White copper-based antibacterial master batch for fibers, and preparation method thereof
An antibacterial masterbatch, white technology, applied in the chemical characteristics of fibers, rayon manufacturing, textiles and papermaking, etc., can solve the problems of different copper valence states and existing states, narrowing of fiber application range, and large color differences, etc., to achieve repeatable High performance, widen the dyeing range, and excellent washing resistance
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Embodiment 1
[0049]A white copper-based antibacterial masterbatch for fibers, which is composed of 0.4% nano copper-nickel alloy antibacterial agent, 99% PP, 0.2% low molecular weight wax, 0.2% oleic acid and 0.2% antioxidant 1010. Wherein, the average particle size of the nano-copper-nickel alloy antibacterial agent is 200nm, and is coated with oleic acid and dispersed.
[0050] The preparation method of this antibacterial masterbatch comprises the steps:
[0051] (1) Grinding: add PP into the mill to grind into PP powder;
[0052] (2) Weighing: take by weight nano-copper-nickel alloy antibacterial agent, PP powder, low molecular wax, oleic acid, antioxidant 1010;
[0053] (3) Mixing: Add 0.4% nano-copper-nickel alloy antibacterial agent, 99% PP powder, 0.2% low-molecular wax, 0.2% oleic acid and 0.2% antioxidant 1010 to a high-speed mixer for high-low speed Mixing, wherein the low-speed mixing speed is 700 rpm, the mixing time is 2 minutes, the high-speed mixing speed is 1400 rpm, and ...
Embodiment 2
[0057] A white copper-based antibacterial masterbatch for fibers, consisting of 1% nano-iron-copper-nickel alloy antibacterial agent, 98.1% PA6, 0.3% silane coupling agent KH560, 0.3% fatty acid and 0.3% antioxidant 1098 , wherein the average particle size of the nano-iron-copper-nickel alloy antimicrobial agent is 300nm, and it is dispersed through fatty acid coating. The extrusion temperature is 250° C., and the other preparation conditions and preparation methods are the same as in Example 1.
Embodiment 3
[0059] A white copper-based antibacterial masterbatch for fiber, composed of 3% nanometer zinc-copper-nickel alloy antibacterial agent, 95.5% PA66, 0.5% phthalate coupling agent, 0.5% ascorbic acid and 0.5% antioxidant 168 Composition, wherein, the average particle size of the nano-zinc-copper-nickel alloy antibacterial agent is 600nm, and is coated with ascorbic acid and dispersed. The extrusion temperature is 275° C., and the other preparation conditions and preparation methods are the same as in Example 1.
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