Low-temperature electrolyte and lithium ion battery containing same
A lithium-ion battery and electrolyte technology, applied in secondary batteries, circuits, electrical components, etc., can solve problems such as hindering the low-temperature performance of the battery, increasing the internal resistance of the battery, etc., achieving excellent low-temperature performance and cycle performance, and improving conductivity. efficiency, high ionic conductivity
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Embodiment 1
[0034] In an inert atmosphere glove box with both water content and oxygen content below 5 ppm, the organic solvent ethylene carbonate (EC) and ethyl methyl carbonate (EMC) were prepared into an organic solvent in a mass ratio of 1:1. Slowly add lithium hexafluorophosphate to the solvent to dissolve, then add 1% fluoroethylene carbonate and 1% pyrrole-1-sulfonic acid pyrrol-1-yloxyalkanecarboxylic acid anhydride (structural formula shown in formula (2)) ), stirring to make it completely dissolved to obtain a lithium-ion battery electrolyte. The mass fractions of lithium hexafluorophosphate, organic solvent, fluoroethylene carbonate, and pyrrole-1-sulfonic acid pyrrol-1-yloxanecarboxylic acid anhydride (denoted as a) were 13.5%, 84.5%, 1%, and 1%, respectively.
[0035]
[0036] The preparation method of the (pyrrol-1-yloxy) methane acid methyl ester compound is the existing method, and the (pyrrol-1-yloxy) methane acid methyl ester compound in the prior art can also be used...
Embodiment 2
[0041] The organic solvents ethylene carbonate (EC), ethyl methyl carbonate (EMC), and dimethyl carbonate (DMC) were mixed in a mass of 1:1:1 in an inert atmosphere glove box with both water and oxygen content below 5 ppm. Than be prepared into an organic solvent, slowly add lithium hexafluorophosphate to the prepared organic solvent to dissolve, then add 1% of the total mass of the electrolyte, fluoroethylene carbonate, 1% of (pyrrol-1-yloxy) formic acid-pyrrole-2 -base ester (the structural formula is shown in formula (3)), which is completely dissolved after stirring to obtain an electrolyte for a lithium ion battery. The mass fractions of lithium hexafluorophosphate, organic solvent, fluoroethylene carbonate, and (pyrrol-1-yloxy)carboxylate-pyrrol-2-yl ester (denoted as b) were 13.5%, 84.5%, 1%, and 1%, respectively.
[0042]
[0043] Compared with Example 1, R in the preparation process of (pyrrol-1-yloxy) formic acid-pyrrol-2-yl ester in this example is
[0044] Su...
Embodiment 3
[0046] The organic solvents ethylene carbonate (EC), ethyl methyl carbonate (EMC) and dimethyl carbonate were prepared in a mass ratio of 1:1:1 in an inert atmosphere glove box with water content and oxygen content below 5ppm. organic solvent, slowly add lithium hexafluorophosphate (LiPF 6 ) to dissolve, then add 1% fluoroethylene carbonate and 1% (pyrrol-1-yloxy) trifluoromethyl formate (structural formula is shown in formula (4)) of the total mass of the electrolyte, and after stirring It was completely dissolved to obtain a lithium-ion battery electrolyte. The mass fractions of lithium hexafluorophosphate, organic solvent, fluoroethylene carbonate and trifluoromethyl (pyrrol-1-yloxy)formate (denoted as c) were 13.5%, 84.5%, 1% and 1%, respectively.
[0047]
[0048] Compared with Example 1, in this example (pyrrol-1-yloxy) trifluoromethyl formate preparation process R is -CF 3 .
[0049] Subsequent battery preparation operations were the same as in Comparative Example...
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