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Odor-removing formaldehyde-removing paint as well as preparation method and application thereof

A technology of deodorization and hydrothermal reaction, applied in separation methods, chemical instruments and methods, catalysts for physical/chemical processes, etc., can solve problems such as secondary pollution, and achieve the effect of preventing secondary pollution and excellent air purification function

Pending Publication Date: 2022-06-07
厦门百安兴新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the main aldehyde removal methods on the market, including air purifiers, various aldehyde removal paints or coatings, are mainly based on the use of various adsorbents for adsorption. The problem of secondary pollution cannot fundamentally solve the pollution of formaldehyde gas (Zhu X D, Shen J, Liu Y.Removal of Formaldehyde and Volatile Organic Compounds from Particleboards by Air-Cleaning Materials[J].Advanced Materials Research,2010,113-116 :1870-1873.)

Method used

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  • Odor-removing formaldehyde-removing paint as well as preparation method and application thereof
  • Odor-removing formaldehyde-removing paint as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The preparation steps of the odor-removing aldehyde paint are as follows:

[0030] (1) Dissolve 1.5g of chitosan in 125mL of 9% acetic acid solution, stir and react for 1h, add a mixture powder consisting of 1.5g of coconut shell charcoal and 1.5g of diatomaceous earth, continue to stir for 1h, and filter the obtained solid Washing with deionized water until the pH value of the collected eluent is close to 7, and drying the washed solid at 110°C to prepare a carboxylated chitosan composite carrier;

[0031] (2) adding the carboxylated chitosan composite carrier prepared in step (1) into 20 ml of acetic acid solution with a mass concentration of 5%, then slowly dripping 8 ml of a copper salt solution with a molar concentration of 50 mmol / L and stirring evenly , continue stirring, add 2 ml of ascorbic acid solution with a mass concentration of 10%, adjust the pH value to 6.5 with dilute ammonia water, and hydrothermally react the resulting mixture at 200 ° C for 2 h, afte...

Embodiment 2

[0036] The odor-removing aldehyde paint prepared in Example 1 was made into a coating and then tested for performance; wherein, the preparation of the odor-removing aldehyde coating was prepared by the method provided in GB / T1727-1992, and the specific steps were as follows: The tinplate sheet conforming to the GB / T2520-2017 specification is cut into a test plate with a size of 50mm × 120mm × 0.3mm, and the test plate is cleaned according to the provisions of GB9271-1988 for the test plate. Put the odor-removing formaldehyde paint on the tinplate test plate with a scraper, and finally stand and cure for 2 days at a temperature of 23°C and a relative humidity of 50% to test its formaldehyde purification effect in the actual environment:

[0037] Place the tinplate test panel coated with deodorant and formaldehyde-removing paint at room temperature of 20±2℃, relative humidity of 80%, and low formaldehyde concentration of 2±0.5mg / m2 3 The purification test was carried out in a si...

Embodiment 3

[0040] The odor-removing aldehyde paint prepared in Example 1 was made into a coating and then tested for performance; wherein, the preparation of the odor-removing aldehyde coating was prepared by the method provided in GB / T1727-1992, and the specific steps were as follows: The tinplate sheet that meets the GB / T2520-2017 specification is cut into a test plate with a size of 50mm × 120mm × 0.3mm, and the test plate is cleaned according to the provisions of GB9271-1988 for the test plate. Put the odor-removing formaldehyde paint on the tinplate test plate with a scraper, and finally stand and cure for 2 days at a temperature of 23°C and a relative humidity of 50% to test its formaldehyde purification effect in the actual environment:

[0041] Place the tinplate test plate coated with odor-removing aldehyde paint at room temperature of 20±2℃, relative humidity of 80%, and low toluene concentration of 2±0.5mg / m2 3 The purification test was carried out in a simulated cabin (30cm×2...

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Abstract

The invention discloses odor-removing and formaldehyde-removing paint as well as a preparation method and application thereof, and the preparation method of the odor-removing and formaldehyde-removing paint comprises the following steps: 1, dissolving chitosan in an acetic acid solution, and adding mixture powder consisting of coconut shell charcoal and diatomite to prepare a carboxylated chitosan composite carrier; 2, loading cuprous oxide and silver nitrate onto the carboxylated chitosan composite material; 3, heating water-borne epoxy resin, triethylene tetramine and polyethylene glycol diglycidyl ether for reaction, and then adding deionized water for dilution to obtain a water-borne epoxy resin curing agent; in the last step, water-borne epoxy resin and the prepared corresponding curing agent are fully mixed, then the silver-cuprous oxide loaded carboxylated chitosan composite material is added, and the mixture is stirred to be uniform. The odor-removing and formaldehyde-removing paint provided by the invention has an excellent air purification function at room temperature, and can completely convert various pollutants, especially formaldehyde, in air into carbon dioxide and water.

Description

technical field [0001] The invention belongs to the technical field of aldehyde-removing purifiers, in particular to a deodorant-removing aldehyde paint and a preparation method and application thereof. Background technique [0002] Various volatile aldehydes, especially formaldehyde, are one of the main sources of indoor air pollution (HuangHB, Xu Y, Feng QY, et al. Low temperature catalytic oxidation of volatile organic compounds: a review [J]. Catal. Sci .Technol. 2015, 5(5):2649-2669.). They are easily released from construction and furniture materials and often have a variety of pungent and unpleasant odors. Long-term exposure can cause serious effects on human health, such as allergic reactions, dermatitis, nasopharyngeal cancer and leukemia. In 2017, the International Agency for Research on Cancer of the World Health Organization has classified formaldehyde as a carcinogen. In view of their harm to human body, all countries in the world have strict regulations on in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/02C09D7/62B01D53/86B01D53/72B01J31/28
CPCC09D163/00C09D7/62B01D53/8668B01J31/28B01D2257/704C08K2003/2248C08K2003/0806C08K9/12C08K3/08C08K3/22Y02A50/20
Inventor 甘勇强甘丽娜卢兰妹戴燕中
Owner 厦门百安兴新材料有限公司