Cement-based pollutant-blocking grouting material and preparation method thereof
A technology for grouting materials and pollutants, applied in the field of cement-based pollutant blocking grouting materials and preparation, can solve problems such as application limitations, inability to prevent and control deep groundwater pollution, and no mention of preventing the spread of pollution sources. , to achieve the effect of large coating thickness, good removal effect and small foaming pores
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[0033] In yet another specific embodiment of the present invention, the present invention provides the above-mentioned method for preparing the cement-based pollutant blocking grouting material, comprising the following steps:
[0034] 1. Ordinary Portland cement 40-50%, calcium oxide 2-5%, gas-generating coated particles 1-2%, sodium silicate 8-13%, basalt fiber 1-2%, guar gum 0.5- 1%, Sodium Dodecyl Sulfonate 0.1-0.5% is crushed in a crusher to make mixed powder.
[0035] 2. Add active fillers to the mixed powder and then crush to make active mixed powder.
[0036] 3. Add water to the active mixed powder, stir quickly and evenly to make grouting liquid.
[0037] Further, in step 1, the mixed powder is stirred for 20 seconds at a stirring speed of 500 r / min.
[0038] Further, in step 2, the active mixed powder is stirred at a stirring speed of 500r / min for 3s.
Embodiment 1
[0047] This embodiment provides a cement-based mine pollutant blocking material that can be used in underground water passages, including the following components by mass percentage: 37.5% of ordinary 42.5 Portland cement, 30% of water, 5% of calcium oxide, active 15% filler, 1% gas-coated particles, 8% sodium silicate, 2% basalt fiber, 1% guar gum, 0.5% sodium lauryl sulfonate. The active filler is composed of the following components in mass percentage: 60% of zero-valent iron, 25% of magnetite and 15% of activated carbon. Stir the above raw materials evenly and pour them into the infiltration mold.
[0048] After testing, the average pore diameter of the material is 0.12mm, the porosity is 67.25%, the initial setting time is 6.5min, the final setting time is 3.5h, the 1d strength is 2.25Mpa, and the permeability coefficient is 3.7×10 -3 cm / s, 25℃, 1g material in 20mg / L Cr 6+ 、Cd 2+ In the solution for 12h (at 25°C, stirring 300r / min), the removal rates of the above two i...
Embodiment 2
[0050] This embodiment provides a cement-based mine pollutant blocking material that can be used in underground water passages, including the following components by mass percentage: 35% of ordinary 42.5 Portland cement, 22% of water, 5% of calcium oxide, active 15% filler, 2% gas-coated particles, 8% sodium silicate, 2% basalt fiber, 0.5% guar gum, 0.5% sodium dodecyl sulfonate. The active filler is composed of the following components in mass percentage: 65% of zero-valent iron, 20% of magnetite, and 15% of activated carbon. Stir the above raw materials evenly and pour them into the infiltration mold.
[0051] After testing, the average pore diameter of the material is 0.15mm, the porosity is 68.31%, the initial setting time is 6.0min, the final setting time is 3.4h, the 1d strength is 2.62Mpa, and the permeability coefficient is 3.8×10 -3 cm / s, 1g material in 20mg / L Cr 6+ 、Cd 2+ In the solution for 12h (at 25°C, stirring 300r / min), the removal rates of the above two ions...
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