Method for preparing starch glue for lumber

A starch glue and starch technology, applied in the directions of starch-derived adhesives, adhesive types, etc., can solve the problems of insignificant performance of wood adhesives, poor water resistance and stability, slow drying speed, etc., and achieve low price and water resistance. Good, fast drying effect

Inactive Publication Date: 2007-01-03
JIANGNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Starch has been used as an adhesive after gelatinization or oxidation modification for a long time, but its application range is greatly limited due to its poor moisture resistance, low initial adhesion, and slow drying speed, especially in wood adhesives. In the industry, few researchers use starch as the main raw material to develop wood adhesives. Most of the research is only adding a small amount of starch to wood adhesives such as white latex and urea-formaldehyde resins. The results are not significant for improving the performance of wood adhesives; there are also a small number of studies Those who directly compound starch or modified starch with polymers such as polyvinyl acetate emulsion, VAE emulsion, etc. in a certain proportion and add additives to make wood adhesives, although this method uses more starch than the previous method. There is a large increase, but because the compounding fails to change the starch properties too much, the water resistance and stability of the adhesive are still poor, and a large amount of additives such as formaldehyde must be added for improvement, which not only complicates the process, but also Increase costs, generate pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Recipe (by mass):

[0039] cornstarch 100

[0040] water 250

[0041] hydrochloric acid 1

[0042]Ammonium persulfate 2.4

[0043] Vinyl acetate 80

[0044] Polyvinyl alcohol 10

[0045] Borax 0.6

[0046] Urea 20

[0047] Glycerin 10

[0048] Tributyl phosphate 4

[0049] Process: Mix cornstarch and hydrochloric acid solution into 30% (w / w) starch milk, add ammonium persulfate, acidolysis and oxidation at 60°C for 1.5h, adjust the pH to about 4.0, slowly add vinyl acetate dropwise, 1.5 After h, add the remaining ammonium persulfate, react at 70°C for 3h, neutralize to neutral, add polyvinyl alcohol solution to the solution, then add dropwise 5% borax solution, heat up to 80°C, and keep warm for reaction 1h, cool down to 50°C, add urea, glycerin and tributyl phosphate, stir for 0.5h, continue to cool down, discharge at room temperature, pack, seal, and set aside....

Embodiment 2

[0051] Recipe (by mass):

[0052] Potato Starch 100

[0053] water 300

[0054] Sulfuric acid 1.5

[0055] Potassium persulfate 3.8

[0056] Butyl acrylate 50

[0057] Polyvinyl alcohol 15

[0058] Borax 1.8

[0059] Urea 40

[0060] Dibutyl phthalate 7

[0061] Octanol 2

[0062] Process: Make potato starch and sulfuric acid solution into 35% (w / w) starch milk, add potassium persulfate, acidolysis and oxidation at 70°C for 0.5h, adjust the pH to about 3.5, slowly add butyl acrylate, 1.5 After h, add the remaining potassium persulfate, react at 65°C for 4h, neutralize to neutral, add polyvinyl alcohol solution to the solution, then add 5% concentration of borax solution dropwise, heat up to 85°C, keep warm for reaction After 30 minutes, cool down to 50°C, add urea, dibutyl phthalate and octanol, stir for 0.5h, then continue to cool down, discharge at room temperature, pack, seal and set as...

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PUM

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Abstract

The present invention relates to a preparation method of starch glue for wood. Said invention uses starch as main raw material, and adopts the following steps: firstly, making starch undergo the processes of acidolysis, oxidation and graft copolymerization, etc., then adding modifying agent and complexing agent to make cross-linking modification, then heating and gelatinizing, cooling and successively adding the adjuvants of diluent, plasticizer and defoaming agent so as to obtain a starch glue with excellent performance for wood.

Description

technical field [0001] The invention relates to a method for preparing starch glue for wood, and the invention belongs to the technical field of adhesive manufacturing methods. Background technique [0002] According to different raw materials and production methods of adhesives, wood adhesives can be divided into two categories: natural polymer adhesives and synthetic polymer adhesives. Natural polymer adhesives mainly include protein glue and starch glue. The history of using natural adhesives in my country is quite long. Since this adhesive is made of natural substances, most of them are water-soluble. Generally speaking, the properties of bonding strength, water resistance, heat resistance, and chemical corrosion resistance are not high. Glued products cannot withstand harsh conditions and have a short service life. Therefore, the amount of natural polymer glue used in wood industry adhesives is decreasing. At present, synthetic polymer adhesives are mainly used, among ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J103/04
Inventor 顾正彪李兆丰洪雁
Owner JIANGNAN UNIV
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