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Low-titanium low-sulfur ferrochrome and production method thereof

A production method and ferrochrome technology, which is applied in the field of ferrochrome alloy, can solve the problems that cannot be produced with high-precision bearing steel, the recovery rate of main element chromium is low, and the energy consumption of the production method is high, so that the product is in good condition, the content of undesired impurities is reduced, The effect of low production cost

Active Publication Date: 2022-08-05
丰镇市华兴化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This production method has high energy consumption, relatively complex process equipment, and because China is a chromium-poor country, chromium resources are extremely tight, and this process inevitably leads to a low recovery rate of the main element chromium
[0006] Although the patent CN101962714B only uses an ordinary submerged arc furnace for selective reduction to produce low titanium and high chromium, this method can only guarantee Ti<0.03%, and the Ti content of the finished product inevitably fluctuates with the furnace conditions, and the pass rate cannot be guaranteed
And due to the relatively high titanium content, the product cannot be used in the production of high-precision bearing steel

Method used

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  • Low-titanium low-sulfur ferrochrome and production method thereof

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Experimental program
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Effect test

Embodiment 1

[0038] The present embodiment provides a kind of production method of low titanium and low sulfur ferrochromium, and specifically comprises the following steps:

[0039] S1. Pretreatment of chromite: grind 200kg of chromite into fine powder, add an ethanol solution containing 5wt% of silane coupling agent KH580, the solid-liquid ratio of chromite powder and ethanol solution containing silane coupling agent KH580 1:5g / mL, 1500W ultrasonic heating to 70 ℃, reacting for 1h, further adding 2.4kg silica powder and 4kg lime powder, pelletizing to obtain green pellets; further drying and roasting to obtain pellets with a particle size of 10- 15mm;

[0040] Silica powder SiO 2 The content is not less than 97%, and the particle size is 0.1-1mm; the CaO content of lime powder is not less than 95%, and the particle size is 0.3-1mm;

[0041] S2. Oxygen blowing melting: add the pellets into the furnace, blow oxygen at the top at the same time, raise the temperature until it is completely...

Embodiment 2

[0051] The present embodiment provides a kind of production method of low titanium and low sulfur ferrochromium, and specifically comprises the following steps:

[0052] S1. Pretreatment of chromite: grind 200kg of chromite into fine powder, add an ethanol solution containing 15wt% silane coupling agent KH590, the solid-liquid ratio of chromite powder and the ethanol solution containing silane coupling agent KH590 1:5g / mL, 2500W ultrasonic heating to 90 ℃, reacting for 3h, further adding 2.4kg silica powder and 4kg lime powder, pelletizing to obtain green pellets; further drying and roasting to obtain pellets with a particle size of 10- 15mm;

[0053] Silica powder SiO 2 The content is not less than 97%, and the particle size is 0.1-1mm; the CaO content of lime powder is not less than 95%, and the particle size is 0.3-1mm;

[0054] S2. Oxygen blowing melting: add the pellets into the furnace, and blow oxygen at the top at the same time, heat up to complete melting, and clean...

Embodiment 3

[0064] The present embodiment provides a kind of production method of low titanium and low sulfur ferrochromium, and specifically comprises the following steps:

[0065] S1. Pretreatment of chromite: grind 200kg of chromite into fine powder, add an ethanol solution containing 10wt% silane coupling agent, and the solid-to-liquid ratio of chromite powder and the ethanol solution containing silane coupling agent is 1 : 5g / mL, 1500W ultrasonic heating to 80 ℃, reaction 2h, further adding 2.4kg silica powder and 4kg lime powder, pelletizing to obtain green pellets; Further drying and roasting are carried out to obtain pellets, and the particle size is 10-15mm;

[0066] The silane coupling agent is the compound mixture of KH560 and KH550, and the mass ratio is 5:3;

[0067] Silica powder SiO 2 The content is not less than 97%, and the particle size is 0.1-1mm; the CaO content of lime powder is not less than 95%, and the particle size is 0.3-1mm;

[0068] S2. Oxygen blowing melting...

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Abstract

The invention provides low-titanium low-sulfur ferrochrome and a production method thereof, and belongs to the technical field of ferrochrome. Chromite, coke, silica powder, lime powder, a titanium removal agent, a desulfurizing agent and a slag former are used as raw materials; the low-titanium and low-sulfur ferrochrome is obtained through oxygen blowing melting, titanium removal and desulfurization, carbon addition, dephosphorization and desulfurization, refining and continuous casting after chromite is pretreated. The final slag is controlled to be in a CaO-Al2O3-SiO2-MgO four-source slag type; the mass percent of TiO2 in the chromite is less than or equal to 0.5%, the mass percent of S is less than or equal to 0.2%, and the mass percent of P is less than or equal to 0.3%. The production process is simple, the production cost is obviously lower than that of the prior art, the smelting process technology is reasonable, an industrial submerged arc furnace is adopted for continuous smelting, the product state is good, components are stable, meanwhile, the content of undesirable impurities such as Ti, P and S in the ferrochrome alloy is obviously reduced, and the strength, toughness, ductility and abrasion resistance of the obtained product are all obviously improved.

Description

technical field [0001] The invention relates to the technical field of ferrochromium alloys, in particular to a low-titanium and low-sulfur ferrochromium and a production method thereof. Background technique [0002] Bearing is a mechanical part used to support the transmission shaft and bear the load. It is a commonly used wearing part in the machinery and equipment manufacturing industry, and its use and consumption are very large. The quality of the bearing will directly affect the performance of the mechanical equipment, and the quality of the bearing is mainly determined by the performance of the bearing steel material. With the rapid development of my country's bearing industry, the demand for high-quality bearing steel with excellent performance is also increasing. [0003] Ferrochromium is the most important raw material for the production of stainless steel, mainly used in the production of stainless steel, ball bearing steel, tool steel, nitrided steel, heat-stren...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/02C22C27/06
CPCC22C1/02C22C27/06Y02P10/20
Inventor 张先锋黄海庄爱玲
Owner 丰镇市华兴化工有限公司
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