Polyurethane for bearing and preparation method thereof

A polyurethane and bearing technology, which is applied in the field of polyurethane for bearings and its preparation, can solve the problems of permanent deformation of polyurethane and affect the service life of polyurethane, and achieve the effects of good resilience, prolonging service life and improving structural density.

Pending Publication Date: 2022-08-09
烟台辰宇汽车部件有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, when the bearing is applied to a vehicle, it is easily affected by the high-load extrusion force. When the high load is removed, the polyurethane is prone to permanent deformation, which affects the service life of the polyurethane on the bearing.

Method used

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  • Polyurethane for bearing and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0045] Preparation Example 1: Modified four-needle zinc oxide whiskers were prepared by the following method:

[0046] Weigh 10 g of four-needle zinc oxide whiskers and place them in 200 g of aminopropyltriethoxysilane to disperse evenly, then dry and disperse until the four-needle zinc oxide whiskers do not agglomerate and adhere to each other to obtain a finished product; four The diameter of the central body of the needle-shaped zinc oxide whisker is 1 μm, and the length of the needle-shaped body is 20 μm.

[0047] Preparation example of mesoporous silica

preparation example 2

[0048] Preparation Example 2: Mesoporous silica was prepared by the following method:

[0049] Weigh 490 mg of cetyl trimethyl ammonium chloride, 15 mg of 99% absolute ethanol, and 0.22 mg of triethanolamine together into 400 mL of deionized water, and stirred at 84 °C for 0.6 h, and then added to 1 mL / mL of deionized water. Add 2.6 mL of tetraethyl orthosilicate at the speed of min, stir evenly, stir at 84 °C for 6 h, collect the product by centrifugation for 15 min, wash with methanol 5 times, and then disperse in an acidic methanol solution (containing 2 mL of HCl 100mL methanol) was condensed and refluxed for 3 times, the temperature of the condensed reflux was 66 ° C, and the time was 14h. After the washing was complete, the semi-finished product was collected by centrifugation, then washed with methanol twice, and then washed with deionized water for 3 times, and then vacuum freeze-dried 12h, the finished mesoporous silica was obtained.

[0050] Preparation example of e...

preparation example 3

[0052] Preparation Example 3: The epoxy resin liquid was prepared by the following method:

[0053] Weigh 60kg of epoxy resin, 20kg of curing agent, 8kg of diluent, and 1.6kg of leveling agent, mix and stir to obtain the finished epoxy resin liquid; epoxy resin model E44; curing agent is T-31 curing agent; diluent is Anhydrous ethanol, the mass fraction of anhydrous ethanol is 99%; the leveling agent is HR-6031 wetting and leveling agent (polyether modified polysiloxane polymer).

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Abstract

The invention relates to the field of high polymer materials, and particularly discloses polyurethane for a bearing and a preparation method of the polyurethane. The invention discloses polyurethane for a bearing. The polyurethane is prepared from the following raw materials in parts by weight: 50-75 parts of polymer polyol, 20-40 parts of diisocyanate, 4-8 parts of a chain extender, 2-5 parts of a cross-linking agent, 1-3 parts of loading mesoporous silica and 0.5-1.5 parts of filler fibers, the preparation method comprises the following steps: S1, weighing the loading material mesoporous silica and the filler fiber, and uniformly mixing and stirring to prepare a primary mixture; s2, weighing polymer polyol and diisocyanate, mixing the polymer polyol and the diisocyanate, and carrying out a reaction at 70-85 DEG C for 2-3.5 h to prepare a prepolymer; s3, weighing a prepolymer, a chain extender, a cross-linking agent and the primary mixture, uniformly mixing and stirring, and reacting at 100-120 DEG C for 12-15 hours to obtain a finished product polyurethane; the polyurethane on the bearing is not prone to permanent deformation after being subjected to high load force, and the service life of the polyurethane on the bearing is prolonged.

Description

technical field [0001] The present application relates to the field of polymer materials, and more particularly, to a polyurethane for bearings and a preparation method thereof. Background technique [0002] Polyurethane is a polymer compound with good stability, chemical resistance, resilience and mechanical properties. [0003] Bearing is a component that supports the mechanical rotating body, reduces the friction coefficient during the movement of the mechanical rotating body, and ensures the rotation accuracy; while the bearing is often easy to withstand high load forces during use, in order to make the bearing have better buffer, reduce Vibration effect, polyurethane is applied to the bearing. [0004] However, when the bearing is applied to the vehicle, it is easily affected by the high-load extrusion force. When the high load is removed, the polyurethane is prone to permanent deformation, thereby affecting the service life of the polyurethane on the bearing. [0005...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L63/00C08L75/06C08K7/08C08K7/06C08K9/10C08K7/26
CPCC08L75/04C08L75/06C08L63/00C08K7/08C08K7/06C08K9/10C08K7/26
Inventor 王海杰傅运军高鹏孙立胜柳尧辉
Owner 烟台辰宇汽车部件有限公司
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