Preparation method and application of lithium battery negative plate

A negative electrode sheet and lithium battery technology, applied in battery electrodes, secondary batteries, inductors/transformers/magnets, etc., can solve problems such as large concentration polarization, increased difficulty, and potential safety hazards, and achieve a large loss tangent , good thermal stability, fast heating effect

Active Publication Date: 2022-07-15
新乡市中天新能源科技股份有限公司
View PDF19 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, thick electrodes can also negatively impact battery performance while increasing energy density
As the thickness of the electrode increases, it becomes more difficult for the electrolyte to penetrate from the interface between the separator and the coating layer to the interface between the coating layer and the current collector, and it is easy to cause the electrode to be incompletely wetted, resulting in lithium deposition in the battery at a high rate of full charge, reducing the battery capac

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method and application of lithium battery negative plate
  • Preparation method and application of lithium battery negative plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0032] Step S1: put 1mol·L −1 FeCl 3 ·6H 2 O solution and 0.5mol·L −1 FeSO 4 ·7H 2 Add 50 mL of each O solution into a three-necked round-bottomed flask, stir in an oil bath at 60 °C for 30 min under nitrogen protection, and then add 10 mL with a concentration of 1 mol·L -1 NH 3 ·H 2 O adjusted the pH of the mixed system to 11, and after cooling to room temperature, the black nano-Fe was separated by a magnetic field. 3 O 4 The particles were washed alternately with ethanol and deionized water for several times, and then dried at 60 °C to obtain nano-Fe 3 O 4 particle;

[0033] Step S2: put 0.03g nano Fe 3 O 4 The particles were mixed with 0.04 mmol dodecylbenzene sulfonic acid and 0.0267 mmol hydrochloric acid in deionized water, and then 20 mL was added to a concentration of 0.5 mol L -1 Aniline, with the addition of aniline, the emulsion quickly turned white, continue to stir for 30min, add 30mL dropwise to the reaction solution with a concentration of 1mol·L ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Viscosityaaaaaaaaaa
Thicknessaaaaaaaaaa
Viscosityaaaaaaaaaa
Login to view more

Abstract

The preparation method specifically comprises the following steps: uniformly mixing a core-shell structure magnetic nano template which takes polyaniline as a shell and Fe3O4 as a core with a negative electrode material, a binder, a conductive agent and a solvent water to prepare negative electrode slurry, coating the surface of a current collector with the negative electrode slurry, and drying to obtain the lithium battery negative electrode plate. The preparation method comprises the following steps: preparing a thick electrode from magnetic nano Fe3O4, directionally assembling the magnetic nano Fe3O4 on the surface of a current collector by loading a magnetic field, recycling the magnetic nano Fe3O4 in the thick electrode through microwave heating and a magnetic recycling device, and constructing a three-dimensional network channel with high conductivity in the thick electrode to effectively improve the conductivity of the electrode, shorten ion and electron migration paths and improve the conductivity of the electrode. A multi-dimensional open permeation channel is provided, the wettability of an electrolyte is enhanced, the electrode tortuosity is reduced, the gradient porosity is generated, a molecular-level channel beneficial to lithium ion transportation is formed, and high-speed conduction of lithium ions is promoted.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a preparation method and application of a lithium battery negative electrode sheet. Background technique [0002] Lithium-ion batteries have the advantages of small self-discharge, high specific energy, long cycle life, environmental protection and no pollution, and are widely used in portable electronic products, electric vehicles, reserve power sources, and aviation fields. With the development of lithium-ion battery technology and the continuous advancement of the country's new energy industry, people's requirements for high energy density, high power and light weight of lithium-ion batteries are getting higher and higher. [0003] The preparation of ultra-thick pole pieces with high coating weight is one of the most direct ways to improve the specific energy of batteries. However, thick electrodes can negatively affect battery performance while incr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): H01M4/1393H01M4/62H01M4/133H01M10/0525H01F1/00H01F41/00
CPCH01M4/1393H01M4/133H01M4/624H01M10/0525H01F1/0054H01F41/00H01M2004/027H01M2004/021Y02E60/10
Inventor 张学红郑莉曹季坤刘琦王长磊李文梦白正宇
Owner 新乡市中天新能源科技股份有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products