Front aluminum paste suitable for N-type TOPCon battery and preparation method of front aluminum paste

A battery and aluminum paste technology, applied in the field of solar cells, can solve the problems of no Voc gain, less formation of P+ layer, high cost, etc., and achieve the effects of excellent corrosion, enhanced corrosion, and improved open circuit voltage.

Pending Publication Date: 2022-03-18
JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Defects and insufficiencies of the existing technology: currently the positive silver-aluminum paste on the market mainly provides a good contact effect after sintering, cannot or rarely forms a P+ layer, and has almost no gain to Voc; on the other hand, the silver paste has always been a non-silicon The cost occupies a large proportion, and its high cost is ultimately not conducive to the grid parity of photovoltaics

Method used

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  • Front aluminum paste suitable for N-type TOPCon battery and preparation method of front aluminum paste

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A front aluminum paste suitable for N-type TOPCon batteries is prepared from the following components according to mass percentage:

[0025] Aluminum powder 70%: spherical, particle size 1μm, D100<10μm, oxygen content 0.4%;

[0026] Group III nanometer metal powder and its alloy powder 5.5%: the specific table is 14m 2 / g. Contains: 2% aluminum-silicon alloy powder, 3% aluminum-boron alloy powder;

[0027] Main glass powder 1%: average particle size 0.5μm, softening point 320°C, composition is lead oxide 90%, silicon oxide 1%, boron oxide 4%, zinc oxide 4%, gallium oxide 1%;

[0028] Secondary glass powder 0.5%: average particle size 0.5μm, softening point 420°C, components are barium oxide 40%, strontium oxide 10%, antimony trioxide 6%, silicon oxide 4%, boron oxide 20%, zinc oxide 10% %, gallium oxide 10%;

[0029] The above is the solid content, and the solid content is 77%.

[0030] Organic carrier 21%: the main components are resin and solvent, which are mixed...

Embodiment 2

[0037] A front aluminum paste suitable for N-type TOPCon batteries is prepared from the following components according to mass percentage:

[0038] Aluminum powder 73%: spherical, particle size 3μm, D100<10μm, oxygen content 0.2%;

[0039] Group III nanometer metal powder and its alloy powder 3%: ratio table 20m 2 / g. Contains: 2% boron powder, 1% indium powder, etc.;

[0040] Main glass powder 4%: average particle size 2μm; softening point 430°C, composition is lead oxide 50%, bismuth oxide 30%, silicon oxide 10%, boron oxide 6%, aluminum oxide 1%, titanium oxide 3%;

[0041] Secondary glass powder 2%: average particle size 2μm; softening point 580°C, composition is barium oxide 10%, calcium oxide 20%, silicon oxide 10%, boron oxide 30%, aluminum oxide 4%, zinc oxide 20%, oxide Titanium 6%;

[0042] The above is the solid content, and the solid content is 82%.

[0043] Organic carrier 10%: the main components are resin and solvent, mix, heat and stir the two, and boil at...

Embodiment 3

[0053] A front aluminum paste suitable for N-type TOPCon batteries is prepared from the following components according to mass percentage:

[0054] Aluminum powder 75%: spherical, particle size 2μm, D100<10μm, oxygen content 0.3%;

[0055] Group III nanometer metal powder and its alloy powder 1%: ratio table 20m 2 / g. Contains: 1% indium powder, etc.;

[0056] Main glass powder 3%: average particle size 1μm; softening point 380°C, composition is lead oxide 60%, bismuth oxide 10%, silicon oxide 5%, boron oxide 15%, zinc oxide 5%, titanium oxide 5%;

[0057]Secondary glass powder 1%: average particle size 1μm; softening point 500°C, components are 20% barium oxide, 30% strontium oxide, 9% antimony trioxide, 1% silicon oxide, 10% boron oxide, 30% zinc oxide ;

[0058] The above is the solid content, and the solid content is 80%.

[0059] Organic carrier 15%: the main components are resin and solvent, mix, heat and stir the two, and boil at 70°C;

[0060] The resin accounts ...

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Abstract

The invention provides front aluminum paste suitable for an N-type TOPCon battery, which is prepared from the following components in percentage by mass: 70 to 75 percent of aluminum powder, 1 to 6 percent of III-group nano metal powder and alloy powder thereof, 1 to 4 percent of main glass powder, 0.5 to 2 percent of secondary glass powder, 10 to 22 percent of organic carrier, 0.5 to 2 percent of dispersing agent, 0.5 to 2 percent of thixotropic agent, 0 to 2 percent of slipping agent, 0 to 2 percent of inorganic additive and 0 to 2 percent of fluoride. According to the method, the aluminum paste is used as the N-type TOPCon front paste, the good contact effect is provided, the P + layer is formed, the open-circuit voltage is remarkably improved by 10 mV or above, and the cost is relatively reduced by 90% or above.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to a front aluminum paste suitable for N-type TOPCon cells and a preparation method thereof. Background technique [0002] The development of solar technology is changing with each passing day, and new cell technologies and processes are constantly emerging. The current PERC process will eventually be replaced by HJT or Topcon (Tunnel Oxide Passivating Contacts) tunnel oxide passivating contact cells. Compared with HJT, Topcon technology has the advantages of low cost of ownership and good inheritance with PERC technology. It is still the mainstream of solar cell technology in the past 3-5 years. At present, the conductive paste used for front metallization of Topcon batteries is mainly silver-aluminum paste. [0003] Defects and insufficiencies of the existing technology: currently the positive silver-aluminum paste on the market mainly provides a good contact effect after sin...

Claims

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Application Information

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IPC IPC(8): H01B1/22H01B13/00H01L31/0224
CPCH01B1/22H01B13/00H01L31/0224
Inventor冷青松刘瑞鸿丰昭耿心彤许飞赵军
OwnerJIANGSU ZHENGNENG ELECTRONICS TECH CO LTD