanced refractory materials with high efficiency, energy saving, functionalization, long life and safety, reduce the consumption and cost of refractory materials, and increase the service life of working linings in converters, ladles, RH furnaces and tundishes. It is an inevitable trend. At present, gunning and maintenance of furnace lining materials is one of the important measures to prolong the service life and reduce the consumption of refractory materials. [0003] However, with the increase of high-grade special steel varieties, especially the sharp increase in demand for clean steel, aluminum-killed steel and silic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66C04B35/043C21C5/44C21C7/076C21C7/10B22D41/02C04B35/632C04B35/636
CPCC04B35/66C04B35/043C04B35/6365C04B35/636C04B35/632C21C5/443C21C7/10B22D41/023C21C7/076C04B2235/3208C04B2235/447C04B2235/5212C04B2235/402Y02P10/20
Inventor 刘光平李媛媛宋雅楠王玉龙程文雍沈明科尹明强罗明
Owner ZHEJIANG ZILI HIGH TEMPERATURE TECH CO LTD
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