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Silicon-based high-speed perovskite light source and preparation method thereof

A technology of perovskite and cesium-lead-bromide perovskite, which is applied in the field of silicon-based high-speed perovskite light source and its preparation, can solve the problems of large Auger recombination constant, poor thermal conductivity of perovskite, device aging and failure, etc. , to achieve the effects of reducing luminescence quenching, increasing the current density range, and improving heat dissipation management

Pending Publication Date: 2022-05-27
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the perovskite light source has the following problems at the material level: the Auger recombination constant is large, which is 2-3 orders of magnitude of GaAs material; the thermal conductivity of perovskite is also poor, which is 2-3 times lower than that of silicon and GaAs orders of magnitude
Therefore, Auger recombination at higher injection currents can lead to severe Joule heating, which eventually leads to device aging failure

Method used

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  • Silicon-based high-speed perovskite light source and preparation method thereof
  • Silicon-based high-speed perovskite light source and preparation method thereof

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preparation example Construction

[0036] The present invention also provides a preparation method of a silicon-based high-speed perovskite light source, comprising the following steps:

[0037] S1 provides a silicon base layer;

[0038] S2 prepares a strip-shaped gold electrode layer, uses a magnetron sputtering coating system and a mask, and coats a 200nm-thick gold layer on the silicon-based designated area substrate;

[0039] S3 carries out ultraviolet ozone treatment on the strip-shaped gold electrode; the preferred treatment is 20 minutes;

[0040] S4 prepares the hole transport layer, preferably using PEDOT:PSS to spin-coat on the substrate after S3 treatment, and bake in a vacuum box; preferably bake in a vacuum box at 150°C for 40 minutes;

[0041] S5 prepares a methyl-cesium lead bromide perovskite layer, and after the substrate treated in S4 is cooled, it is transferred to a nitrogen glove box, and the methyl-cesium lead bromide perovskite precursor solution is used for spin coating on the substrate...

Embodiment 1

[0052] The preparation method of the silicon-based high-speed perovskite light source of the present embodiment is as follows:

[0053] S1 provides a silicon base layer;

[0054] S2 prepares a strip-shaped gold electrode layer, uses a magnetron sputtering coating system and a mask, and coats a 200nm-thick gold layer on the silicon-based designated area substrate;

[0055] S3 performs ultraviolet ozone treatment on the strip-shaped gold electrode layer for 20 minutes;

[0056] The PEDOT:PSS hole transport layer was prepared from S4, spin-coated on the S3-treated substrate with PEDOT:PSS, and baked at 150 °C for 40 minutes in a vacuum box, with a thickness of about 40 nm;

[0057] The methyl-cesium lead bromide perovskite layer was prepared in S5, and after the substrate treated in S4 was cooled, it was transferred to a nitrogen glove box, and the methyl-cesium lead bromide perovskite precursor solution was used for spin coating on the substrate, and the Annealed on the substrat...

Embodiment 2

[0061] The preparation method of the silicon-based high-speed perovskite light source of the present embodiment is as follows:

[0062] S1 provides a silicon base layer;

[0063] S2 prepares a strip-shaped gold electrode layer, uses an electron beam evaporation coating system and a mask, and coats a 200nm-thick gold layer on the silicon-based designated area substrate;

[0064] S3 performs oxygen plasma treatment on the strip-shaped gold electrode layer for 10 minutes;

[0065] The PEDOT:PSS hole transport layer was prepared from S4, spin-coated on the S3-treated substrate with PEDOT:PSS, and baked at 150 °C for 40 minutes in a vacuum box, with a thickness of about 40 nm;

[0066] The methyl-cesium lead bromide perovskite layer was prepared in S5, and after the substrate treated in S4 was cooled, it was transferred to a nitrogen glove box, and the methyl-cesium lead bromide perovskite precursor solution was used for spin coating on the substrate, and the Annealed on the subs...

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Abstract

The silicon-based high-speed perovskite light source comprises a silicon-based layer, a gold electrode layer, a hole transport layer, a methyl-cesium lead bromide perovskite layer, an electron transport layer and a semitransparent silver electrode layer which are stacked in sequence, and methyl ammonium bromide is added when the methyl-cesium lead bromide perovskite layer is prepared. According to the silicon-based high-speed perovskite light source, light emitting quenching of the cesium-lead-bromine perovskite light source and external quantum fluorescence efficiency dithering under high current density can be reduced, and the modulatable current density interval and the effective modulation bandwidth range of a device are improved.

Description

technical field [0001] The invention relates to the field of light-emitting devices, in particular to a silicon-based high-speed perovskite light source and a preparation method thereof. Background technique [0002] In recent years, emerging halide perovskite perovskite materials, as emerging semiconductor materials, have the advantages of large absorption coefficient, long carrier diffusion length, low defect state density and tunable band gap, etc., and have been used in solar cells, photodetectors, etc. , LED and other optoelectronic fields show a wide range of application prospects. Its solution-processable properties allow perovskite materials to be grown and processed on any material platform, with strong compatibility and tunability. In addition to its reference in the field of display and light-emitting, perovskite light sources can also be used as light sources to convert electrically modulated data into modulated optical signals, and conduct data transmission thr...

Claims

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Application Information

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IPC IPC(8): H01L51/50H01L51/54H01L51/56
CPCH10K71/12H10K71/40H10K85/30H10K50/11Y02E10/549
Inventor 巫江任翱博
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA